1,1'-Bis[ (alkyl/aryl)phosphino]ferrocenes: Synthesis and Metal Complex Formation. Crystal Structure of Three Metal Complexes of Fe(η5-C5H4PPh2)2

Organometallics

Volumn 4, Issue 6, 1985, Pages 972-980

  Butler, Ian R ^a   Cullen, William R ^a   Kim, Tae Jeong ^a   Rettig, Steven J ^a   Trotter, James ^a  

^a UNIVERSITY OF BRITISH COLUMBIA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33845379620     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om00125a003     Document Type: Article

References (43)

1. (a) Cullen, W. R.; Woollins, J. D. Coord. Chem. Rev. 1982, 39, 1. (b) Hayashi, T.; Kumada, M. Acc. Chem. Res. 1982, 15, 395. (c) Hayashi, T.; Mise, T.; Fukushima, M.; Kagotani, M.; Nagashima, N.; Hamada, Y.; Matsomoto, A.; Kawakami, S.; Konishi, M.; Yamamoto, K.; Kumada, M. Bull. Chem. Soc. Jpn. 1980, 53, 1138.
2. Yamamoto, K.; Watatsuki, J.; Sugimoto, R. Bull. Chem. Soc. Jpn. 1980, 53, 1132.
3. Cullen, W. R.; Woollins, J. D. Can. J. Chem. 1982, 60, 1793.
4. Cullen, W. R.; Einstein, F. W. B.; Jones, T.; Kim, T.-J. Organometallics 1983, 2, 714.
5. Cullen, W. R.; Kim, T.-J.; Einstein, F. W. B.; Jones, T. Organometallics 1985, 4, 346.
6. (a) Rodgers, G. E.; Cullen, W. R.; James, B. R. Can. J. Chem. 1983, 61, 1314. (b) Cullen, W. R.; Han, N.-F., unpublished results.
7. Cullen, W. R.; Appleton, T. D.; Evans, S. V.; Kim, T. J.; Trotter, J. T. J. Organomet. Chem. 1985, 279, 5.
8. Kumada, M. Pure Appl. Chem. 1980, 52, 669.
9. Hayashi, T.; Konishi, M.; Fukushima, M.; Mise, T.; Kagotani, M.; Tajika, M.; Kumada, M. J. Am. Chem. Soc. 1982, 104, 189.
10. Hayashi, T.; Konishi, M.; Ito, H.; Kumada, M. J. Am. Chem. Soc. 1982, 104, 4962.
11. Hayashi, T.; Konishi, M.; Kobori, Y.; Kumada, M.; Higuchi, T.; Hirotsu, K. J. Am. Chem. Soc. 1984, 106, 158.
12. (a) Davison, A.; Bishop, J. J. Inorg. Chem. 1971, 10, 826. (b) Davison, A.; Bishop, J. J. J. Chem. Phys. 1971, 10, 832. (c) Rudie, A. W.; Lichtenberg, D. W.; Katcher, M. L.; Davison, A. Inorg. Chem. 1978, 17, 2859. (d) Bishop, J. J.; Davison, A.; Katcher, M. L.; Lientenberg, D. W.; Merrill, R. E.; Smart, J. C. J. Organomet. Chem. 1971, 27, 241.
13. (a) Hayashi, T.; Mise, T.; Kumada, M. Tetrahedron. Lett. 1976, 4351. (b) Hayashi, T.; Mise, T.; Kumada, M. J. Chem. Phys. 1979, 425. (c) Hayashi, T.; Konishi, M.; Kumada, M. J. Organomet. Chem. 1980, 186, Cl. (d) Hayashi, T.; Tamoao, K.; Katsuro, Y.; Nakae, I.; Kumada, M. Tetrahedron. Lett. 1980, 1871.
14. Mague, J. T.; Nutt, M. O. Inorg. Chem. 1977, 16, 1259.
15. Pierport, C. G.; Aisenberg, R. Inorg. Chem. 1972, 11, 828.
16. Seyferth, D. M.; Withers, H. P. Organometallics 1982, 1, 1275.
17. Schrock, R. R.; Osborn, J. A. J. Am. Chem. Soc. 1976, 98, 2143.
18. The computer programs used include locally written programs for data processing and locally modified versions of the following: ORFLS, full-matrix least-squares and Orffe, function and errors, by W. R. Busing, K. 0. Martin, and H. A. Levy; FORDAP, Patterson and Fourier syntheses, by A. Zalkin; Ortepii, illustration, by C. K. Johnson.
19. Coppens, P.; Leiserowitz, L.; Rabinovich, D. Acta Crystallogr. 1965, 18, 1035.
20. Busing, W. R.; Levy, H. A. Acta Crystallogr. 1967, 22, 457.
21. Cromer, D. T.; Mann, J. B. Acta Crystallogr., Sect. A 1968, A24, 321.
22. Stewart, R. F.; Davidson, E. R.; Simpson, W. T. J. Chem. Phys. 1965, 42, 3175.
23. Cromer, D. T.; Liberman, D. J. Chem. Phys. 1970, 53, 1891.
24. Becker, P. J.; Coppens, P. Acta Crystallogr., Sect. A 1974, A30, 129; 1974, A30, 148; 1975, A31, 417.
25. Coppens, P.; Hamilton, W. C. Acta Crystallogr., Sect. A 1970, A26, 71.
26. Thornley, F. R.; Nelmes, R. J. Acta Crystallogr., Sect. A 1974, A30, 748.
27. Mari, A.; Gleizes, A.; Dartiguenave, M.; Dartiguenave, Y. Inorg. Chim. Acta 1981, 52, 83.
28. Jarvis, J. A. J.; Mais, R. H. B.; Owston, P. G. J. Chem. Soc. A 1968, 1473.
29. Kilbourn, B. T.; Powell, H. M. J. Chem. Soc. A 1970, 1688.
30. Morandini, F.; Consiglio, G.; Piccolo, O. Inorg. Chim. Acta 1982, 52, 15.
31. Butler, I. R.; Cullen, W. R.; Einstein, F. W. B.; Rettig, S. J.; Willis, A. J. Organometallics 1983, 2, 128.
32. Rosenblum, M.; Banerjee, A. K.; Danieli, N.; Fish, R. W.; Schlatter, V. J. Am. Chem. Soc. 1963, 85, 316.
33. Bernal, I.; Davis, B. R. J. Cryst. Mol. Struct. 1972, 2, 107.
34. Osborne, A. G.; Hollands, R. E.; Howard, J. A. K.; Bryan, R. F. J. Organomet. Chem. 1981, 205, 395.
35. Bishop, J. J.; Davison, A. Inorg. Chem. 1971, 10, 826.
36. (a) Davison, A.; Smart, J. C. J. Organomet. Chem. 1979, 174, 321. (b) Abel, E. W.; Booth, M.; Orrell, K. G. J. Organomet. Chem. 1981, 208, 213. (c) Abel, E. W.; Booth, M.; Brown, C. A.; Orrell, K. G.; Woodford, R. L. J. Organomet. Chem. 1981, 214, 93.
37. Sollott, G. P.; Mertway, H. H.; Portnoy, S.; Snead, J. L. J. Org. Chem. 1963, 28, 1040.
38. +).
39. 2 as in eq 2.
40. (a) Butler, I. R.; Cullen, W. R. Can. J. Chem. 1983, 61, 147. (b) Withers, H. P.; Seyferth, D.; Fellmann, J. D.; Garrow, P. E. Organometallics 1982, 1, 1283.
41. Distinction between the isomers of 6 was made on the basis of the crystal structures of the derivatives (Rh(L-L)NBD] CLO, 4,., 45, [(L-L)HR-h(H), 3, RhH(L-L)] CLO, 4,., 45, The ligand is the rac isomer in both cases.
42. Butler, I. R.; Cullen, W. R.; Kim, T.-J.; Einstein, F. W. B.; Willis, A. J. J. Chem. Soc., Chem. Commun. 1984, 719.
43. The NMR spectra in Table V are qualitatively all as expected. Because some ligands have low symmetry, extensive decoupling experiments would be required for precise assignments to be made.