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Volumn 22, Issue 6, 1983, Pages 888-891

Metal Complexes with Tetrapyrrole Ligands. 30. The Manganese-Nitrogen Triple Bond. Synthesis and Molecular Stereochemistry of (545-Dimethyl-2,3,5,8,12,13,17,18-octaethyl-5H,15H-porphinato)ntriidomanganese(V)

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EID: 33845550840     PISSN: 00201669     EISSN: 1520510X     Source Type: Journal    
DOI: 10.1021/ic00148a010     Document Type: Article
Times cited : (94)

References (40)
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    • Technische Hochschule Darmstadt
    • Technische Hochschule Darmstadt.
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    • University of Notre Dame
    • University of Notre Dame.
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    • The Porphyrins
    • Dolphin, D., Ed.; Academic Press: New York
    • Buchler, J. W. In “The Porphyrins”; Dolphin, D., Ed.; Academic Press: New York, 1978; Vol. I, pp. 440-444.
    • (1978) , vol.1 , pp. 440-444
    • Buchler, J.W.1
  • 7
    • 85012365327 scopus 로고    scopus 로고
    • Abbreviations used: TPP, the dianion of mero-tetraphenylporphyrin; OEP, the dianion of octaethylporphyrin; TTP, the dianion of meso-tetra-p-tolylporphyrin; OEPMe2, the dianion of 5, 15-dimethyl-2, 3,7, 8,12, 13, 17, 18-octaethylporpnodimethene; Me, methyl; Np, nitrogen atom of a porphyrin or porphodimethene ligand; py, pyridine
    • Abbreviations used: TPP, the dianion of mero-tetraphenylporphyrin; OEP, the dianion of octaethylporphyrin; TTP, the dianion of meso-tetra-p-tolylporphyrin; OEPMe2, the dianion of 5, 15-dimethyl-2, 3,7, 8,12, 13, 17, 18-octaethylporpnodimethene; Me, methyl; Np, nitrogen atom of a porphyrin or porphodimethene ligand; py, pyridine.
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    • (a), (b) Hoffman, B. M.; Weschler, C. J.; Basolo, F. J. Am. Chem. Soc. 1976, 98, 5473-5481.
    • (a) Weschler, C.J.; Hoffman, B. M.; Basolo, F. J. Am. Chem. Soc. 1975, 97, 5278-5280. (b) Hoffman, B. M.; Weschler, C. J.; Basolo, F. J. Am. Chem. Soc. 1976, 98, 5473-5481.
    • (1975) J. Am. Chem. Soc. , vol.97 , pp. 5278-5280
    • Weschler, C.J.1    Hoffman, B.M.2    Basolo, F.3
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    • Paper IN 109 presented at the 28th Congress on the International Union of Pure and Applied Chemistry
    • Vancouver, B.C. Canada, August 18
    • Hill, C. L. Paper IN 109 presented at the 28th Congress on the International Union of Pure and Applied Chemistry, Vancouver, B.C. Canada, August 18, 1981.
    • (1981)
    • Hill, C.L.1
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    • (a), Angew. Chem., Int. Ed. Engl. 1981, 20, 413-426. (b) Arshankow, S. I.; Poznjak, A. L. Z. Anorg. Allg. Chem. 1981, 481, 201-206.
    • (a) Dehnicke, K.; Strahle, J. Angew. Chem. 1981, 93, 451-464; Angew. Chem., Int. Ed. Engl. 1981, 20, 413-426. (b) Arshankow, S. I.; Poznjak, A. L. Z. Anorg. Allg. Chem. 1981, 481, 201-206.
    • (1981) Angew. Chem. , vol.93 , pp. 451-464
    • Dehnicke, K.1    Strahle, J.2
  • 27
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    • Programs used in this study included local modifications of Jacobson's alff and alls, Busing and Levy's orffe and orfls, and Johnson's ortem2. Atomic form factors were from: Cromer, D. T.; Mann, J. B. Acta Crystallogr., Sect. A 1968, 24, 321-323 (with real and imaginary corrections for anomalous dispersion in the form factor of the manganese atom from: Cromer, D. T.; Liberman, D. J. J. Chem. Phys. 1970, 53, 1891-1898). Scattering factors for hydrogen were from
    • Programs used in this study included local modifications of Jacobson's alff and alls, Busing and Levy's orffe and orfls, and Johnson's ortem2. Atomic form factors were from: Cromer, D. T.; Mann, J. B. Acta Crystallogr., Sect. A 1968, 24, 321-323 (with real and imaginary corrections for anomalous dispersion in the form factor of the manganese atom from: Cromer, D. T.; Liberman, D. J. J. Chem. Phys. 1970, 53, 1891-1898). Scattering factors for hydrogen were from: Stewart, R. F.; Davidson, E. R.; Simpson, W. T. J. Chem. Phys. 1965, 42, 3175-3187.
    • (1965) J. Chem. Phys. , vol.42 , pp. 3175-3187
    • Stewart, R.F.1    Davidson, E.R.2    Simpson, W.T.3
  • 32
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    • The titanium(IV) atom is displaced 0.58 Å from the N4 plane and 0.79 A from the mean plane of the core. See ref 24
    • The titanium(IV) atom is displaced 0.58 Å from the N4 plane and 0.79 A from the mean plane of the core. See ref 24.


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