Magnesiate Ions in Solutions and Solids Prepared from Dialkylmagnesium Compounds and Cryptands

Journal of the American Chemical Society

Volumn 107, Issue 2, 1985, Pages 432-435

  Squiller, Edward P ^a   Whittle, Robert R ^a   Richey, Herman G ^a  

^a PENNSYLVANIA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33845377870     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00288a026     Document Type: Article

References (10)

1. Richey, H. G., Jr.; King, B. A. J. Am. Chem. Soc. 1982, 104, 4672.
2. Thoennes, D.; Weiss, E. Chem. Ber. 1978, 111, 3726.
3. Weiss, E. J. Organomet. Chem. 1965, 4, 101. For dimethylmagnesium, the ring bond angles are 105 (2)° and 75 (2)° and the Mg-Mg distance is 2.72 (2) Å [Weiss, E. J. Organomet. Chem. 1964, 2, 314].
4. Vranka, R. G.; Amma, E. L. J. Am. Chem. Soc. 1967, 89, 3121.
5. Mortier, W. J.; Pluth, J. J.; Smith, J. V. Nature (London) 1975, 256, 718.
6. Structures containing trivalent magnesium have been proposed for a number of species in solution. For a review see: Pinkus, A. G. Coord. Chem. Rev. 1978, 25, 173.
7. Almenningen, A.; Halvorsen, S.; Haaland, A. J. Chem. Soc., Chem. Commun. 1969, 644.
8. Ashby, E. C.; Fernholt, L.; Haaland, A.; Seip, R.; Smith, R. S. Acta Chem. Scand., Ser. A 1980, 34, 213.
9. Owen, J. D. J. Chem. Soc., Dalton Trans. 1978, 1418.
10. 2_in a crystal: Passer, E.; White, J. G.; Cheng, K. L. Inorg. Chim. Acta 1977, 24, 13.