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X-ray data for 1 and 2 are collected using Mo Kα (λ, 0.71073 Å) radiation on a SMART APEX diffractometer equipped with a CCD area detector at 100 K. Crystals are selected from the mother liquor and immersed in Partone oil and then mounted. Data collection, data reduction, and structure solution/refinement are carried out using the software package of SMART APEX. Graphics are generated using PLATON8a and MERCURY 1.3.8b Both the structures are solved by direct methods and refined in a routine manner. In the case of 1, one amino nitrogen of the cryptand moiety and the nitro oxygen of the picrate are disordered at two positions, and their occupancy factor is defined using the FVAR command of the SHELXL-97 program. Both of these disorderd atoms are refined only isotropically, whereas the rest of the non-hydrogen atoms in 1 and all the non-hydrogen atoms in 2 are treated anisotropically. Whenever possible, the hydro
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See the Supporting Information.
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