A general strategy for synthesis of both (6Z)- and (6E)-cladiellin diterpenes: Total syntheses of (-)-cladiella-6,11-dien-3-ol, (+)-polyanthellin A, (-)-cladiell-11-ene-3,6,7-triol, and (-)-deacetoxyalcyonin acetate

Journal of the American Chemical Society

Volumn 128, Issue 49, 2006, Pages 15851-15855

  Kim, Hyoungsu ^a   Lee, Hyunjoo ^a   Kim, Jayoung ^a   Kim, Sanghee ^a   Kim, Deukjoon ^a  

^a Seoul National University   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYLATION; ESTERS; MOLECULAR DYNAMICS; SYNTHESIS (CHEMICAL);

CLADIELLIN DITERPENES; DEACETOXYALCYONIN ACETATES; INTRAMOLECULAR AMIDE ENOLATE ALKYLATION; INTRAMOLECULAR DIELS-ALDER STRATEGY;

OLEFINS;

AMIDE; CLADIELL 11 ENE 3,6,7 TRIOL; CLADIELLA 6,11 DIEN 3 OL; CLADIELLIN DITERPENE; DEACETOXYALCYONIN ACETATE; DITERPENE; POLYANTHELLIN A;

ALKYLATION; ARTICLE; CHLORINATION; CYCLIZATION; DESILYLATION; DIELS ALDER REACTION; DRUG STRUCTURE; DRUG SYNTHESIS; OXIDATION; PROTON NUCLEAR MAGNETIC RESONANCE; STEREOCHEMISTRY;

BRIDGED COMPOUNDS; CYCLIZATION; DITERPENES; FURANS; MODELS, CHEMICAL; STEREOISOMERISM; STEROIDS;

EID: 33845462422     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja065782w     Document Type: Article

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