(Fe,Mn)-Mg interdiffusion in natural diopside: Effect of pO2

European Journal of Mineralogy

Volumn 18, Issue 6, 2006, Pages 705-718

  Dimanov, Alexandre ^a,b   Wiedenbeck, Michael ^a  

^a GFZ GERMAN RESEARCH CENTRE FOR GEOSCIENCES   (Germany)

^b ECOLE POLYTECHNIQUE   (France)

Author keywords

Cation vacancies; Diopside; Divalent cation diffusion; Oxygen fugacity; SIMS

Indexed keywords

ACTIVATION ENERGY; BINARY ALLOYS; DEPTH PROFILING; IRON ALLOYS; MANGANESE ALLOYS; OXYGEN; OXYGEN VACANCIES; POINT DEFECTS; POSITIVE IONS; SECONDARY ION MASS SPECTROMETRY;

CATION VACANCIES; DIFFUSION MECHANISMS; DIOPSIDE; DIVALENT CATION; INTER-DIFFUSION COEFFICIENTS; OXYGEN FUGACITY; RF PLASMA SPUTTERING; VACANCY MECHANISMS;

MAGNESIUM ALLOYS;

CRYSTAL CHEMISTRY; DIOPSIDE; FUGACITY; IRON; MANGANESE; MASS SPECTROMETRY;

EID: 33846000321     PISSN: 09351221     EISSN: None     Source Type: Journal    
DOI: 10.1127/0935-1221/2006/0018-0705     Document Type: Article

References (43)

1. Abart, R., Kunze, K., Milke, R., Sperb, R., Heinrich, W. (2004): Silicon and oxygen self diffusion in enstatite polycrystals: the Milke et al. (2001) rim growth experiments revisited. Contrib. Mineral. Petrol., 147, 633-646.
2. Adda, Y. & Philibert, J. (1996): La Diffusion dans les Solides. Bibliothèque des Sciences et Techniques Nucléaires, INSTN-PUF, Paris, 1268 pp.
3. Azough, F. & Freer, R. (2000): Iron Diffusion in Single-Crystal Diopside. Phys. Chem. Miner., 27, 732-740.
4. Bai, Q., Wang., Z.C., Kohlstedt, D.L. (1995): Manganese Olivine I: Electrical Conductivity. Phys. Chem. Miner., 22, 489-503.
5. Bai, Q., Wang., Z.C., Kohlstedt, D.L. (1998): Manganese Olivine II: Point Defects Relaxation. Phys. Chem. Miner., 25, 122-129.
6. Béjina, F. & Jaoul, O. (1996): Silicon self-diffusion in quartz and diopside measured by nuclear micro-analysis methods. Phys. Earth. Planet. Inter., 97, 145-162.
7. Brady, J. B. (1975): Reference frames and diffusion coefficients. Am. J. Sci., 275, 954-983.
8. Brady, J. B. (1995): Diffusion data for silicate minerals, glasses, and liquids. in "Mineral Physics and Crystallography: A Handbook of Physical Constants", Ahrens, T.H., ed. AGU Reference Shelf 2, American Geophysical Union, Washington, D.C., 269-290.
9. Brady, J.B. & McCallister, R.H. (1983): Diffusion data for clinopyroxenes from homogenization and self-diffusion experiments. Am. Miner., 68, 95-105.
10. Buenning, D.K. & Buseck, P.R. (1973): Fe-Mg lattice diffusion in olivine. J. Geophys. Res., 78, 6852-6862.
11. Cherniak, D.J. (2001): Pb diffusion in Cr diopside, augite and enstatite, and considerations of the dependence of cation diffusion in pyroxene on oxygen fugacity. Chem. Geol., 177, 381-397.
12. Dimanov, A. (1995): Autodiffusion du calcium dans le diopside monocristallin. Thesis. Univ. Paris XI, Orsay.
13. Dimanov, A. & Jaoul, O. (1998): Calcium self-diffusion in diopside at high temperature: implications for transport properties. Phys. Chem. Miner., 26, 116-127.
14. Dimanov, A. & Sautter, V. (2000): "Average" interdiffusion of (Fe, Mn)-Mg in natural diopside. Eur. J. Mineral., 12, 749-760.
15. Dimanov, A., Jaoul, O., Sautter, V. (1996): Calcium self-diffusion in natural diopside single crystals. Geochim. Cosmochim. Acta, 60, 4095-4106.
16. Dodson, M.H. (1973): Closure temperature in cooling geochronological and petrological systems. Contrib. Mineral. Petrol., 40, 259-274.
17. Dohmen, R., Becker, H.-W., Meißner, E., Etzel, T., Chakraborty, S. (2002): Production of silicate thin films using pulsed laser deposition (PLD) and applications to studies in mineral kinetics. Eur. J. Mineral., 14, 1155-1168.
18. Doukhan, N., Doukhan, J.C., Ingrin, J., Jaoul, O., Raterron, P. (1993): Early partial melting in pyroxenes. Am. Miner., 78, 1247-1257.
19. Elphick, S.C., Ganguly, J., Loomis, T.P. (1985): Experimental determination of cation diffusivities in aluminosilicate garnets. I. Experimental methods and interdiffusion data. Contrib. Mineral. Petrol., 90, 36-44.
20. Fernandez-Moran, H., Ohtsuki, M., Hibino, H. (1971): Correlated electron microscopy and diffraction of lunar clinopyroxenes from Apollo 12 samples. Proc. Second Lunar Sci. Conf., 1, 109-116.
21. Freer, R. & Edwards, A. (1999): An experimental study of Ca(Fe,Mg) interdiffusion in silicate garnets. Contrib. Mineral. Petrol., 134, 370-379.
22. 3+ substitutions in calcium Tschermak's pyroxene. Contrib. Mineral. Petrol., 92, 530-535.
23. 4 (III). Phys. Chem. Miner, 11, 161-166.
24. 2. Eur. J. Mineral., 4, 105-114.
25. Houlier, B., Jaoul, O., Abel., F., Lieberman, R.C. (1988): Oxygen and silicon self-diffusion in natural olivine at T = 1300 °C. Phys. Earth Planet. Inter., 50, 240-250.
26. Houlier, B., Cheraghmakani, M., Jaoul, O. (1990): Silicon diffusion in San Carlos olivine. Phys. Earth Planet. Inter., 62, 329-340.
27. Huebner, J.S. & Voigt, D.E. (1988): Electrical conductivity of diopside: evidence of oxygen vacancies. Am. Miner., 73, 1235-1254.
28. 6. Contrib. Mineral. Petrol., 81, 113-118.
29. 2 precipitation. J. Geophys. Res., 99, 9423-9439.
30. Kröger, F.A. & Vink, H.J. (1956): Relations between the concentrations of imperfections in cristalline solids. in "Solid State Physics Advances in Research and Applications". Seitz, F. & Turnbull, D., eds. vol. 3, 307-435.
31. Lasaga, A.C. (1979): Multicomponent exchange and diffusion in silicates. Geothim. Cosmochim. Acta, 43, 455-469.
32. Lasaga, A.C. (1983): Geospeedometry: An extension of geothermometry. in "Advances in Physical Geochemistry; Kinetics and Equilibrium in Mineral Reactions", Saxena, S.K., ed. Springer, vol. 3, 81-114.
33. 3-d. Sol. State Ion., 154-155, 189-193.
34. Milke, R., Wiedenbeck, M., Heinrich, W. (2001): Grain boundary diffusion fusion of Si, Mg and O in enstatite rims: a SIMS study using isotopically doped reactants. Contrib. Mineral. Petrol., 142, 15-26.
35. Nakamura, A. & Schmalzried, H. (1983): On the nonstoichiometry and point defects of olivine. Phys. Chem. Miner. 10, 27-37.
36. Nitsan, U. (1974): Stability field of olivine with respect to oxidation and reduction. J. Geophys. Res., 79, 706-711.
37. Raterron, P. & Jaoul, O. (1991): High-temperature deformation of diopside single crystal, 1, Mechanical data. J. Geophys. Res., 96, 14277-14286.
38. Ross, M., Huebner, J.S., Dowty, E. (1973): Delineation of the one-atmosphere augite-pigeonite miscibility gap for pyroxenes from lunar basalt 12021. Am. Miner, 58, 619-635.
39. 28Si nuclear reaction: preliminary results. Earth, Planet. Sci. Lett. 89, 109-114.
40. Sautter, V., Duchêne, S., Marques, F.O. (2001): New analytical and numerical geospeedometers tested on garnet pyroxenites from Braganca Nappe Complex (NE-Portugal). Tectonophysics 342, 39-59.
41. Schwandt, G.S., Cygan, R.T., Westrich, H.R. (1993): A thin film approach for producing mineral diffusion couples. Pure Appl. Geophys., 141, 631-642.
42. Tannhauser, D.S. (1956): Concerning a systematic error in measuring diffusion constants. J. Appl. Phys., 27, 662.
43. van Orman, J.A., Grove, T.L., Shimizu, N. (2001): Rare earth element diffusion in diopside: influence of temperature, pressure, and ionic radius, and an elastic model for diffusion in silicates. Contrib. Mineral. Petrol., 141, 687-703.