Acridinium salt based fluorescent and colorimetric chemosensor for the detection of cyanide in water

Organic Letters

Volumn 8, Issue 25, 2006, Pages 5721-5723

  Yang, Young Keun ^a   Tae, Jinsung ^a  

^a Yonsei University   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

ACRIDINE DERIVATIVE; ACRIDINE ORANGE; CYANIDE; DIMETHYL SULFOXIDE; FLUORESCENT DYE; SOLVENT;

ARTICLE; CHEMISTRY; COLORIMETRY; WATER SUPPLY;

ACRIDINE ORANGE; ACRIDINES; COLORIMETRY; CYANIDES; DIMETHYL SULFOXIDE; FLUORESCENT DYES; SOLVENTS; WATER SUPPLY;

EID: 33846328727     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol062323r     Document Type: Article

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25. f = 0.46 in EtOH) as a reference (Soep, B.; Kellamnn, A.; Lindqvist, L. Chem. Phys. Lett. 1972, 13, 241-244).
26. - (0.1 equiv) and 1 reaches completion within 10 min at 50 °C (see Supporting Information for time-dependent fluorescence changes).
27. Attempts to isolate 2 were unsuccessful, producing only 3. The related conversion of N-methyl-9-cyanoacridan to N-methylacridone by oxygen is known (ref 14b).
28. 1H NMR titration spectra suggest that the equilibrium between 1 and its ylide generated by the basic anions causes H/D exchange of α-carbonyl protons.
29. Upon addition of cyanide to 1, the solution turns colorless then pale blue. The intensity of the blue color becomes more intense with time. This may imply that the acridinone 3 is responsible for the blue color.
30. See Supporting Information for the sample calculation.
31. -.