Catalysis of Hydrogen Production in Irradiated Aqueous Solutions by Gold Sols

Journal of the American Chemical Society

Volumn 101, Issue 20, 1979, Pages 6133-6135

  Meisel, D ^a  

^a ARGONNE NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33845559059     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00514a052     Document Type: Letter

References (13)

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2. J.M. Lehn and J.P. Sauvage, Nouv. J. Chim., 1, 449 (1977).
3. K. Kalyanasundaram, J. Kiwi, and M. Gratzei, Helv. Chim. Acta, 61, 2720 (1978).
4. S.M. Kuznicki and E.M. Eyring, J. Am. Chem. Soc., 100, 6790 (1978).
5. A. Henglein, Angew. Chem., 91, 449 (1979).
6. J. Turkevich, P.L. Stevenson and J. Hillier, Discuss. Farad. Soc., 11, 55 (1951).
7. No other component of the system, including any reasonable oxidation product introduced by the sol production procedure, could effectively compete for the primary radicals under our experimental conditions in an H2-producing reaction. See the following NBS specific rate tables: Farhataziz and A.B. Ross, Natl. Stand. Ref. Data Ser., Natl. Bur. Stand., No. 59 (1977).
8. M. Anbar Farhataziz, and A.B. Ross, Natl. Stand. Ref. Data Ser., No. 51 (1975).
9. M. Bambenek, and A.B. Ross, Natl. Stand. Ref. Data Ser. No. 43 (1973).
10. J. Lilie, G. Beck, and A. Henglein, Ber. Bunsenges. Phys. Chem., 75, 458 (1971).
11. M. Simic, P. Neta, and E. Hayon, J. Phys. Chem., 73, 3794 (1969).
12. Such /3-hydrogen abstraction by reduced cadmium cations was, however, suggested: M. Kelm, J. Lilie, and A. Henglein, J. Chem. Soc., Faraday Trans. 1, 71, 1132 (1975).
13. M. Freiberg and D. Meyerstein, J. Chem. Soc., 73, 622 (1977).