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Volumn 207, Issue 24, 2006, Pages 2257-2279

Metallocene catalysts for 1-butene polymerization

Author keywords

Isotactic; Metallocene catalysts; NMR; Poly(1 butene); Thermal properties

Indexed keywords

BUTENES; CATALYST SELECTIVITY; CRYSTALLIZATION; MICROSTRUCTURE; NUCLEAR MAGNETIC RESONANCE; ORGANOMETALLICS; POLYBUTENES; POLYMERIZATION; SUBSTITUTION REACTIONS; THERMODYNAMIC PROPERTIES;

EID: 33845994015     PISSN: 10221352     EISSN: 15213935     Source Type: Journal    
DOI: 10.1002/macp.200600307     Document Type: Article
Times cited : (37)

References (72)
  • 4
    • 33846003024 scopus 로고
    • Studies in Polymer Science 7, Elsevier, Amsterdam, Chapter 11, p
    • [2c] S. Van der Ven, "Polypropylene and other polyolefins", Studies in Polymer Science 7, Elsevier, Amsterdam 1990; Chapter 11, p. 494 ff.
    • (1990) Polypropylene and other polyolefins
    • Van der Ven, S.1
  • 6
    • 33846006091 scopus 로고    scopus 로고
    • Search for PB-1 in www.basell.com.
    • Search for PB-1 in www.basell.com.
  • 7
    • 33845978273 scopus 로고    scopus 로고
    • N. Arich de Finetti, P. Baita, D. Bigiavi, M. Covezzi, G. Mei, M. S. Tonti, A new manufacturing technology for the production of polybutene-1 presented at Workshop Neue Materialentwicklungen und Märkte bei Polyolefinen, 26 June 2002 Würzburg.
    • N. Arich de Finetti, P. Baita, D. Bigiavi, M. Covezzi, G. Mei, M. S. Tonti, "A new manufacturing technology for the production of polybutene-1" presented at Workshop "Neue Materialentwicklungen und Märkte bei Polyolefinen", 26 June 2002 Würzburg.
  • 8
    • 33845994634 scopus 로고    scopus 로고
    • See for example: WO 099883 2003, Basell, invs, G. Vitale, G. Morini, G. Cecchin
    • See for example: WO 099883 (2003), Basell, invs.: G. Vitale, G. Morini, G. Cecchin.
  • 12
    • 33846017555 scopus 로고
    • Catalysis in Polymer Synthesis
    • E. J. Vandenberg, J. C. Salamone, Eds, American Chemical Society, Washington, DC
    • [9b] W. Kaminsky, S. Niedoba, N. Möller-Lindenhof, O. Rabe, "Catalysis in Polymer Synthesis", E. J. Vandenberg, J. C. Salamone, Eds.; ACS Symposium Series 496; American Chemical Society, Washington, DC 1992; p. 63.
    • (1992) ACS Symposium Series , vol.496 , pp. 63
    • Kaminsky, W.1    Niedoba, S.2    Möller-Lindenhof, N.3    Rabe, O.4
  • 13
    • 33845997334 scopus 로고    scopus 로고
    • Eur 604908 (1994), Himont, invs.: L. Resconi, R. L. Jones;
    • [10a] Eur 604908 (1994), Himont, invs.: L. Resconi, R. L. Jones;
  • 16
    • 33845976235 scopus 로고    scopus 로고
    • Eur 387609 (1990, US 5391672 1995, Himont, invs, E. Albizzati, L. Resconi, A. Zambelli;
    • [11a] Eur 387609 (1990), US 5391672 (1995), Himont, invs.: E. Albizzati, L. Resconi, A. Zambelli;
  • 31
    • 33845996835 scopus 로고    scopus 로고
    • Eur 1260525 (2002), Idemitsu Petrochemical Co, invs.: Y. Minami, M. Kanamaru, K. Kakigami, H. Funabashi.
    • Eur 1260525 (2002), Idemitsu Petrochemical Co, invs.: Y. Minami, M. Kanamaru, K. Kakigami, H. Funabashi.
  • 32
    • 33845970120 scopus 로고    scopus 로고
    • WO 100908 2002, Basell, invs, L. Resconi;
    • [21a] WO 100908 (2002), Basell, invs.: L. Resconi;
  • 33
    • 33846005042 scopus 로고    scopus 로고
    • WO 100909 2002, Basell, invs, L. Resconi;
    • [21b] WO 100909 (2002), Basell, invs.: L. Resconi;
  • 34
    • 33845999483 scopus 로고    scopus 로고
    • WO 042258 2003, Basell, invs, L. Resconi;
    • [21c] WO 042258 (2003), Basell, invs.: L. Resconi;
  • 35
    • 33846022612 scopus 로고    scopus 로고
    • WO 050724 2004, Basell, invs, L. Resconi, A. Cascio Ingurgito;
    • [21d] WO 050724 (2004), Basell, invs.: L. Resconi, A. Cascio Ingurgito;
  • 36
    • 33846031357 scopus 로고    scopus 로고
    • WO 050713 2004, Basell, invs, L. Resconi, A. Pelliconi, E. Garagnani;
    • [21e] WO 050713 (2004), Basell, invs.: L. Resconi, A. Pelliconi, E. Garagnani;
  • 37
    • 33845965598 scopus 로고    scopus 로고
    • WO 099269 2004, Basell, invs, L. Resconi
    • [2If] WO 099269 (2004), Basell, invs.: L. Resconi.
  • 41
    • 33845986956 scopus 로고    scopus 로고
    • WO 44318 2001, Basell, invs, J. A. Ewen, M. J. Elder, R. L. Jones
    • [24b] WO 44318 (2001), Basell, invs.: J. A. Ewen, M. J. Elder, R. L. Jones.
  • 44
    • 33846003023 scopus 로고    scopus 로고
    • WO 47939 2001, Basell, invs, I. E. Nifant'ev, S. Guidotti, L. Resconi, I. P. Laishevtsev
    • [26b] WO 47939 (2001), Basell, invs.: I. E. Nifant'ev, S. Guidotti, L. Resconi, I. P. Laishevtsev.
  • 47
    • 33846000538 scopus 로고    scopus 로고
    • WO 00706 2003, Basell, invs, C. Fritze, L. Resconi, J. Schulte, S. Guidotti
    • WO 00706 (2003), Basell, invs.: C. Fritze, L. Resconi, J. Schulte, S. Guidotti.
  • 54
    • 0343440567 scopus 로고
    • Catalysis in Polymer Synthesis
    • E. J. Vandenberg, J. C. Salamone, Eds, American Chemical Society, Washington DC
    • M. Kioka, A. Mizuno, T. Tsutsui, N. Kashiwa, "Catalysis in Polymer Synthesis", E. J. Vandenberg, J. C. Salamone, Eds., ACS Symposium Series Vol. 496; American Chemical Society, Washington DC 1992, p. 72.
    • (1992) ACS Symposium Series , vol.496 , pp. 72
    • Kioka, M.1    Mizuno, A.2    Tsutsui, T.3    Kashiwa, N.4
  • 58
    • 0032492573 scopus 로고    scopus 로고
    • This latter scenario has been suggested by one of the reviewers, who also suggested the use of 13C-labelled ethylene in order to reveal the possible presence of very low (<0.1, amounts of regioerrors, following the method of Busico and coworkers (V. Busico, R. Cipullo, G. Talarico, L. Caporaso, Macromolecules 1998, 31, 2387, We plan to investigate this aspect for both propylene and 1-butene polymerizations in the future. However, a low-molecularweight PB sample prepared at 1 bar butene pressure with 17/ MAO (average degree of polymerization of about 4000) shows in the olefinic region of its 1H NMR spectrum only vinylidene end groups, and no internal double bonds that would be generated by chain transfer to monomer after a secondary insertion
    • 1H NMR spectrum only vinylidene end groups, and no internal double bonds (that would be generated by chain transfer to monomer after a secondary insertion).
  • 60
    • 33845994633 scopus 로고    scopus 로고
    • The molecular origin of this effect is currently being investigated by QM/MM molecular modeling. P. Mercandelli, L. Resconi, A. Sironi, work in progress.
    • The molecular origin of this effect is currently being investigated by QM/MM molecular modeling. P. Mercandelli, L. Resconi, A. Sironi, work in progress.
  • 70
    • 0011395781 scopus 로고
    • G. Fink, R. Mülhaupt, H.-H. Brintzinger Eds, Springer, Berlin
    • J. A. Ewen, M. J. Elder "Ziegler Catalysts", G. Fink, R. Mülhaupt, H.-H. Brintzinger Eds., Springer, Berlin 1995, p. 99.
    • (1995) Ziegler Catalysts , pp. 99
    • Ewen, J.A.1    Elder, M.J.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.