A study of β-hydride abstraction from alkanediyl homobimetallic complexes [{Cp(CO)2Fe}2{μ-(CnH2n)}] (n = 4-10, Cp = η5-C5H5)

Journal of Organometallic Chemistry

Volumn 692, Issue 5, 2007, Pages 1138-1149

  Changamu, Evans O ^a   Friedrich, Holger B ^a  

^a UNIVERSITY OF KWAZULU NATAL   (South Africa)

Author keywords

Alkyl bridged complexes; Carbenium ion; Dicationic; Hydride abstraction; Metallacyclopropane; Monocationic

Indexed keywords

COMPLEXATION; ETHERS; IRON COMPOUNDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PROPANE; REACTION KINETICS;

ALKYL-BRIDGED COMPLEXES; CARBENIUM IONS; DICATIONIC; HYDRIDE ABSTRACTION; METALLACYCLOPROPANE; MONOCATIONIC;

ORGANOMETALLICS;

EID: 33846391216     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2006.11.017     Document Type: Article

References (28)

1. King R.B., and Bisnette M.B. J. Organomet. Chem. 7 (1967) 311
2. Finch K.P., Gafoor M.A., Mapolie S.F., and Moss J.R. Polyhedron 10 (1991) 963
3. Johnson J.W., and Moss J.R. Polyhedron 4 (1985) 563
4. Changamu E.O., Friedrich H.B., and Rademeyer M. Acta Crystallogr., Sect. E 62 (2006) m442
5. Friedrich H.B., Changamu E.O., and Rademeyer M. Acta Crystallogr., Sect. E 62 (2006) m405
6. Friedrich H.B., and Moss J.R. J. Chem. Soc., Dalton Trans. (1993) 2863
7. Finch K.P., Moss J.R., and Niven M.L. Inorg. Chim. Acta 166 (1989) 181
8. Scott L.G., Moss J.R., Brown M.E., and Hindson K.J. J. Organomet. Chem. 282 (1985) 255
9. Archer S.J., Finch K.P., Friedrich H.B., Moss J.R., and Crouch A.M. Inorg. Chim. Acta 182 (1991) 145
10. Lennon P., and Rosenblum M. J. Am. Chem. Soc. 105 (1983) 1233
11. Lennon J.P., Rosan A., Rosenblum M., Tancrede J., and Waterman P. J. Am. Chem. Soc. 102 (1980) 7033
12. Aris K.R., Aris V., and Brown J.M. J. Organomet. Chem. 42 (1972) C67
13. Sanders A., and Gierring W.P. J. Organomet. Chem. 104 (1976) 67
14. Chatt J., and Duncanson L.A. J. Chem. Soc. (1953) 2339
15. Silverstein R.M., Webster F.X., and Kiemle D.J. Spectrometric Identification of Organic Compounds. 7th ed. (2005), John Wiley & Sons Inc.
16. Gunther H. NMR Spectroscopy, Basic Principles, Concepts and Applications in Chemistry. 2nd ed. (1995), John Wiley & Sons Inc.
17. Watson L.A., Franzman B., Bollinger J.C., and Caulton K.G. New J. Chem. 27 (2003) 1769
18. Chang T.C.T., Foxman B.M., Rosenblum M., and Stockman C. J. Am. Chem. Soc. 103 (1981) 7361-7362
19. Dooling D., Joorst G., and Mapolie S.F. Polyhedron 20 (2001) 467
20. Friedrich H.B., Moss J.R., and Williamson B.K. J. Organomet. Chem. 394 (1990) 313
21. Dewar M.J.S. Bull. Soc. Chim. Fr. 18 (1951) C79
22. Govender T., Kruger H.G., and Raasch T. Struct. Chem. 16 (2005) 129
23. Crabtree R.H. The Organometallic Chemistry of the Transition Metals (1988), Wiley-Interscience, Singapore
24. Clayton H.S., Moss J.R., and Dry M.E. J. Organomet. Chem. 688 (2003) 181
25. Joorst G., Karlie R., and Mapolie S.F. S. Afr. J. Chem. 51 (1998) 132
26. Lennon P., Madhavarao M., Rosan A., and Rosenblum M. J. Organomet. Chem. 108 (1976) 93
27. King R.B., and Stone F.G.A. Inorg. Synth. 7 (1963) 110
28. King R.B. Inorg. Chem. 2 (1963) 531