RAFT emulsions, microemulsions and dispersions

Surface Coatings International Part B: Coatings Transactions

Volumn 89, Issue 4, 2006, Pages 293-304

  Lubnin, A ^a   Lenhard, S ^a   Lai, J ^a  

^a LUBRIZOL CORPORATION   (United States)

Author keywords

Controlled free radical polymerisation; Dithiocarbamate; Emulsion polymerisation; Living polymerisation; Microemulsions; RAFT polymerisation; Solution dispersion process; Telechelic polymers

Indexed keywords

COMPOSITION; DIFFUSION; DISPERSIONS; EMULSION POLYMERIZATION; LIVING POLYMERIZATION; SOLUTIONS;

CONTROLLED FREE RADICAL POLYMERIZATION; RAFT POLYMERIZATION; SOLUTION DISPERSION PROCESS; TELECHELIC POLYMERS;

MICROEMULSIONS;

EID: 33846116285     PISSN: 14764865     EISSN: 17420261     Source Type: Journal    
DOI: 10.1007/BF02765581     Document Type: Article

References (39)

1. Ziegler K, 'The importance of alkali metallo-organic compounds for synthesis', Angew Chem, 49, 499-502, 1936
2. Szwarc M, 'Living'" polymers', Nature, 178, 1168-9, 1956
3. Szwarc M, M Levy and R Milkovich. 'Polymerisation initiated by electron transfer to monomer. Anew method of formation of block polymers', J Am Chem Soc, 78, 2656-7, 1956
4. Doi Y, S Ueki and T Keii, '"Living" coordination polymerisation of propene initiated by the soluble V(acac)3-Al(C2H5)2Cl system', Macromolecules, 12, 814-9, 1979
5. Anderson B C, G D Andrews, P Arthur. H W Jacobson Jr, L R Melby, A J Playtis and W H Sharkey, Anionic polymerisation of methacrylates. Novel functional polymers and copolymers', Macromolecules, 14, 1599-601, 1981
6. Otsu T and M Yoshida, 'Role of initiator-transfer agent-terminator (iniferter) in radical polymerisations: polymer design by organic disulphides as iniferters", Makromol Chem, Rapid Commun, 3, 127-32, 1982
7. Otsu T, M Yoshida and T Tazaki, 'A model for living radical polymerisation', Makromol Chem, Rapid Commun, 3, 133-40, 1982
8. Webster W, W R Hertier, D Y Sogah, W B Farnham and T V RajanBabu, 'Group-transfer polymerisation. 1. A new concept for addition polymerisation with organosilicon initiators', J Amer Chem, Soc, 105, 5706-8, 1983
9. Miyamoto M, M Sawamoto and T Higashimura, 'Living polymerisation of isobutyl vinyl ether with hydrogen iodide/iodine initiating system", Macromolecules, 18, 265-8, 1984
10. Solomon D H, E Rizzardo and P Cacioli, US Patent 4 581 429, 1986
11. Faust R and J P Kennedy, 'living carbocationic polymerization. III. Demonstration of the living polymerisation of isobutylene', Polym Bull, 15, 317-23, 1986
12. Gilliom L R and R H Grubbs, Titanacyclobutanes derived from strained, cyclic olefins: the living polymerisation of norbornene", J Am Chem Soc, 108, 733-42, 1986
13. Georges M K, R P N Veregin, P M Kazmaier and G K Hamer, 'Narrow molecular weight resins by a freeradical polymerisation process', Macromolecules, 26, 2987-8, 1993
14. Wang J S and K Matyjaszewski, 'Controlled"living" radical polymerisation. Atom transfer radical polymerisation in the presence of transition-metal complexes', J Am Chem Soc, 117, 5614-5, 1995
15. Chiefari J, Y K Chong, F Ercole, J Krstina, J Jeffery, T P T Le, R T A Mayadunne, G F Meijs, C L Moad, G Moad, E Rizzardo and S H Thang, 'Living free-radical polymerisation by reversible addition-fragmentation chain transfer: The RAFT process" Macromolecules, 31, 5559-62. 1998
16. Charmot D, P Corpart, H Adam, S Z Zard, T Biadatti and G Bouhadir, 'Controlled radical polymerisation in dispersed media' Macmmol Symp. 150, 23-32, 2000
17. Uzulina, S Kanagasabapathy and J Claverie, 'Reversible addition fragmentation transfer (RAFT) polymerisation in emulsion', Macromol Symp, 150, 33-8, 2000
18. Matyjaszewski, J Qiu, D A Shipp and S G Gaynor, 'Controlled/ "living" radical polymerisation applied to water-borne systems', Macromol Symp, 155, 15-29, 2000
19. Rizzardo E, J Chiefari, B Y K Chong, F Ercole, J Krstina, J Jeffrey, T P T Le. R T A Mayadunne, G F Meijs. C L Moad, G Moad and S H Thang. 'Tailored polymers by free radical processes', Macromol Symp, 143, 291-307, 1999
20. Ferguson C J, R J Hughes, B T T Pham, B S Hawkett, R G Gilbert, A K Sereli and C H Such, 'Effective ab initio emulsion polymerisation under RAFT control', Macromolecules, 35 9243-5, 2002
21. Prescott S W, M J Ballard, E Rizzardo and R G Gilbert, 'Successful use of RAFT techniques in seeded emulsion polymerisation of styrene: living character, RAFT agent transport, and rate of polymerisation", Macromolecules, 35, (14), 5417-25, 2002
22. de Brouwer H, J G Tsavalas, F J Schrok and M J Monteiro, 'Living radical polymerisation in mini-emulsion using reversible addition-fragmentation chain transfer', Macromolecules, 33, 9239-46 2000
23. Senyek M L, J J Kulig and D K Parker, U S Patent 6 369 158, 2002
24. Moad G, E Rizzardo and S H Thang, 'Living radical polymerisation by the RAFT process', Aust J Chem, 58, 379-410 2005
25. Perrier S and P Takolpuckdee, 'Macromolecular design via reversible addition-fragmentation chain transfer (RAFT)/xanthates (MADIX) polymerization', J Polym Sci: Polym Chem, 43, 5347-93, 2005
26. Lai T, D Filla and R Shea, 'Functional polymers from novel carboxyl-terminated trithiocarbonates as highly efficient RAFT agents', Macromolecules, 35, 6754-6, 2000
27. Lai J T, US Patent Application No 10/278335, 2002
28. Lai J T US Patent 6 596 899, 2003
29. Lai J T, and R Hsu, US Patent Application No 11/206393, 2004
30. Lai JT AD Pajerski and R Shea, US Patent Application No 10/913972, 2004
31. Lai J T and R Shea, 'Controlled radical polymerisation by carboxyl-terminated dithiocarbamates and xanthates", J Polyrn Sci: Polym Chem, 44, 4298-316, 2006
32. Laughlin R G, The Aqueous Phase Behaviour of Surfactants, 271, Academic Press. 1994. ISBN 0 12 4377602
33. Monteiro M J, M M Adamy, B J Leeuwen, AM van Herk and M Destarac, 'A "living" radical ab initio emulsion polymerisation of styrene using a fluorinated xanthate agent', Macromolecules, 38, 1538-41, 2005
34. Daniels W E, 'Vinyl acetate polymers', Encyclopedia of Polymer Science and Engineering, (eds) H F Mark, N M Bikales, C G Overherger, G Menges and J I Kroschwitz, 17. 393-425, 1989, ISBN 0 471 81181 5
35. Mayo F R, C Walling, F M Lewis and W F Hulse, 'Copolymerisation. V. Some copolymerisations of vinyl acetate', J Amer Chem Sci, 70, 1523-5, 1948
36. Dunn A S, 'Polymerisation in micelles and microemulsions', Comprehensive Polym er Science, (eds) G Allen and J C Bevington, 4, 219-24, 1989, ISBN 0 08 036208 7
37. Smith D H, 'Microemulsions', Kirk-Othmer Bicyclopedia of Chemical Technology, (4th edition), Supplementary volume, 299-314, 1998, ISBN 0471 52696 7
38. Hermanson KD, S Liu and E W Kaler, 'RAFT polymerization in microemulsions'. Proceedings from 226th ACS National Meeting, Paper 293, New York, USA, September 2003
39. McLeary J B, M P Tonge, D De Wet Roos, R D Sanderson and B Klumperman, 'Controlled, radical reversible addition-fragmentation chain-transfer polymerisation in high-surfactant-concentration ionic miniemulsions", J Polymer Sci: Polymer Chem, 42, 960-74, 2004