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Attention is drawn to the distinction between isomerization, through which the cis- and trans- [LW(CO)4(s)] (6 and 5) are interconverted and fluxionality, which would permute labeled CO groups in each of these species without isomerization. Fluxional processes have been studied extensively through isotopic labeling experiments; for a general review see
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Attention is drawn to the distinction between isomerization, through which the cis- and trans- [LW(CO)4(s)] (6 and 5) are interconverted and fluxionality, which would permute labeled CO groups in each of these species without isomerization. Fluxional processes have been studied extensively through isotopic labeling experiments; for a general review see: Howell, J. A.: Burkinshaw. P. M. Chem. Rev. 1983. 83. 537.
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