Reaction between Hydroxylamine and Molybdate(VI): Preparation of the Complexes [Mo(NO)(CN)5]2-, [Mo(NO)(H2NO)Cl4]2-, and [Mo(NO)(H2NO)(N3)4]2-. Crystal Structure of [(C6H5)4P]2[Mo(NO)(H2NO)(N3)4]-H2O

Inorganic Chemistry

Volumn 22, Issue 8, 1983, Pages 1221-1224

  Wieghardt, Karl ^a   Backes Dahmann, Gabriele ^a   Swiridoff, Wolfgang ^a   Weiss, Johannes ^b  

^a RUHR UNIVERSITY BOCHUM   (Germany)

^b UNIVERSITY OF HEIDELBERG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33845549981     PISSN: 00201669     EISSN: 1520510X     Source Type: Journal    
DOI: 10.1021/ic00150a016     Document Type: Article

References (21)

1. (a) Ruhr-Universität Bochum. (b) University of Heidelberg.
2. Wieghardt, K.; Holzbach, W.; Weiss, J.; Nuber, B.; Prikner, B. Angew. Chem. 1979, 91, 582; Angew. Chem., Int. Ed. Engl. 1979, 18, 548.
3. Wieghardt, K.; Holzbach, W.; Nuber, B.; Weiss, J. Chem. Ber. 1979, 113, 629.
4. Mflller, A.; Sarkar, S.; Mohan, N.; Bhattacharya, R. G. Inorg. Chim. Acta 1980, 45, L245.
5. Mttller, A.; Mohan, N. Z. Anorg. Allg. Chem. 1981, 480, 157.
6. Lassner, E. J. Less-Common Met. 1968, 15, 143.
7. Enemark, J.H.; Feltham, R. D. Coord. Chem. Rev. 1974, 13, 339.
8. Computations were carried out on a NOVA3 (General Data) computer using shelxtl (Revision 3.0, July 1981) by G. M. Sheldrick, University Gottingen.
9. Wieghardt, K.; Holzbach, W. Angew. Chem. 1979, 91, 583; Angew. Chem., Int. Ed. Engl. 1979, 18, 549.
10. Heide, K.; Hofmann, K. A. Z. Anorg. Allg. Chem. 1896, 12, 277.
11. Svedung, D.H.; Vannerberg, N. G. Acta Chem. Scand. 1968, 22, 1551.
12. Sarkar, S.; Miiller, A. Z. Naturforsch., B: Anorg. Chem., Org. Chem. 1978, 33B, 1053.
13. The reaction of MoG42-with hydroxylamine in concentrated hydrochloric acid is reported to give Cs2[Mo(NO)Cl5]; see ref 12, footnote 5.
14. Sarkar, S.; Miiller, A. Angew. Chem. 1977, 89, 189; Angew. Chem., Int. Ed. Engl. 1977, 16, 183.
15. Hejmo, E.; Jakob, W.; Kanas, A. Rocz. Chem. 1968, 42, 965.
16. Wieghardt, K.; Holzbach, W.; Weiss, J. Inorg. Chem. 1981, 20, 3436.
17. Miiller, U. Struct. Bonding (Berlin) 1973, 14, 141.
18. Schweda, E.; Strahle, J. Z. Naturforsch., B: Anorg. Chem., Org. Chem. 1980, 35B, 1146.
19. Dehnicke, K.; Schmitte, J. Z. Naturforsch., B: Anorg. Chem., Org. Chem. 1980, 35B, 1070.
20. Nuber, B.; Weiss, J. Acta Crystaliogr., Sect. B 1981, B37, 947.
21. Adrian, H.W.W.; van Tets, A. Acta Crystaliogr., Sect. B 1979, B35, 153.