Determination of the interconversion energy barrier of 2,3-pentadienedioic acid enantiomers by HPLC. 2. On-column inteconversion

Journal of Separation Science

Volumn 29, Issue 17, 2006, Pages 2594-2599

  Mydlová, Janka ^a   Fedurcová, Andrea ^a   Lehotay, Jozef ^a   Krupcík, Jan ^a   Májek, Pavel ^a   Armstrong, Daniel W ^b   He, Brian Lingfeng ^c   Cotton, F Albert ^d  

^a SLOVAK UNIVERSITY OF TECHNOLOGY   (Slovakia)

^b UNIVERSITY OF TEXAS AT ARLINGTON   (United States)

^c Advanced Separation Technologies Inc   (United States)

^d TEXAS A AND M UNIVERSITY   (United States)

Author keywords

2,3 Pentadienedioic acid enantiomers; Direct enantiomers separation; Energy barrier to interconversion; On column interconversion of enatiomers

Indexed keywords

ACTIVATION ENERGY; CHEMICAL REACTIONS; ENTHALPY; ENTROPY; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; RATE CONSTANTS; REACTION KINETICS;

ENANTIOMERIZATION; INTERCONVERSION ENERGY BARRIER; PENTADIENEDIOIC ACID ENANTIOMERS;

ACIDS;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; COLUMN CHROMATOGRAPHY; COMPUTER ANALYSIS; CONFORMATIONAL TRANSITION; ENANTIOMER; ENTHALPY; ENTROPY; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; PRIORITY JOURNAL; RACEMIC MIXTURE; SEPARATION TECHNIQUE; STRUCTURE ANALYSIS; TEMPERATURE SENSITIVITY;

ALKADIENES; CARBOXYLIC ACIDS; CHROMATOGRAPHY, HIGH PRESSURE LIQUID; STEREOISOMERISM; THERMODYNAMICS;

EID: 33845971286     PISSN: 16159306     EISSN: 16159314     Source Type: Journal    
DOI: 10.1002/jssc.200600164     Document Type: Article

References (7)

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