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Volumn 10, Issue 1, 2007, Pages 109-113

An unique trinuclear triply bridged Cu(II) compound containing double acetato and single azido bridges: Synthesis, X-ray structure and magnetism of [Cu3(dpyam)2(μ1,1-N3) 2(μ-CH3COO- κ-O1)2(μ-CH3COO-κ-O 1,O2)2]

Author keywords

Azide bridges; Copper(II); Crystal structure; Di 2 pyridylamine; EPR; Magnetism

Indexed keywords


EID: 33845419210     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2006.09.015     Document Type: Article
Times cited : (14)

References (44)
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    • Vrieze K., and van Koten G. In: Wilkinson G., Gillard R.D., and McLeverty J.A. (Eds). Comprehensive Coordination Chemistry vol. 2 (1987), Oxford, England 225
    • (1987) Comprehensive Coordination Chemistry , vol.2 , pp. 225
    • Vrieze, K.1    van Koten, G.2
  • 25
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    • note
    • -1.
  • 26
    • 33845438877 scopus 로고    scopus 로고
    • note
    • 2 with anisotropic thermal parameters for all non-hydrogen atoms using the SHELXTL-PC [23] software package. All hydrogen atoms were located and refined isotropically, except H3, H4 of the dpyam ligand and three H atoms of acetate anion which were fixed geometrically with the HFIX utility. The molecular graphics were created by using SHELXTL-PC [23]. CCDC No. 616472. See http://www.ccdc.cam.ac.uk for crystallographic data in CIF format.
  • 32
    • 33845406556 scopus 로고    scopus 로고
    • note
    • -1. The X-band powder EPR spectra were obtained as polycrystalline samples with a JEOL RE2X electron spin resonance spectrophotometer with DPPH (g = 2.0036) as a reference. Magnetic susceptibility measurements (5-300 K) were carried out using a Quantum design MPMS-5S SQUID magnetometer (measurements carried out at 0.1 mT). Data were corrected for magnetization of the sample holder and for diamagnetic contributions, which were estimated from the Pascal constants.
  • 33
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    • Wilkinson G., Gill R.D., and McCleverty J.A. (Eds), Pergamon Press, Oxford
    • Hathaway B.J. In: Wilkinson G., Gill R.D., and McCleverty J.A. (Eds). Comprehensive Coordination Chemistry vol. 5 (1987), Pergamon Press, Oxford
    • (1987) Comprehensive Coordination Chemistry , vol.5
    • Hathaway, B.J.1
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    • Siemens. SAINT. 1996, Version 4 Software Reference Manual, Siemens Analytical X-ray Systems, Inc., Madison, WI, USA.
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    • Bruker. XSHELL. 1999, Version 6.12 Reference Manual, Bruker AXS, Inc., Madison, WI, USA.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.