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6
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33947306589
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Strictly speaking, for bond-making and bond-breaking reactions, eq 2 is an approximation to Marcus' hyperbolic tangent equation. See eq 35 of
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Strictly speaking, for bond-making and bond-breaking reactions, eq 2 is an approximation to Marcus' hyperbolic tangent equation. See eq 35 of: Marcus, R. A. J. Phys. Chem. 1968, 72, 891.
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For various explanations of the anomalous α values, see
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More O'Ferrall, R. A. In “Proton Transfer Reactions”; Caldin, E., Gold, V., Eds.; Chapman and Hall: London, 1975.
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For a theoretical analysis, see
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For a theoretical analysis, see: Shaik, S. J. am. Chem. Soc. 1981, 103, 3692.
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For recent reviews, see: Epiotis, N. D.; Shaik, S.; Zander, W. In “Rearrangements in Ground and Excited States”; De Mayo, P., Ed.; Academic Press: New York, 1980.
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For a recent application to electron transfer and nucleophilic attack on peroxides, see
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For a recent application to electron transfer and nucleophilic attack on peroxides, see: Walling, C. J. Am. Chem. Soc. 1980, 102, 6854.
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