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Volumn , Issue 1, 2007, Pages 39-43

The transient titanocene(II): Direct synthesis from solvated titanium(II) chloride and cyclopentadienylsodium and ensuing interception with diphenylacetylene as 1,1-bis(cyclopentadienyl)-2,3,4,5- tetraphenyltitanacyclopentadiene

Author keywords

1,1 Bis(cyclopentadienyl) titanacyclopentadienes; 1,1 Bis(cyclopentadienyl)titanacyclopropenes; Epititanation; Titanocene(II); Wilkinson metallocene synthesis

Indexed keywords

HYDRIDES; LIGHTING; LITHIUM COMPOUNDS; ORGANOMETALLICS; SODIUM CHLORIDE; TITANIUM COMPOUNDS;

EID: 33846295532     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200600766     Document Type: Article
Times cited : (8)

References (31)
  • 4
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    • A comprehensive survey of the various syntheses of cyclopentadienyl-metal compounds reported in the scientific and patent literature prior to 1963 has appeared: J. M. Birmingham, Adv. Organomet. Chem. 1964, 2, 365
    • A comprehensive survey of the various syntheses of cyclopentadienyl-metal compounds reported in the scientific and patent literature prior to 1963 has appeared: J. M. Birmingham, Adv. Organomet. Chem. 1964, 2, 365.
  • 7
    • 85163243373 scopus 로고    scopus 로고
    • A detailed recounting of the Titanocene Saga has appeared in two reviews: a An empirical summary of the several experimental efforts: P. C. Wailes, R. S. P. Coutts, H. Weigold, Organometallic Chemistry of Titanium, Zirconium, and Hafnium, Academic Press, New York, 1974, pp. 228-239;
    • A detailed recounting of the "Titanocene Saga" has appeared in two reviews: a) An empirical summary of the several experimental efforts: P. C. Wailes, R. S. P. Coutts, H. Weigold, Organometallic Chemistry of Titanium, Zirconium, and Hafnium, Academic Press, New York, 1974, pp. 228-239;
  • 8
    • 85163246550 scopus 로고    scopus 로고
    • A more recent review of experimental observations with considerable structure interpretation: M. Bottrill, P. D. Gavens, J. McMeeking, in: Comprehensive Organometallic Chemistry (Eds.: G. Wilkinson, F. G. A. Stone, E. W. Abel), Pergamon Press, Oxford, 1982, pp. 314-320.
    • b) A more recent review of experimental observations with considerable structure interpretation: M. Bottrill, P. D. Gavens, J. McMeeking, in: Comprehensive Organometallic Chemistry (Eds.: G. Wilkinson, F. G. A. Stone, E. W. Abel), Pergamon Press, Oxford, 1982, pp. 314-320.
  • 10
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    • Doctoral Thesis, Harvard University
    • b) J. M. Birmingham, Doctoral Thesis, Harvard University, 1955.
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  • 13
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    • 4 bridging ring π-bonded to the Ti on the left and σ-bonded to the Ti on the right).
    • 4 bridging ring π-bonded to the Ti on the left and σ-bonded to the Ti on the right).
  • 21
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  • 27
    • 85163242742 scopus 로고    scopus 로고
    • For a leading reference to other recent chemical trapping methods for intercepting assumed titanocene(II) as an intermediate in other reactions of titanocene(IV) derivatives: N. Mézailles, N. Avarvari, D. Bourissou, F. Mathey, P. LeFloch, Organometallics 1998, 17, 2677-2679
    • For a leading reference to other recent chemical trapping methods for intercepting assumed titanocene(II) as an intermediate in other reactions of titanocene(IV) derivatives: N. Mézailles, N. Avarvari, D. Bourissou, F. Mathey, P. LeFloch, Organometallics 1998, 17, 2677-2679.
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    • R. B. King, in: Organometallic Syntheses (Eds.: J. J. Eisch, R. B. King), vol. 1, Academic Press, New York, 1965, pp. 64-66.
    • (1965) Organometallic Syntheses , vol.1 , pp. 64-66
    • King, R.B.1
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    • Eds, J. J. Eisch, R. B. King, Academic Press, New York
    • J. J. Eisch, in: Organometallic Syntheses (Eds.: J. J. Eisch, R. B. King), vol. 2, Academic Press, New York, 1981, pp. 3-37.
    • (1981) Organometallic Syntheses , vol.2 , pp. 3-37
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    • Boleslawski, M.P.1    Eisch, J.J.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.