Cooperative effect between iridium and platinum in the carbonylation of methanol to acetic acid

Topics in Catalysis

Volumn 40, Issue 1-4, 2006, Pages 83-90

  Gautron, Samuel ^a,b   Lassauque, Nicolas ^a   Le Berre, Carole ^a   Azam, Laurent ^a   Giordano, Roberto ^a   Serp, Philippe ^a   Laurenczy, Gábor ^c   Thiébaut, Daniel ^b   Kalck, Philippe ^a  

^a UNIVERSITÉ DE TOULOUSE   (France)

^b ACETEX   (France)

^c INSTITUTE OF CHEMICAL SCIENCES AND ENGINEERING   (Switzerland)

Author keywords

Bimetallic catalysis; Mechanistic studies; NMR

Indexed keywords

BIMETALLIC CATALYSIS; CATALYTIC CONDITIONS; CO-OPERATIVE EFFECTS; HIGH-PRESSURE NMR; LOW WATER-CONTENT; MECHANISTIC STUDIES; RATE DETERMINING STEP; SHORT-LIVED SPECIES;

ACETIC ACID; CARBONYLATION; CATALYSIS; DIMERS; METHANOL; NUCLEAR MAGNETIC RESONANCE; PH; PLATINUM;

IRIDIUM;

EID: 33845595059     PISSN: 10225528     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11244-006-0110-x     Document Type: Conference Paper

References (16)

1. K. Weissermel, H.J. Arpe, in: Industrial Organic Chemistry, 3rd ed., eds.WCH (Weinheim, 1997).
2. P. Torrence, in: Applied Homogeneous Catalysis with Organometallic Conpounds, eds. B. Cornils and. W.A. Herrmann (Wiley-VCH, Weinheim, 2002) p. 104.
3. N. Yoneda, S. Kusano, M. Yasui, P. Pujado and S. Wilcher, Appl. Catal. 221 (2001) 253.
4. F. E. Paulik, A. Hersman, W.R. Knox and J.F. Roth, 3,769,329: US Patent, 1973 to Monsanto Company.
5. D. Forster, Adv. Organomet. Chem 17 (1979) 225.
6. B.L. Smith, G.P. Torrence, A. Aguilo and S. Alder, US patent 5,001,259 (1991), to Hoechst Celanese Corp.
7. J.H. Jones, Platinum Metal Rev. 44 (2000) 94.
8. P.M. Maitlis, A. Haynes, G.J. Sunley and M.J. Howard, J. Chem. Soc., Dalton Trans. (1996), 2187.
9. C.J.E. Vercauteren, K.E. Clode and D.J. Watson, European patent 616997 (1994), to BP Chemicals.
10. A. Haynes et al., J. Am. Chem. Soc. 126 (2004) 2847.
11. C. Le Berre, P. Serp, P. Kalck, L. Layeillon and D. Thiebaut, French Patent 9813954 (1998) to Acetex Chimie.
12. D. Brodzki, B. Denise and G. Pannetier, J. Mol. Cat. 2 (1977) 149.
13. S. Gautron, R. Giordano, C. Berre, J. Jaud, J.-C Daran, P. Serp and P. Kalck, Inorg. Chem. 42 (2003) 5523.
14. T. Ghaffar, H. Adams, P.M. Maitlis, G.J. Sunley, M.J. Baker and A. Haynes, Chem. Commun. (1998) 1023.
15. D. Forster, J. Chem. Soc., Dalton Trans. (1979) 1639.
16. R. H. Crabtree, in: The Organometallic Chemistry of the Transition Metals, 3rd ed. (Wiley-interscience, New York, 2001) p. 109.