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Volumn 46, Issue 3, 2007, Pages 429-432

Formation and structure of a sterically protected molybdenum hydride complex with a 15-electron configuration: [(1,2,4-C5H 2tBu3)Mo(PMe3)2H]

Author keywords

EPR spectroscopy; Hydride ligands; Molybdenum; Reductive elimination; Structure elucidation

Indexed keywords

CARRIER CONCENTRATION; COMPLEXATION; ELECTRON SPIN RESONANCE SPECTROSCOPY; MOLECULAR STRUCTURE; REDOX REACTIONS; STEREOCHEMISTRY;

EID: 33846427330     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200603628     Document Type: Article
Times cited : (14)

References (29)
  • 4
    • 0038362040 scopus 로고    scopus 로고
    • Eds, R. Poli, M. Peruzzini, Elsevier Science, Amsterdam
    • R. Poli in Recent Advances in Hydride Chemistry (Eds.: R. Poli, M. Peruzzini), Elsevier Science, Amsterdam, 2001, p. 139.
    • (2001) Recent Advances in Hydride Chemistry , pp. 139
    • Poli, R.1
  • 20
    • 33846445124 scopus 로고    scopus 로고
    • The structures were solved by direct methods (SIR97) and refined by full-matrix least squares (SHELXL97, H atoms were treated with the riding model except for the hydride ligands, which were fully refined with isotropic thermal parameters. CCDC-619352-619354 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via [CptBuMo-(PMe3)2H3, C 23H50MoP2, Mr, 484.51, monoclinic, space group P21/n a, 16.2915(15, b, 17.4655(16, c, 9.2144(8) Å, β, 92.651(10)°, V, 2619.1(4) Å3, Z, 4, ρcalcd, 1.229 g cm-3, μ, 0.629 mm-1, MoKα radiation λ, 0.71073 Å, T, 180 K, 2θmax
    • -3.
  • 21
    • 0000714026 scopus 로고    scopus 로고
    • R. Poli, Chem. Rev. 1996, 96, 2135.
    • (1996) Chem. Rev , vol.96 , pp. 2135
    • Poli, R.1
  • 26
    • 33846434671 scopus 로고    scopus 로고
    • This compound has been isolated and fully characterized, including by X-ray crystallography. Details will be presented in a forthcoming full paper
    • This compound has been isolated and fully characterized, including by X-ray crystallography. Details will be presented in a forthcoming full paper.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.