Symmetric vs. Asymmetric Linear M-X-M Linkages in Molecules, Polymers, and Extended Networks

Journal of the American Chemical Society

Volumn 108, Issue 9, 1986, Pages 2222-2236

  Wheeler, Ralph A ^a   Hoffmann, Roald ^a   Whangbo, Myung Hwan ^b   Hughbanks, Timothy ^c   Burdett, Jeremy K ^c   Albright, Thomas A ^d  

^a Department of Obstetrics Gynecology   (United States)

^b NORTH CAROLINA STATE UNIVERSITY   (United States)

^c UNIVERSITY OF CHICAGO   (United States)

^d UNIVERSITY OF HOUSTON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33845373759     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00269a018     Document Type: Article

References (131)

1. Taube, H. Chem. Rev. 1952, 50, 69.
2. Taube, H.; Myers, H.; Rich, R.L. J. Am. Chem. Soc. 1953, 75, 4118.
3. Taube, H.; Myers, H. J. Am. Chem. Soc. 1954, 76, 2103.
4. Haim, A. Prog. Inorg. Chem. 1983, 30, 273.
5. Wohler, F. Pogg. Ann. 1824, 2, 350.
6. Goodenough, J.B. Prog. Solid State Chem. 1971, 5, 313.
7. Hagenmuller, P. Prog. Solid State Chem. 1971, 5, 175.
8. Müller, O.; Roy, R. “The Major Ternary Structural Families”; Springer-Verlag: Berlin, 1974; p 174 ff.
9. Galasso, F.S. “Structure Properties, and Preparation of Perovskite-Type Compounds”; Pergamon Press: Oxford, 1969.
10. Triclinic W.; Diehl, R.; Brandt, G.; Salje, E. Acta Crystallogr. 1978, B34, 1105.
11. Monoclinic W.; Loopstra, B.O.; Rietveld, H.M. Acta Crystallogr. 1969, B25, 1420.
12. Orthorhombic W.; Salje, E. Acta Crystallogr. 1977, B33, 574.
13. Straumanis, M.E. J. Am. Chem. Soc. 1949, 71, 679.
14. Frazer, B.C.; Danner, H.R.; Pepinsky, R. Phys. Rev. 1955, 100, 745.
15. Katz, L.; Megaw, H.D. Acta Crystallogr. 1967, 22, 639.
16. Ridgley, D.; Ward, R. J. Am. Chem. Soc. 1955, 77, 6132.
17. Kreiser, R.R.; Ward, R. J. Solid State Chem. 1970, 1, 368.
18. Bither, T.A.; Gillson, J.L.; Young, H.S. Inorg. Chem. 1966, 5, 1559.
19. Goodenough, J.B.; Longo, J.M. in LANDOLT-BORNSTEIN TABELLEN, New Series III/4a; Hellwege, K.H., Hellwege, A.M., Eds.; Springer-Verlag: Berlin, 1970; p 162.
20. Abe, R.; Furuhata, Y.; Ikeda, T.; Makita, Y.; Marutake, M.; Nakamura, E.; Nomura, S.; Sawaguchi, E.; Shiozaki, Y.; Toyoda, K. In LANDOLT-BORNSTEIN TABELLEN, New Series III/3; Hellwege, K.H., Hellwege, A.M., Eds.; Springer-Verlag: Berlin, 1969; p 37.
21. Jona, F.; Shirane, G. “Ferroelectric Crystals”; MacMillan: New York, 1962; Chapters IV and V.
22. Dehnicke, K.; Strähle, J. Angew. Chem. 1981, 93, 451
23. Angew, Chem., Int. Ed. Engl. 1981, 20, 413.
24. Griffith, W.P. Coord. Chem. Rev. 1972, 8, 369.
25. Strähle, J. Z. Anorg. Allg. Chem. 1970, 375, 238.
26. Müller, U.; Kujanek, R.; Dehnicke, K. Z. Anorg. Allg. Chem. 1982, 495, 127.
27. Stráhle, J.; Weiher, U.; Dehnicke, K. Z. Naturforsch. 1978, B33, 1347.
28. Musterle, W.; Strahle, J.; Liebelt, W.; Dehnicke, K. Z. Naturforsch. 1979, B34, 942.
29. Walker, I.; Strähle, J.; Ruschke, P.; Dehnicke, K. Z. Anorg. Allg. Chem. 1982, 487, 26.
30. Liese, W.; Dehnicke, K.; Walker, I.; Strähle, J. Z. Naturforsch. 1980, B35, 776.
31. Noble, M.E.; Folting, K.; Huffman, J.C.; Wentworth, R.A.D. Inorg. Chem. 1982, 21, 3772.
32. Liese, W.; Dehnicke, K.; Walker, I.; Strähle, J. Z. Naturforsch. 1979, B34, 693.
33. Davies, W.O.; Johnson, N.P.; Johnson, P.; Graham, A.J. J. Chem. Soc., Chem. Commun. 1969, 736.
34. Jordan, B.; Calvo, C. Can. J. Chem. 1973, 51, 2621.
35. Longo, J.M.; Arnott, R.J. J. Solid State Chem. 1970, 1, 394.
36. Eick, H.A.; Kihlborg, L. Acta Chem. Scand. 1966, 20, 722.
37. Longo, J.M.; Kierkegaard, P. Acta Chem. Scand. 1966, 20, 72.
38. Longo, J.M.; Pierce, J.W.; Kafalas, J.A. Mater. Res. Bull. 1971, 6, 1157.
39. Kierkegaard, P.; Westerlund, M. Acta Chem. Scand. 1964, 18, 2217.
40. Hoffmann, R.; Lipscomb, W.N. J. Chem. Phys. 1962, 36, 2179, 3489.
41. Hoffmann, R. J. Chem. Phys. 1963, 39, 1397.
42. Glazer, A.M. Acta Crystallogr. 1975, A31, 756.
43. Glazer, A.M. Acta Crystallogr. 1972, B28, 3384.
44. Schrock, R.R.; Listemann, M.L.; Sturgeoff, L.G. J. Am. Chem. Soc. 1982, 104, 4291.
45. Chisholm, M.H.; Hoffman, D.M.; Huffman, J.C. Inorg. Chem. 1983, 22, 2903.
46. Cotton, F.A.; Schwotzer, W.; Shamshoum, E.S. Organometallics 1984, 3, 1770.
47. Chan, D.M.-T.; Chisholm, M.H.; Folting, K.; Huffman, J.C.; Marchant, N.S., private communication. In that complex the MoN distances in the one-dimensional chain are 1.66 and 2.86 A.
48. Elian, M.; Hoffmann, R. Inorg. Chem. 1975, 14, 1058.
49. Chisholm, M.H.; Huffman, J.C.; Marchant, N.S. J. Am. Chem. Soc. 1983, 105, 6162.
50. Liebelt, W.; Dehnicke, K. Z. Naturforsch, 1979, B34, 7.
51. Englman, R. “The Jahn-Teller Effect in Molecules and Crystals”; Wiley-Interscience: New York, 1972.
52. Bersuker, I.B. “The Jahn-Teller Effect and Vibronic Interactions in Modern Chemistry”; Plenum Press: New York, 1984.
53. Burdett, J.K. Appl. Spectrosc.Rev. 1970, 4, 43.
54. Groves, J.T.; Takahashi, T.; Butler, W.M. Inorg. Chem. 1983, 22, 884.
55. Fenske, D.; Liebelt, W.; Dehnicke, K. Z. Anorg. Allg. Chem. 1980, 467, 83.
56. Müller, U.; Schweda, E.; Strähle, J. Z. Naturforsch. 1983, B38, 1299.
57. Knopp, B.; Lorcher, K.-P.; Strahle, J. Z. Naturforsch. 1977, B32, 1361.
58. Dehnicke, K.; Krueger, N.; Kujanek, R.; Weller, F. Z. Kristallogr. 1980, 153, 181.
59. Dehnicke, K.; Schmitte, J.; Fenske, D. Z. Naturforsch. 1980, B35, 1070.
60. Schmitte, J.; Friebel, C.; Weller, F.; Dehnicke, K. Z. Anorg. Allg. Chem. 1982, 495, 148.
61. Schweda, E.; Strahle, J. Z. Naturforsch. 1981, B36, 662.
62. Hill, C.L.; Hollander, F.J. J. Am. Chem. Soc. 1982, 104, 7318.
63. Buchler, J.W.; Dreher, C.; Lay, K.-L.; Lee, Y.J.; Scheidt, W.R. Inorg. Chem. 1983, 22, 888.
64. Baldas, J.; Bonnyman, J.; Pojer, P.M.; Williams, G.A.; Mackay, M.F. J. Chem. Soc., Dalton Trans. 1981, 1798.
65. Kafitz, W.; Weller, F.; Dehnicke, K. Z. Anorg. Allg. Chem. 1982, 490, 175.
66. Liese, W.; Dehnicke, K.; Rogers, R.D.; Shakir, R.; Atwood, J.L. J. Chem. Soc., Dalton Trans. 1981, 1061.
67. Doedens, R.J.; lbers, J.A. Inorg. Chem. 1967, 6, 204.
68. Fletcher, S.R.; Skapski, A.C. J. Chem. Soc., Dalton Trans. 1972, 1079.
69. Fletcher, S.R.; Rowbottom, J.F.; Skapski, A.C.; Wilkinson, G. J. Chem. Soc., Chem. Commun. 1970, 1572.
70. Phillips, F.C.; Skapski, A.C. Acta Crystallogr. 1975, B31, 2667.
71. Collison, D.; Garner, C.D.; Mabbs, F.E. J. Chem. Soc., Dalton Trans. 1981, 1820.
72. Phillips, F.L.; Skapski, A.C. J. Cryst. Mol. Struct. 1975, 5, 83.
73. Collison, D.; Garner, C.D.; Mabbs, F.E.; Salthouse, J.A.; King, T.J. J. Chem. Soc., Dalton Trans. 1981, 1812.
74. Phillips, F.L.; Skapski, A.C.; Withers, M. J. Transition Met. Chem. (Weinheim, Ger.) 1975–1976.
75. Fenske, D.; Kujanek, R.; Dehnicke, K. Z. Anorg. Allg. Chem. 1983, 507, 51.
76. Holmes, R.R. Prog. Inorg. Chem. 1984, 32, 216.
77. Rossi, A.R.; Hoffmann, R. Inorg. Chem. 1975, 14, 365.
78. Albright, T.A. Tetrahedron 1982, 38, 1339.
79. Albright, T.A.; Burdett, J.K.; Whangbo, M.-H. “Orbital Interactions in Chemistry”; John Wiley: New York, 1984; Chapter 17.
80. DuBois, D.L.; Hoffmann, R. Nouv. J. Chim. 1977, 1, 479.
81. Buchler, J.W.; Dreher, C.; Lay, K.-L.; Raap, A.; Gersonde, K. Inorg. Chem. 1983, 22, 879.
82. Lack, G.M.; Gibson, J.F. J. Mol. Struct. 1978, 46, 299.
83. Groves, J.T.; Takahashi, T. J. Am. Chem. Soc. 1983, 105, 2073.
84. Wright, M.J.; Griffith, W.P. Transition Met. Chem. (Weinheim, Ger.) 1982, 1, 53.
85. Pawson, D.; Griffith, W.P. J. Chem. Soc., Dalton Trans. 1975, 417.
86. Pawson, D.; Griffith, W.P. Inorg. Nucl. Chem. Lett. 1974, 10, 253.
87. Griffith, W.P.; Pawson, D. J. Chem. Soc., Chem. Com mun. 1973, 418.
88. Dehnicke, K.; Prinz, H.; Kafitz, W.; Kujanek, R. Liebigs Ann. Chem. 1981, 20.
89. Phillips, F.L.; Skapski, A.C. J. Chem. Soc., Dalton Trans. 1978, 1448.
90. Mronga, N.; Weller, F.; Dehnicke, K. Z. Anorg. Allg. Chem. 1983, 502, 35.
91. Choukroun, R.; Gervais, D.; Dilworth, J.R. Transition Met. Chem. (Weinheim, Ger.) 1978, 81, 4, 249.
92. Dilworth, J.R.; de Liefde Meijer, H.J.; Teuben, J.H. J. Organomet. Chem. 1978, 159, 47.
93. Müller, U.; Dübgen, R.; Dehnicke, K. Z. Anorg. Allg. Chem. 1981, 473, 115.
94. Dübgen, R.; Muller, U.; Weller, F.; Dehnicke, K. Z. Anorg. Allg. Chem. 1980, 471, 89.
95. Bezler, H.; Strähle, J. Z. Naturforsch. 1979, B34, 1199.
96. Scott, D.; Wedd, A.G. J. Chem. Soc., Chem. Commun. 1974, 527.
97. Schweda, E.; Strahle, J. Z. Naturforsch. 1980, B35, 1146.
98. Dilworth, J.R.; Dahlstrom, P.L.; Hyde, J.R.; Zubieta, J. Inorg. Chim. Acta 1983, 71, 21.
99. Baldas, J.; Bonnyman, J.; Williams, G.A. J. Chem. Soc., Dalton Trans. 1984, 833.
100. Kafitz, W.; Dehnicke, K.; Schweda, E.; Strähle, J. Z. Naturforsch. 1984, B39, 1114.
101. de C.T. Carrondo, M.A.A.; Shakir, R.; Skapski, A.C. J. Chem. Soc., Dalton Trans. 1978, 844.
102. Corfield, P.W.R.; Doedens, R.J.; Ibers, J.A. Inorg. Chem. 1967, 6, 197.
103. Bright, D.; Ibers, J.A. Inorg. Chem. 1969, 8, 709.
104. Atovmyan, L.O.; Tkachev, V.V. Zh. Strukt. Khim. 1968, 9, 708
105. J. Struc. Chem. 1968, 9, 618.
106. Atovmyan, L.O.; Tkachev, V.V. Zh. Strukt. Khim. 1970, 11, 933.
107. Struct. Chem. (Engl. Transl.) 1970, 1, 868.
108. Atovmyan, L.O.; Bok, G.B. II, Zh. Strukt. Khim. 1960, 1, 501
109. J. Struct. Chem. (Engl. Transl.) 1960, 1, 468.
110. Tkachev, V.V.; Krasochka, O.N.; Atovmyan, L.O. Zh. Strukt. Khim. 1976, 17, 940
111. J. Struct. Chem. (Engl. Transl.) 1976, 17, 807.
112. Berry, R.S. J. Chem. Phys. 1960, 32, 933.
113. Berry, R.S. Rev. Mod. Phys. 1960, 32, 447.
114. Rappe, A.K. Inorg. Chem. 1984, 23, 995.
115. Hess, H.; Hartung, H. Z. Anorg. Allg. Chem. 1966, 344, 157.
116. Müller, U. Acta Crystallogr. 1984, C40, 915.
117. Edwards, A.J. J. Chem. Soc. 1964, 3714.
118. Münninghoff, G.; Hellner, E.; El Essawi, M.; Dehnicke, K. Z. Kristallogr. 1978, 147, 231.
119. Edwards, A. J. Adv. Inorg. Chem. Radiochem. 1983, 27, 83.
120. Edwards, A.J.; Jones, G.R. J. Chem. Soc. A 1969, 1651.
121. Edwards, A. J. Proc. Chem. Soc. 1963, 205.
122. Edwards, A.J.; Hugill, D.; Peacock, R.D. Nature (London) 1963, 200, 672.
123. Edwards, A.J.; Jones, G.R.; Steventon, B.R. J. Chem. Soc., Chem. Commun. 1967, 462.
124. Edwards, A.J.; Steventon, B.R. J. Chem. Soc. A 1968, 2503.
125. Edwards, A.J.; Jones, G.R. J. Chem. Soc. A 1968, 2511.
126. Hughbanks, T. J. Am. Chem. Soc., submitted for publication.
127. Mattheiss, L.F. Phys. Rev. 1969, 181, 987.
128. Mattheiss, L.F. Phys. Rev. B.: Condens. Matter 1972, 6, 4718.
129. Tatsumi, K.; Hoffmann, R. Inorg. Chem. 1980, 19, 2656.
130. Hoffman, D.M.; Hoffmann, R.; Fisel, C.R. J. Am. Chem. Soc. 1982, 104, 3858.
131. Whangbo, M.-H.; Foshee, M. J. Inorg. Chem. 1981, 20, 113.