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33846105551
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Compound 2a: mp 51-53°C. 1H NMR (CDCl3) δ 2.10 (s, 3H, SMe, 2.85 (dd, 1H, J, 5.6, 14.0 Hz, CH2, 3.05 (dd, 1H, J, 7.6, 14.0 Hz, CH2, 5.56 (dd, 1H, J, 5.6, 7.6 Hz, CH, 7.09-7.55 (m, 8H, Ar, 8.18 (dd, 1H, J, 1.2, 8.4Hz, Ar, 13CNMR (CDCl3) δ 16.86 (SMe, 40.49 (CH2, 75.68 (CH, 124.74, 125.30, 126.60, 128.37, 128.51, 129.51, 131.72, 132.74, 139.71 (Ar, 156.56 (C=O, Compound 4: colorless oil. 1HNMR (CDCl 3) δ 1.72 (s, 3H, SMe, 2.37 (s, 3H, Me, 3.90 (dd, 1H, J, 9.6, 12.8 Hz, CH2, 4.18-4.25 (m, 2H, CH2, CH, 7.03 (t, 1H, J, 7.6 Hz, Ar, 7.20-7.25 (m, 5H, Ar, 7.65-7.73 (m, 3H, Ar, 13CNMR (CDCl3) δ 11.89 (SMe, 21.76 (Me, 43.65 (CH, 56.79 (CH2, 114.78, 124.23, 125.77, 127.59, 129.33, 129.94, 130.93, 133.96, 142.20, 144.55 Ar
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2), 114.78, 124.23, 125.77, 127.59, 129.33, 129.94, 130.93, 133.96, 142.20, 144.55 (Ar).
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17
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0000896854
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