The direct chiral separations of fungicide enantiomers on amylopectin based chiral stationary phase by HPLC

Chirality

Volumn 19, Issue 2, 2007, Pages 114-119

  Wang, Peng ^a   Liu, Donghui ^a   Jiang, Shuren ^a   Gu, Xu ^a   Zhou, Zhiqiang ^a  

^a CHINA AGRICULTURAL UNIVERSITY   (China)

Author keywords

ATPC; Chiral separation; Fungicides; HPLC

Indexed keywords

2 PROPANOL; AMINOPROPYLSILICA; AMYLOPECTIN; AMYLOPECTIN TRIS(PHENYLCARBAMATE); BENALAXYL; DINICONAZOLE; ENILCONAZOLE; FLUTRIAFOL; FUNGICIDE; HEXACONAZOLE; HEXANE; METALAXYL; MYCLOBUTANIL; PACLOBUTRAZOL; PYRROLE DERIVATIVE; SILICON DIOXIDE; TEBUCONAZOLE; TRIADIMEFON; UNCLASSIFIED DRUG; UNICONAZOLE; VINCLOZOLIN;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL STRUCTURE; CHIRALITY; CIRCULAR DICHROISM; ENANTIOMER; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; PRIORITY JOURNAL; STEREOCHEMISTRY;

AMYLOPECTIN; CHROMATOGRAPHY, HIGH PRESSURE LIQUID; FUNGICIDES, INDUSTRIAL; STEREOISOMERISM;

EID: 33846296975     PISSN: 08990042     EISSN: 1520636X     Source Type: Journal    
DOI: 10.1002/chir.20353     Document Type: Article

References (16)

1. Maier NM, Franco P, Lindner W. Separation of enantiomers: needs, challenges, perspectives. J Chromatogr A 2001;906:3-33.
2. Williams A. Opportunities for chiral agrochemicals. Pestic Sci 1996;46: 3-9.
3. Monkiedje A, Spiteller M, Bester K. Degradation of Racemic and enantiopure metalaxyl in tropical and temperate soils. Environ Sci Technol 2003;37:707-712.
4. Buerge I, Thomaspoiger , Muller M. Enantioselective degradation of metalaxyl in soils: Chiral preference changes with soil pH. Environ Sci Technol 2003;37:2668-2674.
5. Muller MD, Buser HR. Environmental behavior of acetamide pesticide stereoisomers, Part 2: stereo- and enantioselective degradation in sewage sludge and soil. Environ Sci Technol 1995;29:2031-2037.
6. Buser HR, Muller MD, Poiger T, Balmer ME. Environmental behaviour of the chiral acetamide pesticide metalaxyl: enantioselective degradation and chiral stability in soil. Environ Sci Technol 2002;36:221-226.
7. Zadra C, Marucchini C, Zazzerini A. Behavior of metalaxyl and its pure R-enantiomer in sunflower plants. J Agr Food Chem 2002;50: 5373-5377.
8. Marucchini C, Zadra C. Stereoselective degradation of metalaxyl and metalaxyl-M in soil and sunflower plants. Chirality 2002;14:32-38.
9. Qiu J, Wang QX, Wang P, Jia GF, Li JL, Zhou ZQ. Enantioselective degradation kinetics of metalaxyl in rabbits. Pestic Biochem Phys 2005; 83:1-8.
10. Ali I, Aboul-Enein HY. Chiral pollutants: distribution, toxicity and analysis by chromatography and capillary electrophoresis. Chichester: Wiley; 2004. p 13.
11. Yashima E. Polysaccharide-based chiral stationary phases for high-performance liquid Chromatographic enantioseparation. J Chromatogr A2001;906:105-125.
12. Okamoto Y, Kaida Y. Resolution by high performance liquid chromatography using polysaccharide carbamates and benzoates as chiral stationary phases. J Chromatgr A 1994;666:403-419.
13. Zhou ZQ, Wang P, Jiang SR, Wang M, Yang L. The Preparation of polysaccharide-based chiral stationary phases and the direct separation of five chiral pesticides and related itermediates. J Li Qchromatogr Rel Tech 2003;26:2873-2880.
14. Okamoto Y, Kawashima M, Hatada K. Chromatographic resolution. J Chromatogr 1986;363:173-186.
15. Aboul-Enein HY, Ali I. Studies on the effect of alcohols on the chiral discrimination mechanisms of amylose stationary phase on the enantioseparation of nebivolol by HPLC. J Biochem Bioph Meth 2001; 48:175-188.
16. Bobbitt DR, Linder SW. Recent advances in chiral detection for high performance liquid chromatography. Trends Analyt Chem 2001;20(3): 111-123.