Heavy cyclopropene analogues R4SiGe2 and R4Ge3 (R = SiMetBu2) - New members of the cyclic digermenes family

Journal of Organometallic Chemistry

Volumn 692, Issue 1-3, 2007, Pages 10-19

  Lee, Vladimir Ya ^a   Yasuda, Hiroyuki ^a   Ichinohe, Masaaki ^a   Sekiguchi, Akira ^a  

^a UNIVERSITY OF TSUKUBA   (Japan)

Author keywords

Digermene; Ring expansion; Siladigermirene; Small ring; Trigermirene; X ray crystallographic analysis

Indexed keywords

CHEMICAL BONDS; PARAFFINS; REACTION KINETICS; SILICON COMPOUNDS; X RAY ANALYSIS; X RAY CRYSTALLOGRAPHY;

DIGERMENE; RING EXPANSION; SILADIGERMIRENE; SMALL RINGS; TRIGERMIRENE; X RAY CRYSTALLOGRAPHIC ANALYSIS;

OLEFINS;

EID: 33845638801     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2006.03.049     Document Type: Article

References (41)

1. Lee V.Ya., and Sekiguchi A. In: Rappoport Z. (Ed). The Chemistry of Organic Germanium, Tin and Lead Compounds vol. 2 (2002), Wiley, Chichester Part 1; Chapter 14
2. Sekiguchi A., and Lee V.Ya. Chem. Rev. 103 (2003) 1429
3. Sekiguchi A., and Lee V.Ya. In: Auner N., and Weis J. (Eds). Organosilicon Chemistry V (From Molecules to Materials) (2003), Wiley-VCH, Weinheim 92
4. Sekiguchi A., Yamazaki H., Kabuto C., Sakurai H., and Nagase S. J. Am. Chem. Soc. 117 (1995) 8025
5. Sekiguchi A., Fukaya N., Ichinohe M., Takagi N., and Nagase S. J. Am. Chem. Soc. 121 (1999) 11587
6. Sekiguchi A., Ishida Y., Fukaya N., Ichinohe M., Takagi N., and Nagase S. J. Am. Chem. Soc. 124 (2002) 1158
7. Iwamoto T., Kabuto C., and Kira M. J. Am. Chem. Soc. 121 (1999) 886
8. Ichinohe M., Matsuno T., and Sekiguchi A. Angew. Chem., Int. Ed. 38 (1999) 2194
9. Iwamoto T., Tamura M., Kabuto C., and Kira M. Science 290 (2000) 504
10. Ichinohe M., Igarashi M., Sanuki K., and Sekiguchi A. J. Am. Chem. Soc. 127 (2005) 9978
11. Wiberg N., Lerner H.-W., Vasisht S.-K., Wagner S., Karaghiosoff K., Nöth H., and Ponikwar W. Eur. J. Inorg. Chem. (1999) 1211
12. Lee V.Ya., Ichinohe M., Sekiguchi A., Takagi N., and Nagase S. J. Am. Chem. Soc. 122 (2000) 9034
13. Lee V.Ya., Ichinohe M., and Sekiguchi A. J. Am. Chem. Soc. 122 (2000) 12604
14. Lee V.Ya., Matsuno T., Ichinohe M., and Sekiguchi A. Heteroatom. Chem. 12 (2001) 223
15. Lee V.Ya., Ichinohe M., and Sekiguchi A. Chem. Lett. (2001) 728
16. Lee V.Ya., Ichinohe M., and Sekiguchi A. Chem. Commun. (2001) 2146
17. Lee V.Ya., Ichinohe M., and Sekiguchi A. J. Organomet. Chem. 636 (2001) 41
18. Lee V.Ya., Ichinohe M., and Sekiguchi A. J. Am. Chem. Soc. 124 (2002) 9962
19. Lee V.Ya., Ichinohe M., and Sekiguchi A. Main Group Met. Chem. 25 (2002) 1
20. Lee V.Ya., Takanashi K., Ichinohe M., and Sekiguchi A. J. Am. Chem. Soc. 125 (2003) 6012
21. Lee V.Ya., and Sekiguchi A. Chem. Lett. 33 (2004) 84
22. Lee V.Ya., Takanashi K., Nakamoto M., and Sekiguchi A. Russ. Chem. Bull., Int. Ed. 53 (2004) 1102
23. Lee V.Ya., Ichinohe M., and Sekiguchi A. J. Organomet. Chem. 685 (2003) 168
24. Preliminary communication:. Lee V.Ya., Yasuda H., Ichinohe M., and Sekiguchi A. Angew. Chem., Int. Ed. 44 (2005) 6378
25. Mallela S.P., and Geanangel R.A. Inorg. Chem. 30 (1991) 1480
26. Lerner H.-W., Schödel F., Sänger I., Wagner M., and Bolte M. Z. Naturforsch. 59b (2004) 277
27. Ichinohe M., Arai Y., Sekiguchi A., Takagi N., and Nagase S. Organometallics 20 (2001) 4141
28. Sekiguchi A., Inoue S., Ichinohe M., and Arai Y. J. Am. Chem. Soc. 126 (2004) 9626
29. 3SiNa: Ref. [3c] and. Ichinohe M., Sekiyama H., Fukaya N., and Sekiguchi A. J. Am. Chem. Soc. 122 (2000) 6781
30. The Ge{double bond, long}Ge bond is typically trans-bent:. Power P.P. Chem. Rev. 99 (1999) 3463
31. Sekiguchi A., Izumi R., Ihara S., Ichinohe M., and Lee V.Ya. Angew. Chem., Int. Ed. 41 (2002) 1598
32. 2 will be reported in the forthcoming publication.
33. We do not discuss the structural parameters of 2b in details, because its refinement was not sufficiently good.
34. Hong J.-H., Han J.S., Lee G.-H., and Jung I.N. J. Organomet. Chem. 437 (1992) 265
35. Braddock-Wilking J., Chiang M.Y., and Gaspar P.P. Organometallics 12 (1993) 197
36. Baines K.M., and Stibbs W.G. Coord. Chem. Rev. 145 (1995) 157
37. Kira M., Ishima T., Iwamoto T., and Ichinohe M. J. Am. Chem. Soc. 123 (2001) 1676
38. Mochida K., Kayamori T., Wakasa M., Hayashi H., and Egorov M.P. Organometallics 19 (2000) 3379
39. Samuel M.S., Jennings M.C., and Baines K.M. Organometallics 20 (2001) 590
40. Altomare A., Cascarano G., Giacovazzo C., Guagliardi A., Burla M.C., Polidori G., and Camalli M. J. Appl. Crystallogr. 27 (1994) 435
41. Sheldrick G.M. shelxl-97, Program for Crystal Structure Refinement (1997), University of Göttingen, Germany