Monomeric and Dimeric Thiodithiazyl Cations, S3N2+ and S6N42+. Preparation and Crystal Structures of (S3N2)(AsF6), (S6N4)(S2O2F)2, and (S6N4)(SO3F)2

Inorganic Chemistry

Volumn 20, Issue 11, 1981, Pages 3784-3799

  Gillespie, Ronald J ^a   Kent, James P ^a   Sawyer, Jeffery F ^a  

^a MCMASTER UNIVERSITY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33845557536     PISSN: 00201669     EISSN: 1520510X     Source Type: Journal    
DOI: 10.1021/ic50225a041     Document Type: Article

References (59)

1. Roesky, H. W.; Bowing, W. G. J. Chem. Soc., Chem. Commun. 1975, 735.
2. Banister, A. J.; Durant, J. A.; Rayment, I.; Shearer, H. M. M. J. Chem. Soc., Dalton Trans. 1976, 929.
3. Hazell, A. C.; Hazell, R. G. Acta Chem. Scand. 1972, 26, 1987.
4. Weidenhammer, K.; Ziegler, M. L. Z. Anorg. Allg. Chem. 1977, 434, 152.
5. Guru Row, T. N.; Coppens, P. Inorg. Chem. 1978, 17, 1670.
6. Mayerle, J. J.; Wolmershauser, G.; Street, G. B. Inorg. Chem. 1979, IS, 1161.
7. Ziegler, M. L.; Schlimper, H. U.; Nuber, B.; Weiss, J.; Ertl, G. Z. Anorg. Allg. Chem. 1975, 415, 193.
8. Kruss, B.; Ziegler, M. L. Z. Naturforsch, B: Anorg. Chem., Org. Chem. 1972, 27B, 1282.
9. Kruss, B.; Ziegler, M. L. Z. Anorg. Allg. Chem. 1972, 3S8, 158.
10. Gillespie, R. J.; Slim, D. R.; Tyrer, J. D. J. Chem. Soc., Chem. Commun. 1977, 253.
11. Gillespie, R. J.; Kent, J. P.; Sawyer, J. F.; Slim, D. R.; Tyrer, J. D. Inorg. Chem., in press.
12. Banister, A. J.; Clarke, H. G.; Rayment, I.; Shearer, H.M.M.M. Inorg. Nucl. Chem. Lett. 1974, 10, 647.
13. Paul, R. C.; Sharma, R. P.; Verma, R. D. Indian J. Chem. 1974, 12, 418.
14. Krebs, B.; Henken, G.; Pohl, S.; Roesky, H. W. Chem. Ber. 1980, 113, 226.
15. Roesky, H. W.; Hamza, A. Angew Chem., Int. Ed. Engl. 1976, 15, 226.
16. Gillespie, R. J.; Ireland, P. R.; Vekris, J. E. Can. J. Chem. 1975, 53, 3147.
17. Gillespie, R. J.; Kent, J. P.; Sawyer, J. F. Inorg. Chem., in press.
18. Barr, J.; Gillespie, R. J.; Thompson, R. C. Inorg. Chem. 1964, 3, 1149.
19. Becke-Goehring, M. Inorg. Synth. 1960, 6, 123.
20. Dean, P. A. W.; Gillespie, R. J.; Ummat, P. K. Inorg. Synth. 1974, 15, 213.
21. Cell found: orthorhombic, Pnma, a = 8.955 (2) Å, b = 5.981 (1) Å, c = 7.519 (2) A. V = 402.7 (1) A3. Literature [O’Sullivan, K.; Thompson, R. C.; Trotter, J. J. Chem. Soc. A 1970, 1814]: orthorhombic, Pnma, a = 8.972 (10) k, b = 5.996 (10) A. c = 7.542 (10) A. V = 405.7 A3.
22. Unit cell found: orthorhombic, Pbca, a = 8.061 (3) k, b = 8.107 (5) A. c = 9.209 (3) A. V= 601.9 (5) A3. Literature [Bats, J. W.; Coppens, P.; Koetzle, T. F. Acta Crystallogr., Sect. B 1977, B33, 37]: a = 8.034 k, b = 8.030 (1) A. c = 9.236 (2) A. V = 595.1 (2) A3.
23. k, b = 8.030 (1) A. c = 9.236 (2) A. V = 595.1 (2) A3.
24. Unit cell found: S6N4(S03F)2, monoclinic, P2Jn, a = 6.109 (2) A. b = 11.723 (3) A. c = 9.775 (2) A. β = 102.48 (2)°, V= 683.6 (3) A3. Unit cell found: S4N4-S03, monoclinic, Pl\jn, a = 7.173 (2) A. b = 10.451 (2) A. c = 10.782 (2) A. β = 95.79 (2)°, V= 804.17 (33) A3. Literature [Gieren, A.; Deberer, B.; Roesky, H. W.; Amin, N.; Petersen, N. Z. Anorg. Allg. Chem. 1978, 440, 119]: a = 7.175 (3) k, b= 10.456 A. c = 10.769 (4) A. β = 95.30 (4)°, V = 804.5 A3
25. A. c = 10.769 (4) A. β = 95.30 (4)°, V = 804.5 A3
26. Booth, M.; Morton, M. J.; Gillespie, R. J. Adv. Raman Spectrosc. 1972, 1, 364.
27. X-RAY System of crystallographic programs, Technical Report TR-446; Computer Science Centre: University of Maryland, 1976.
28. Sheldrick, G. M. “SHELX System of Crystallographic Programs”; University of Cambridge: Cambridge, 197
29. Dunphy, R. F.; Lau, C.; Lynton, H.; Passmore, J. J. Chem. Soc., Dalton Trans. 1973, 2533.
30. “International Tables for X-ray Crystallography”; Kynoch Press: Birmingham, U.K., 1965.
31. Distinct differences in the magnetic behavior of two forms have been found experimentally: Gillespie, R. J.; Kent, J. P.; Lever, A. B. P., unpublished results.
32. Coppens, P.; Yang, Y. W.; Blessing, R. H.; Cooper, W. F.; Larsen, F. K. J. Am. Chem. Soc. 1977, 99, 760.
33. Foss, O.; Janickis, V. J. Chem. Soc., Chem. Commun. 1977, 834.
34. Gleiter, R.; Bartetzko, R.; Hofmann, P. Z. Nalurforsch., B: Anorg. Chem., Org. Chem. 1980, 35B, 1166.
35. Sletten, J. Acta Chem. Scand., Ser. A 1976, AS0, 397.
36. DeLucia, M. L.; Coppens, P. Inorg. Chem. 1978, 17, 2336.
37. Chivers, T.; Proctor, J. J. Chem. Soc., Chem. Commun. 1978, 642.
38. Roesky, H. W.; Witi, M.; Krebs, B.; Korte, H.-J. Angew Chem., Ini. Ed. Engl. 1979, 18, 415.
39. Chivers, T.; Fielding, L. J. Chem. Soc., Chem. Commun. 1978, 212.
40. Davies, C. G.; Gillespie, R. J.; Park, J. J.; Passmore, J. Inorg. Chem. 1971, 10, 2781.
41. Leitch, J.; Nyburg, S. C.; Armitage, D. A.; Clark, M. J. J. Cryst. Mot. Struct. 1973, 3, 337.
42. Olsen, F. P.; Barrick, J. C. Inorg. Chem. 1973, 12, 1353.
43. Dulmage, W. J.; Meyers, E. A.; Lipscomb, W. N. Acta Crystallogr. 1953, 6, 760.
44. Howie, R.A.; Glasser, L. S. D.; Moser, W. J. Chem. Soc. A 1968, 3043.
45. Capiomont, A.; Chion, B.; Lajzerowicz, J. Acta Crystallogr., Sect. B 1971, B27, 322.
46. Prout, C. K.; Wright, J. D. Angev Chem. 1968, 7, 659.
47. Alcock, N. W. Adv. Inorg. Chem. Radiochem. 1973, 15, 1.
48. Hordvik, A. Q. Rep. Sulfur Chem. 1970, 5, 21
49. Zalkin, A.; Hopkins, T. E.; Templeton, D. H. Inorg. Chem. 1966, 5, 1767.
50. Mayerle, J. J.; Kuyper, J.; Street, G. B. Inorg. Chem. 1978, 17, 2610.
51. Andersen, O.; Hazell, A. C.; Hazell, R. G. Acta Crystallogr., Sect. B 1977, B33, 1109. See also: Heath, G. A.; Murray-Rust, P.; Murray-Rust, J. Inorg. Chem. 1977, B33, 1209.
52. Rosenfield, R. E.; Parthasarathy, R.; Dunitz, J. D. J. Am. Chem. Soc. 1977, 99, 4860.
53. Gainer, G.; Kruger, G. J. Acta Crystallogr., Sect. B 1974, B30, 250.
54. Coppens, P.; Moss, G.; Guru Row, T. N. Inorg. Chem. 1980, 19, 2396.
55. For comparison the Sb-Cl distances in K2SbCl are 2.385 (2) (axial), 2.633 (2), 2.625 (2), 2.799 (2) and 2.509 (2) A (basal): Wismer, R. K.; Jacobson, R. A. Inorg. Chem. 1974, 13, 1678.
56. Kvick, A.; Johnson, P.-R.; Olovsson, I. Inorg. Chem. 1969, 8, 2775.
57. Steudel, R.; Rose, F.; Reinhardt, R.; Bradaczek, H. Z. Naturforsch., B\ Anorg. Chem., Org. Chem. 1977, 32B, 488.
58. Zak, Z.; Kosicka, M. Acta Crystallogr., Sect. B 1978, B34, 38.
59. Jones, P. G.; Kennard, O. Acta Crystallogr., Sect. B 1978, B34, 335.