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Volumn 35, Issue 10, 2006, Pages 1178-1179

Immobilization of a binuclear ruthenium(III) complex on a gold (111) surface: Observations of proton-coupled electron transfer and electrochemical durability in aqueous media

(5) Uehara, Hiromitsu a Abe, Masaaki b Hisaeda, Yoshio b Uosaki, Kohei a Sasaki, Yoichi a

a HOKKAIDO UNIVERSITY (Japan)

b KYUSHU UNIVERSITY (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33846079312 PISSN: 03667022 EISSN: None Source Type: Journal
DOI: 10.1246/cl.2006.1178 Document Type: Article

Times cited : (14)

References (13)

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9
- 33846077229
- This complex has also been prepared by A. Nagasawa and his co-workers: H. Sawamoto, Master Thesis, Saitama University, 2000. A detailed synthetic work-up and characterization data of the complex will be described in a separate full paper
- This complex has also been prepared by A. Nagasawa and his co-workers: H. Sawamoto, Master Thesis, Saitama University, 2000. A detailed synthetic work-up and characterization data of the complex will be described in a separate full paper.

10
- 33846040887
- 1-SAM was prepared by immersing a flame-annealed Au(111) electrode (S, 0.16 cm2; roughness factor, 1.1) into a ethanolic solution of, 4-Py)CH2NHC(O)(CH2)10S}2 (50 μM) for 12h at 25 °C. The surface coverage was 1.1 × 10 -9 mol cm-2 on the basis of reductive desorption experiment (the reduction peak potential, 1.1 V vs. Ag/AgCl in 0.5 mol dm -3 KOH aq
- -3 KOH (aq).

11
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12
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- -), respectively) requires further examination, since, in some reported cases, the pH dependency is influenced by, for example, the interfacial proton concentration and the distance between the redox center and the electrode surface.
- -), respectively) requires further examination, since, in some reported cases, the pH dependency is influenced by, for example, the interfacial proton concentration and the distance between the redox center and the electrode surface.

13
- 33846056668
- Details of the PCET reactions in homogeneous solutions will be reported separately: A. Kikuchi, T. Fukumoto, K. Umakoshi, Y. Sasaki, A. Ichimura, to be submitted.
- Details of the PCET reactions in homogeneous solutions will be reported separately: A. Kikuchi, T. Fukumoto, K. Umakoshi, Y. Sasaki, A. Ichimura, to be submitted.

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