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33845508776
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note
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Catalyst loadings were not less than 1 mol% in all cases except those reported in references [10b] and [11a].
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21
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0009910435
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Compound 2a can be synthesized from benzonitrile in one step: Y. H. Suen, A. Horeau, H. B. Kagan, Bull. Soc. Chim. Fr. 1965, 5, 1454.
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Hamada, T.1
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23
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2542556554
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This complex was successfully employed as a catalyst for nucleophilic additions to acylimines. a) S. Kobayashi, H. Kiyohara, Y. Nakamura, R. Matsubara, J. Am. Chem. Soc. 2004, 126, 6558;
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24
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4544280305
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b) R. Matsubara, Y. Nakamura, S. Kobayashi, Angew. Chem. 2004, 116, 1711;
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Matsubara, R.1
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26
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c) S. Kobayashi, R. Matsubara, Y. Nakamura, H. Kitagawa, M. Sugiura, J. Am. Chem. Soc. 2003, 225, 2507.
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27
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33845483422
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note
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After screening various ligands, such as diamines bearing 1,2-diphenylethylenediamine and 1,2-dicyclohexane diamine back-bones, ligand 3b was found to be the best.
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28
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33845474452
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note
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4. See the Supporting Information for details.
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29
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33745110538
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and references therein
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S. R. S. S. Kotti, C. Timmons, G. Li, Chem. Biol. Drug Des. 2006, 67, 101, and references therein.
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Kotti, S.R.S.S.1
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30
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33845478516
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note
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Contrary to this result, in reference [6] the sense of asymmetric induction is dependent on the geometry of the silicon enolates.
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31
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33845491863
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a) R. Matsubara, N. Kawai, S. Kobayashi, Angew. Chem. 2006, 118, 3898;
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4544361660
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b) R. Matsubara, P. Vital, Y. Nakamura, H. Kiyohara, S. Kobayashi, Tetrahedron 2004, 60, 9769;
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Matsubara, R.1
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