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Volumn 63, Issue 9, 2007, Pages 2009-2018

Studies on the zirconium-mediated alkyne-aldehyde coupling reactions: a facile synthesis of stereodefined allylic alcohols and (Z)-2-en-4-yn-1-ols

Author keywords

[No Author keywords available]

Indexed keywords

ALDEHYDE; ALKYNE; ALKYNYL GROUP; ALLYL COMPOUND; ZIRCONIUM;

EID: 33846383696     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tet.2006.12.051     Document Type: Article
Times cited : (10)

References (54)
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    • For reviews, see:
  • 3
    • 4544294423 scopus 로고    scopus 로고
    • Imamoto T. (Ed), Georg Thieme, New York, NY
    • Negishi E., and Takahashi T. In: Imamoto T. (Ed). Science of Synthesis (Houben-Weyl Methods of Molecular Transformations). Category 1: Organometallics Vol. 2 (2003), Georg Thieme, New York, NY 681-848
    • (2003) Category 1: Organometallics , vol.2 , pp. 681-848
    • Negishi, E.1    Takahashi, T.2
  • 11
    • 33846378971 scopus 로고    scopus 로고
    • For the reaction of zirconacyclopentenes with aldehydes, see:
  • 15
    • 0038102454 scopus 로고    scopus 로고
    • For the reaction of zirconocene-alkyne complexes with aldehydes, see:
    • Zhao C., Yan J., and Xi Z. J. Org. Chem. 68 (2003) 4355 For the reaction of zirconocene-alkyne complexes with aldehydes, see:
    • (2003) J. Org. Chem. , vol.68 , pp. 4355
    • Zhao, C.1    Yan, J.2    Xi, Z.3
  • 31
    • 33846379716 scopus 로고    scopus 로고
    • note
    • For detailed reactions, see Supplementary data.
  • 32
    • 33846360461 scopus 로고    scopus 로고
    • note
    • nPrCHO at 0 °C. To our surprise, the coupling product of 5e was formed as a major product in 52% isolated yield after 6 h at 0 °C, along with the formation of 3e in 12% isolated yield.
  • 47
    • 33846362333 scopus 로고    scopus 로고
    • For transmetalation with CuCl, see:
  • 54
    • 33846396539 scopus 로고    scopus 로고
    • Komiya S. (Ed), Wiley, Chichester, UK
    • In: Komiya S. (Ed). Synthesis of Organometallic Compounds (2002), Wiley, Chichester, UK 338
    • (2002) Synthesis of Organometallic Compounds , pp. 338


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.