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McCleverty, J. A, Meyer, T. J, Eds, Elsevier Pergamon: Oxford, UK
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(a) Miller, A.-F. In Comprehensive Coordination Chemistry II; McCleverty, J. A., Meyer, T. J., Eds.; Elsevier Pergamon: Oxford, UK, 2004.
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Comprehensive Coordination Chemistry II
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Miller, A.-F.1
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0003483645
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Meunier, B, Ed, Imperial College Press: London
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(b) Cabelli, D. E.; Riley, D.; Rodriguez, J. A.; Valentine, J. S.; Zhu, H. In Biomimetic Oxidations Catalyzed by Transition Metal Complexes; Meunier, B., Ed.; Imperial College Press: London, 2000.
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Biomimetic Oxidations Catalyzed by Transition Metal Complexes
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Cabelli, D.E.1
Riley, D.2
Rodriguez, J.A.3
Valentine, J.S.4
Zhu, H.5
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3
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0033573861
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Hart, P. J.; Balbirnie, M. M.; Ogihara, N. L.; Nersissian, A. M.; Weiss, M. S.; Valentine, J. S.; Eisenberg, D. Biochemistry 1999, 38, 2167.
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Hart, P.J.1
Balbirnie, M.M.2
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Nersissian, A.M.4
Weiss, M.S.5
Valentine, J.S.6
Eisenberg, D.7
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4
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0015982070
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(a) Fielden, E. M.; Roberts, P. B.; Bray, R. C.; Lowe, D. J.; Mautner, G. N.; Rotilio, G.; Calabrese, L. Biochem. J. 1974, 139, 49.
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Fielden, E.M.1
Roberts, P.B.2
Bray, R.C.3
Lowe, D.J.4
Mautner, G.N.5
Rotilio, G.6
Calabrese, L.7
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5
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0015912256
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(b) Klug-Roth, D.; Fridovich, I.; Rabani, J. J. Am. Chem. Soc. 1973, 95, 2786.
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Klug-Roth, D.1
Fridovich, I.2
Rabani, J.3
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6
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84987341320
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(c) Rabani, J.; Klug, D.; Fridovich, I. Isr. J. Chem. 1972, 10, 1095.
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Isr. J. Chem
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Rabani, J.1
Klug, D.2
Fridovich, I.3
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7
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8944224019
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For a discussion of proton transfer and the involvement of fully reduced enzyme lacking the His63 bridge, see: Ellerby, L. M.; Cabelli, D. E.; Graden, J. A.; Valentine, J. S. J. Am. Chem. Soc. 1996, 118, 6556.
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For a discussion of proton transfer and the involvement of fully reduced enzyme lacking the His63 bridge, see: Ellerby, L. M.; Cabelli, D. E.; Graden, J. A.; Valentine, J. S. J. Am. Chem. Soc. 1996, 118, 6556.
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8
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17644386600
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Kohen, A, Limbach, H.-H, Eds, CRC Press: Boca Raton, FL
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Roth, J. P.; Klinman, J. P. In Isotope Effects in Chemistry and Biology: Kohen, A., Limbach, H.-H., Eds.; CRC Press: Boca Raton, FL, 2006.
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Isotope Effects in Chemistry and Biology
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Roth, J.P.1
Klinman, J.P.2
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11
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33845944027
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-4 M ethylenediamine tetraacetic acid (EDTA).
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-4 M ethylenediamine tetraacetic acid (EDTA).
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12
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33845916504
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See Supporting Information for further details
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(b) See Supporting Information for further details.
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14
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4243472823
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Derivations of the expressions are provided as Supporting Information
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(b) Dole, M.; Rudd, D.; Muchow, G. R.; Comte, C. J. Chem. Phys. 1952, 20, 961. Derivations of the expressions are provided as Supporting Information.
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J. Chem. Phys
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Dole, M.1
Rudd, D.2
Muchow, G.R.3
Comte, C.4
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15
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33845949512
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H2O = ηD2O at 20 °C: Hardy, R. C.; Cottington, R. L. J. Res. Natl. Bur. Stand. 1949, 42, 573.
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H2O = ηD2O at 20 °C: Hardy, R. C.; Cottington, R. L. J. Res. Natl. Bur. Stand. 1949, 42, 573.
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16
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0022527381
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(a) Viglino, P.; Scarpa, M.; Coin, F.; Rotilio, G.; Rigo, A. Biochem. J. 1986, 237, 305.
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Biochem. J
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Viglino, P.1
Scarpa, M.2
Coin, F.3
Rotilio, G.4
Rigo, A.5
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17
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0021874129
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(b) Viglino, P.; Scarpa, M.; Cocco, D.; Rigo, A. Biochem. J. 1985, 229, 87.
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Biochem. J
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Viglino, P.1
Scarpa, M.2
Cocco, D.3
Rigo, A.4
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18
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33845961526
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4 reduction following ref 11b.
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4 reduction following ref 11b.
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19
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33845921835
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2 and protect the reduced enzyme.
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2 and protect the reduced enzyme.
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20
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1442328094
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Long-range ET is unlikely in view of the ∼30Å inter-copper distance. See ref 11a. ket ∼ 1013exp-1.2 Å-1 × 30 Å, 0.0023 s-1 is estimated for a barrierless ET. See Gray, H. B, Winkler, J. R. Quart. Rev. Biophys. 2003, 36, 341 for a leading reference
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-1 is estimated for a barrierless ET. See Gray, H. B.; Winkler, J. R. Quart. Rev. Biophys. 2003, 36, 341 for a leading reference.
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21
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33845959177
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11 exp[-(ΔG° + λ)/4λRT].
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11 exp[-(ΔG° + λ)/4λRT].
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22
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9444274813
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Roth, J. P.; Wincek, R.; Nodet, G.; Edmondson, D. E.; McIntire, W. S.; Klinman, J. P. J. Am. Chem. Soc. 2004, 126, 15120.
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Roth, J.P.1
Wincek, R.2
Nodet, G.3
Edmondson, D.E.4
McIntire, W.S.5
Klinman, J.P.6
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23
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0000261827
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Bunks, E.; Bixon, M.; Jortner, J. J. Phys. Chem. 1981, 85, 3763.
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(1981)
J. Phys. Chem
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Bunks, E.1
Bixon, M.2
Jortner, J.3
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24
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0001135382
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.-) = -0.16 V versus NHE.
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.-) = -0.16 V versus NHE.
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25
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27844441878
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Lanci, M. P.; Brinkley, D. W.; Stone, K. L.; Smirnov, V. V.; Roth, J. P. Angew. Chem., Int. Ed. 2005, 44, 7273.
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Angew. Chem., Int. Ed
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Lanci, M.P.1
Brinkley, D.W.2
Stone, K.L.3
Smirnov, V.V.4
Roth, J.P.5
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26
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0037199441
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Mure, M.; Mills, S. A.; Klinman, J. P. Biochemistry 2002, 41, 9269.
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Biochemistry
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Mure, M.1
Mills, S.A.2
Klinman, J.P.3
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