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We observed that phenyl sulfide 6 hardly reacted with hydroxylamine-O-sulfonic acid (HAS) even at room temperature, while Appel reported that dimethylsulfide and diethylsulfide reacted with HAS to give the corresponding S-aminosulfonium salts. See: Appel, R.; Buchiner, W. Chem. Ber. 1962, 95, 849-854.
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We observed that phenyl sulfide 6 hardly reacted with hydroxylamine-O-sulfonic acid (HAS) even at room temperature, while Appel reported that dimethylsulfide and diethylsulfide reacted with HAS to give the corresponding S-aminosulfonium salts. See: Appel, R.; Buchiner, W. Chem. Ber. 1962, 95, 849-854.
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