Relative Importance of Dissociative Loss of Carbon Monoxide and Formation of Benzyl Radicals from Photoexcitation of (η5-C5R5)Fe(CO)2(η1-CH2C6H5) and Evidence for Reaction of Carbon Monoxide with 17-Electron Radicals

Journal of the American Chemical Society

Volumn 107, Issue 9, 1985, Pages 2694-2702

  Blaha, Josephine Paw ^a   Wrighton, Mark S ^a  

^a MASSACHUSETTS INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33845376638     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00295a023     Document Type: Article

References (28)

1. Nelson, G. O.; Wright, M. E. J. Organomet. Chem. 1980, 206, C21; 1982, 239, 353.
2. Nesmeyanov, A. V.; Chenskaya, T. B.; Babakhina, G. N.; Kritskaya, I. I. Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.) 1970, 1129.
3. Kazlauskas, R. J.; Wrighton, M. S. Organometallics 1982, 1, 602.
4. Alt, H. G.; Herberhold, M.; Rausch, M. D.; Edwards, B. H. Z. Naturforsch., B 1979, 34, 1070.
5. Faller, J. W.; Anderson, A. S. J. Am. Chem. Soc. 1969, 91, 1550.
6. Fish, R. W.; Giering, W. P.; Marten, D.; Rosenblum, M. J. Organomet. Chem. 1976, 105, 111.
7. Sim, G. A.; Woodhouse, D. I.; Knox, G. R. J. Chem. Soc., Dalton Trans. 1979, 629.
8. Fettes, D. J.; Narayanaswamy, R.; Rest, A. J. J. Chem. Soc., Dalton Trans. 1981, 2311.
9. Bibler, J. P.; Wojcicki, A. J. Am. Chem. Soc. 1966, 88, 4862.
10. King, R. B.; Igbal, M. Z.; King, A. D., Jr. J. Organomet. Chem. 1979, 171, 53.
11. (a) Abrahamson, H. B.; Wrighton, M. S. J. Am. Chem. Soc. 1977, 99, 5510. (b) Abrahamson, H. B.; Wrighton, M. S. Inorg. Chem. 1978, 17, 1003.
12. Manriquez, J. M.; Fagan, P. J.; Schertz, L. D.; Marks, T. J. “Inorganic Syntheses”; Fackler, J. P., Jr., Ed.; John Wiley and Sons: New York, 1982; Vol. 21.
13. Moses, F. G.; Liu, R. S. H.; Monroe, B. M. Mol. Photochem. 1969, 1, 245.
14. Hatchard, C. G.; Parker, C. A. Proc. R. Soc. London, Ser. A 1956, 235, 518.
15. Silverman, L. D.; Dewan, J. C.; Giandomenico, C. M.; Lippard, S. J. Inorg. Chem. 1980, 19, 3379.
16. -1 ± 20%; Pope, K. R.; Wrighton, M. S., Inorg. Chem., in press.
17. (a) Becker, Y.; Stille, J. K. J. Am. Chem. Soc. 1978, 100, 845. (b) Severson, R. G.; Wojcicki, A. J. Organomet. Chem. 1978, 157, 173.
18. Kazlauskas, R. J.; Wrighton, M. S. J. Am. Chem. Soc. 1982, 104, 6005.
19. Geoffroy, G. O.; Wrighton, M. S. “Organometallic Photochemistry”; Academic Press: New York, 1979.
20. (a) Busch, M. A.; Clark, R. J. Inorg. Chem. 1975, 14, 219. (b) Davidson, G. Inorg. Chim. Acta 1969, 3, 596.
21. Whitesides, T. H.; Shelley, J. Organomet. Chem. 1975, 92, 215.
22. Blaha, J. P.; Wrighton, M. S., unpublished results.
23. Gerhartz, W.; Ellerhorst, G.; Dahler, P.; Eilbracht, P. Liebigs Ann. Chem. 1980, 1296.
24. (a) Wrighton, M. S.; Ginley, D. S. J. Am. Chem. Soc. 1975, 97, 2065. (b) Kidd, D. R.; Brown, T. L. J. Am. Chem. Soc. 1978, 100, 4095. (c) Beyers, B. H.; Brown, T. L. J. Am. Chem. Soc. 1977, 99, 2527. (d) Absi-Halabi, M.; Brown, T. L. J. Am. Chem. Soc. 1977, 99, 298, 2. (e) Hoffman, N. W.; Brown, T. L. Inorg. Chem. 1978, 17, 613. (f) Fox, A.; Malito, J.; Poe, A. J. J. Chem. Soc., Chem. Commun. 1981, 1052 and references therein. (g) Shi, Q.; Richard, T. G.; Trogler, W. C.; Basolo, F. J. Am. Chem. Soc. 1982, 104, 4032.
25. (a) Fachinetti, G.; Del Nero, S.; Floriani, C. J. Chem. Soc., Dalton Trans. 1976, 203. (b) Benfield, F. W. S.; Green, M. L. H. J. Chem. Soc., Dalton Trans. 1974, 1324.
26. (a) Tyler, D. R.; Schmidt, M. A.; Gray, H. B. J. Am. Chem. Soc. 1983, 105, 6018. (b) Abrahamson, H. B.; Palazzotto, M. C.; Reichel, C. L.; Wrighton, M. S. J. Am. Chem. Soc. 1979, 101, 423.
27. (a) Moore, B. D.; Simpson, M. B.; Poliakoff, M.; Turner, J. J. J. Chem. Soc., Chem. Commun. 1984, 972. (b) Hepp, A. F.; Blaha, J. P.; Lewis, C.; Wrighton, M. S. Organometallics 1984, 174. (c) Hooker, R. H.; Rest, A. J. J. Chem. Soc., Chem. Commun. 1983, 1022. (d) Caspar, J.; Meyer, T. J. J. Am. Chem. Soc. 1980, 102, 7794.
28. (a) Hepp, A. F.; Wrighton, M. S. J. Am. Chem. Soc. 1983, 105, 5934. (b) Hughey, J. L.; Anderson, C. P.; Meyer, T. J. J. Organomet. Chem. 1977, 125, C49. (c) Yasufuku, K.; Yesaka, H.; Kobayashi, T.; Yamazaki, H.; Nakagura, S., presented at the 10th International Conference on Organometallic Chemistry, Toronto, Ontario, August 9–14, 1981. (d) Rothberg, L. J.; Cooper, N. J.; Peters, K. S.; Vaida, V. J. Am. Chem. Soc. 1982, 104, 3536. (e) Dunkin, I. R.; Harter, P.; Shields, C. J. J. Am. Chem. Soc. 1984, 106, 7248. (f) Yesaka, M.; Kobayashi, T.; Yasufuku, K.; Nagakura, S. J. Am. Chem. Soc. 1983, 105, 6249.