Cluster analysis of the organic peaks in bulk mass spectra obtained during the 2002 New England air quality study with an aerodyne aerosol mass spectrometer

Atmospheric Chemistry and Physics

Volumn 6, Issue 12, 2006, Pages 5649-5666

  Marcolli, C ^a   Canagaratna, M R ^b   Worsnop, D R ^b   Bahreini, R ^c,d   De Gouw, J A ^c,d   Warneke, C ^c,d   Goldan, P D ^c   Kuster, W C ^c   Williams, E J ^c,d   Lerner, B M ^c,d   Roberts, J M ^c   Meagher, J F ^c   Fehsenfeld, F C ^c   Marchewka, M ^e   Bertman, S B ^e   Middlebrook, A M ^c  

^a Land Climate Dynamics Group   (Switzerland)

^b AERODYNE RESEARCH INC   (United States)

^c EARTH SYSTEM RESEARCH LABORATORY   (United States)

^d UNIVERSITY OF COLORADO   (United States)

^e WESTERN MICHIGAN UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AIR QUALITY; ANTHROPOGENIC SOURCE; BIOGENIC EMISSION; CLUSTER ANALYSIS; COASTAL ZONE; DATA SET; MASS SPECTROMETRY; MONOTERPENE; ORGANIC MATTER; OXIDATION;

ATLANTIC COAST [NORTH AMERICA]; ATLANTIC COAST [UNITED STATES]; NEW ENGLAND; NORTH AMERICA; UNITED STATES;

EID: 33845644984     PISSN: 16807316     EISSN: 16807324     Source Type: Journal    
DOI: 10.5194/acp-6-5649-2006     Document Type: Article

References (52)

1. Alfarra, M. R., Coe, H., Allan, J. D., Bower, K. N., Boudries, H., Canagaratna, M. R., Jimenez, J. L., Jayne, J. T., Garforth, A. A., Li, S. M., and Worsnop, D. R.: Characterization of urban and rural organic particulate in the Lower Fraser Valley using two Aerodyne aerosol mass spectrometers, Atmos. Environ., (Pacific 2001 special issue), 38, 5745-5758, 2004.
2. Alfarra, M. R., Paulsen, D., Gysel, M., Garforth, A. A., Dommen, J., Prevot, A. S. H., Worsnop, D. R., Baltensperger, U., and Coe, H.: A mass spectrometric study of secondary organic aerosols formed from the photooxidation of anthropogenic and biogenic precursors in a reaction chamber, Atmos. Chem. Phys., 6, 5279-5293, 2006, http://www.atmos-chem-phys.net/6/5279/2006A
3. Alfarra, M. R.: Insights into atmospheric organic aerosols using an aerosol mass spectrometer, PhD thesis under Prof. H. Coe, Univ. of Manchester, pp. 79-98 and 215-225, 2004.
4. Allan J. D., Alfarra, M. R., Bower, K. N., Williams, P. I., Gallagher, M. W., Jimenez, J. L., McDonald, A. G., Nemitz, E., Canagaratna, M. R., Jayne, J. T., Coe, H., and Worsnop, D. R.: Quantitative sampling using an Aerodyne aerosol mass spectrometer, 2. Measurements of fine particulate chemical composition in two U.K. cities, J. Geophys. Res., 108(D3), 4091, doi: 10.1029/2002JD002359, 2003b.
5. Allan J. D., Jimenez, J. L., Williams, P. I., Alfarra, M. R., Bower, K. N., Jayne, J. T., Coe, H., and Worsnop, D. R.: Quantitative sampling using an Aerodyne aerosol mass spectrometer, 1. Techniques of data interpretation and error analysis, J. Geophys. Res., 108(D3), 4090, doi: 10.1029/2002JD002358, 2003a.
6. Allan, J. D., Bower, K. N., Coe, H., Boudries, H., Jayne, J. T., Canagaratna, M. R., Millet, D. B., Goldstein, A. H., Quinn, P. K., Weber, R. J., and Worsnop, D. R.: Submicron aerosol composition at Trinidad Head, California, during ITCT 2K2: Its relationship with gas phase volatile organic carbon and assessment of instrument performance, J. Geophys. Res., 109, D23S24, doi:10.1029/2003JD004208, 2004b.
7. Allan, J. D., Delia, A. E., Coe, H., Bower, K. N., Alfarra, M. R., Jimenez, J. L., Middlebrook, A. M., Drewnick, F., Onasch, T. B., Canagaratna, M. R., Jayne, J. T., and Worsnop, D. R.: A generalised method for the extraction of chemically resolved mass spectra from Aerodyne aerosol mass spectrometer data, J. Aerosol Sci., 35(7), 909-922, doi: 10.1016/j.jaerosci.2004.02.007, 2004a.
8. Bahreini, R., Jimenez, J. L., Wang, J., Flagan, R. C., Seinfeld, J. H., Jayne, J. T., and Worsnop, D. R.: Aircraft-based aerosol size and composition measurements during ACE-Asia using an Aerodyne aerosol mass spectrometer, J. Geophys. Res., 108(D23), 8645, doi:10.1029/2002JD003226, 2003.
9. Bahreini, R., Keywood, M. D., Ng, N. L., Varutbangkul, V., Gao, S., Flagan, R. C., Seinfeld, J. H., Worsnop, D. R., and Jimenez, J. L.: Measurements of secondary organic aerosol from oxidation of cycloalkenes, terpenes, and m-xylene using an Aerodyne aerosol mass spectrometer, Environ. Sci. Technol., 39(15), 5674-5688, doi: 10.1021/es048061a, 2005.
10. Bates, T. S., Quinn, P. K., Coffman, D. J., Johnson, J. E., and Middlebrook, A. M.: Dominance of organic aerosols in the marine boundary layer over the Gulf of Maine during NEAQS 2002 and their role in aerosol light scattering, J. Geophys. Res., 110, D18202, doi: 10.1029/2005JD005797, 2005.
11. 3 and other oxides of nitrogen on solid NaCl: The role of surface adsorbed water, J. Phys. Chem., 100, 15218-15228, 1996.
12. Blando, J. D. and Turpin, B. J.: Secondary organic aerosol formation in cloud and fog droplets: a literature evaluation of plausibility, Atmos. Environ., 34, 1623-1632, 2000.
13. x in the summer marine boundary layer, Geophys. Res. Lett., 31, L07108, doi: 10.1029/2004GL019412, 2004.
14. Canagaratna, M. R., Jayne, J. T., Ghertner, D. A., Herndon, S., Shi, Q., Jimenez, J. L., Silva, P. J., Williams, P., Lanni, T., Drewnick, F., Demerjian, K. L., Kolb, C. E., and Worsnop, D. R.: Chase studies of particulate emissions from in-use New York City vehicles, Aerosol Sei. Technol., 38, 555-573, 2004.
15. Canagaratna, M. R., Jayne, J. T., Jimenez, J. L., Allan, J. D., Alfarra, M. R., Zhang, Q., Onasch, T. B., Drewnick, F., Coe, H., Middlebrook, A., Delia, A., Williams, L. R., Trimborn, A. M., Northway, M. J., Kolb, C. E., Davidovits, P., and Worsnop, D. R.: Chemical and microphysical characterization of ambient aerosols with the Aerodyne aerosol mass spectrometer, Mass Spec. Rev., in press, 2006.
16. de Gouw, J. A., Goldan, P. D., Warneke, C., Kuster, W. C., Roberts, J. M., Marchewka, M., Bertman, S. B., Pszenny, A. A. P., and Keene, W. C.: Validation of proton transfer reaction-mass spectrometry (PTR-MS) measurements of gas-phase organic compounds in the atmosphere during the New England Air Quality Study (NEAQS) in 2002, J. Geophys. Res., 108(D21), 4682, doi: 10.1029/2003JD003863, 2003.
17. de Gouw, J. A., Middlebrook, A. M., Warneke, C., Goldan, P. D., Kuster, W. C., Roberts, J. M., Fehsenreld, F. C., Worsnop, D. R., Canagaratna, M. R., Pszenny, A. A. P., Keene, W. C., Marchewka, M., Bertman, S. B., and Bates, T. S.: Budget of organic carbon in a polluted atmosphere: Results from the New England Air Quality Study in 2002, J. Geophys. Res., 110, D16305, doi: 10.1029/2004JD005623, 2005.
18. DeCarlo, P. F., Kimmel, J. R., Trimborn, A., Northway, M. J., Jayne, J. T., Aiken, A. C., Gonin, M., Fuhrer, K., Horvath, T., Docherty, K. S., Worsnop, D. R., and Jimenez, J. L.: Field-deployable, high-resolution, time-of-flight aerosol mass spectrometer, Anal. Chem., 78, 8281-8289, doi:10.1021/ac061249n, 2006.
19. Goldan P. D., Kuster, W. C., Williams, E., Murphy, P. C., Fehsenteld, F. C., and Meagher, J.: Nonmethane hydrocarbon and oxy hydrocarbon measurements during the 2002 New England Air Quality Study, J. Geophys. Res., 109, D21309, doi: 10.1029/2003JD004455, 2004.
20. Guenther, A., Karl, T., Harley, P., Wiedinmyer, C., Palmer, P. I., and Geron, C.: Estimates of global terrestrial isoprene emissions using MEGAN (Model of Emissions of Gases and Aerosols from Nature), Atmos. Chem. Phys., 6, 3181-3210, 2006, http://www.atmos-chem-phys.net/6/3181/2006/.
21. Jayne, J. T., Leard, D. C., Zhang, X., Davidovits, P., Smith, K. A., Kolb, C. E., and Worsnop D. R.: Development of an aerosol mass spectrometer for size and composition analysis of submicron particles, Aerosol Sei. Technol., 33, 49-70, 2000.
22. Jimenez, J. L., Jayne, J. T., Shi, Q., Kolb, C. E., Worsnop, D. R., Yourshaw, I., Seinfeld, J. H., Flagan, R. C., Zhang, X., Smith, K. A., Morris, J. W., and Davidovits, P.: Ambient aerosol sampling using the Aerodyne aerosol mass spectrometer, J. Geophys. Res., 108(D7), 8425, doi: 10.1029/2001JD001213, 2003.
23. Kalberer, M., Paulsen, D., Sax, M. Steinbacher, M., Dommen, J., Prevot, A. S. H., Fisseha, R., Weingartner, E., Frankevich, V., Zenobi, R., and Baltensperger, U.: Identification of Polymers as Major Components of Atmospheric Organic Aerosols, Science, 303, 1659-1662, 2004.
24. Kanakidou, M., Seinfeld, J. H., Pandis, S. N., Barnes, I., Dentener, F. J., Facchini, M. C., Van Dingenen, R., Ervens, B., Nenes, A., Nielsen, C. J., Swietlicki, E., Putaud, J. P., Balkanski, Y., Fuzzi, S., Horth, J., Moortgat, G. K., Winterhalter, R., Myhre, C. E. L., Tsigaridis, K., Vignati, E., Stephanou, E. G., and Wilson, J.: Organic aerosol and global climate modelling: a review, Atmos. Chem. Phys., 5, 1053-1123, 2005, http://www.atmos-chem-phys.net/5/1053/ 2005/.
25. 2.5 concentration, Climate Res., 28, 143-154, 2005
26. Klinedinst, D. B., and Currie, L. A.: Direct quantification of PM2.5 fossil and biomass carbon within the Northern Front Range Air Quality Study's domain, Environ. Sci. Technol., 33, 4146-4154, 1999.
27. x conditions, Geophys. Res. Lett., 32, L18808, doi: 10.1029/2005GL023637, 2005.
28. Kroll, J. H., Ng, N. L., Murphy, S. M., Flagan, R. C., and Seinfeld, J. H.: Secondary organic aerosol formation from isoprene photooxidation, Environ. Sci. Technol., 40(6), 1869-1877, doi: 10.1021/es0524301, 2006.
29. 13C ratios, J. Geophys. Res., 107(D22), 4631, doi: 10.1029/2002JD002339, 2002.
30. Lewis, C. W., Klouda, G. A., and Ellenson, W. D.: Radiocarbon measurement of the biogenic contribution to summertime PM-2.5 ambient aerosol in Nashville, TN, Atmos. Environ., 38, 6053-6061, doi: 10.1016/j.atmosenv.2004.06.011, 2004.
31. Marchewka, M., Bertman, S. B., Roberts, J. M., Warneke, C., de Gouw, J., Kuster, W., Goldan, P., Williams, E., Lerner, B. M., Murphy, P., and Fehsenfeld, F. C.: Measurements of PANs during the New England Air Quality Study 2002, J. Geophys. Res., submitted, doi:10.1029/2006JD007569, 2006.
32. Marcolli, C., Luo, B. P., Peter, Th., and Wienhold, F. G.: Internal mixing of the organic aerosol by gas phase diffusion of semivolatile organic compounds, Atmos. Chem. Phys., 4, 2593-2599, 2004, http://www.atmos-chem-phys. net/4/2593/2004/.
33. McLafferty, F. W. and Tureček, F.: Interpretation of mass spectra, University Science Books, pp. 91-95, Sausalito, CA, 1993.
34. Middlebrook, A. M., Murphy, D. M., Lee, S.-H., Thomson, D. S., Prather, K. A., Wenzel, R. J., Liu, D.-Y., Phares, D. J., Rhoads, K. P., Wexler, A. S., Johnston, M. V., Jimenez, J. L., Jayne, J. T., Worsnop, D. R., Yourshaw, I., Seinfeld, J. H., and Flagan, R. C.: A comparison of particle mass spectrometers during the 1999 Atlanta Supersite Project, J. Geophys. Res., 108(D7), 8424, doi:10.1029/2001JD000660, 2003.
35. Murphy, D. M., Cziczo, D. J., Froyd, K. D., Hudson, P. K., Matthew, B. M., Middlebrook, A. M., Peltier, R. E., Sullivan, A., Thomson, D. S., and Weber, R. J.: Single-particle mass spectrometry of tropospheric aerosol particles, J. Geophys. Res., 111, D23S32, doi:10.1029/2006JD007340, 2006.
36. Murphy, D. M., Middlebrook, A. M., and Warshawsky M.: Cluster analysis of data from the particle analysis by laser mass spectrometry (PALMS) instrument, Aerosol Sci. Technol., 37, 382-391, 2003.
37. Murphy, D. M., Thomson, D. S., and Mahoney, M. J.: In situ measurements of organics, meteoritic material, mercury, and other elements in aerosols at 5 to 19 kilometers, Science, 282, 1664-1669, 1998.
38. Noble, C. A. and Prather, K. A.: Real-time single particle monitoring of a relative increase in marine aerosol concentration during winter rainstorms, Geophys. Res. Lett., 24, 2753-2756, 1997.
39. Ondov, J. M., Buckley, T. J., Hopke, P. K., Ogulei, D., Parlange, M. B., Rogge, W. F., Squibb, K. S., Johnston, M. V., and Wexler, A. S.: Baltimore Supersite: Highly time- and size-resolved concentrations of urban PM2.5 and its constituents for resolution of sources and immune responses, Atmos. Environ., 40, Supp. 2, S224-S237, 2006.
40. Pekney, N. J., Davidson, C. I., Bein, K. J., Wexler, A. S., and Johnston, M. V.: Identification of sources of atmospheric PM at the Pittsburgh Supersite Part I: Single particle analysis and filter-based positive matrix factorization, Atmos. Environ., 40, Supp. 2, S411-S423, 2006.
41. Pöschl, U.: Atmospheric aerosols: Composition, transformation, climate and health effects, Angew. Chem. Int. Ed., 44, 7520-7540, doi:10.1002/anie.200501122, 2005.
42. Quinn, P. K. and Bates T. S.: North American, Asian, and Indian haze: Similar regional impacts on climate?, Geophys. Res. Lett., 30(11), 1555, doi: 10.1029/2003GL016934, 2003.
43. Schneider, J., Borrmann, S., Wollny, A. G., Bläsner, M., Mihalopoulos, N., Oikonomou, K., Sciare, J., Teller, A., Levin, Z., and Worsnop, D. R.: Online mass spectrometric aerosol measurements during the MINOS campaign (Crete, August 2001), Atmos. Chem. Phys., 4, 65-80, 2004, http://www.atmos- chem-phys.net/4/65/2004/.
44. Shibata, K., Endo, M., Yamamoto, N., Yoshinaga, J., Yanagisawa, Y., Endo, O., Goto, S., Yoneda, M., Shibata, Y., and Morita, M.: Temporal variation of radiocarbon concentration in airborne particulate matter in Tokyo, Radiocarbon, 46, 485-490, 2004.
45. Slater, J. F., Dibb, J. E., Keim, B. D., and Talbot, R. W.: Light extinction by fine atmospheric particles in the White Mountains region of New Hampshire and its relationship to air mass transport, Sci. Total Environ., 287, 221-239, 2002.
46. Sullivan, R. C., Guazzotti, S. A., Sodeman, D. A., and Prather, K. A.: Direct observations of the atmospheric processing of Asian mineral dust, Atmos. Chem. Phys. Discuss., 6, 4109-4170, 2006, http ://www.atmos-chem-phys-discuss. net/6/4109/2006/.
47. 14C)-deduced biogenic and anthropogenic contributions to organic carbon (OC) of urban aerosols from Zürich, Switzerland, Atmos. Environ., 38, 4035-4044, doi: 10.1016/j.atmosenv.2004.03. 066, 2004.
48. Turpin, B. J., Saxena, P., and Andrews E.: Measuring and simulating particulate organics in the atmosphere: problems and prospects, Atmos. Environ., 34, 2983-3013, 2000.
49. Williams, J., Roberts, J. M., Fehsenfeld, R C., Bertman, S. B., Buhr, M. P., Goldan, P. D., Hübler, G., Kuster, W. C., Ryerson, T. B., Trainer, M., and Young, V.: Regional ozone from biogenic hydrocarbons deduced from airborne measurements of PAN, PPN, and MPAN, Geophys. Res. Lett., 24(9), 1099-1102, 1997.
50. Zappoli, S., Andracchio, A., Fuzzi, S., Facchini, M. C., Gelencsér, A., Kiss, G., Krivácsy, Z., Molnár, Á., Mészáros, E., Hansson, H.-C., Rosman, K., and Zebühr, Y: Inorganic, organic and macromolecular components of fine aerosol in different areas of Europe in relation to their water solubility, Atmos. Environ, 33, 2733-2743, 1999.
51. Zhang, Q., Alfarra, M. R., Worsnop, D. R., Allan, J. D., Coe, H., Canagaratna, M. R., and Jimenez, J. L.: Deconvolution and quantification of hydrocarbon-like and oxygenated organic aerosols based on aerosol mass spectrometry, Environ. Sci. Technol., 39, 4938-4952, doi:10.1021/es0485681, 2005a, b.
52. Zhang, Q., Canagaratna, M. R., Jayne, J. T., Worsnop, D. R., and Jimenez, J. L.: Time- and size-resolved chemical composition of submicron particles in Pittsburgh: Implications for aerosol sources and processes, J. Geophys. Res., 110, D07S09, doi:10.1029/2004JD004649, 2005b.