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Volumn 109, Issue 14, 1987, Pages 4218-4224

Time-resolved IR Characterization of Cis- andtrans,-[LW(co)4(solvent)] [L = PPh3, P(O-i-pr)3, and P(OEt)3] In n-heptane Solution: The Solvent as a Token Ligand in Short-lived Reaction Intermediates

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EID: 33845281043     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00248a015     Document Type: Article
Times cited : (68)

References (34)
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    • For a review of flash photolysis with infrared detection, see
    • For a review of flash photolysis with infrared detection, see: Poliakoff, M.; Weitz. E. Adv. Organomet. Chem. 1986, 25, 277.
    • (1986) Adv. Organomet. Chem. , vol.25 , pp. 277
    • Poliakoff, M.1    Weitz, E.2
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    • Attention is drawn to the distinction between isomerization, through which the cis- and trans- [LW(CO)4(s)] (6 and 5) are interconverted and fluxionality, which would permute labeled CO groups in each of these species without isomerization. Fluxional processes have been studied extensively through isotopic labeling experiments; for a general review see
    • Attention is drawn to the distinction between isomerization, through which the cis- and trans- [LW(CO)4(s)] (6 and 5) are interconverted and fluxionality, which would permute labeled CO groups in each of these species without isomerization. Fluxional processes have been studied extensively through isotopic labeling experiments; for a general review see: Howell, J. A.: Burkinshaw. P. M. Chem. Rev. 1983. 83. 537.
    • (1983) Chem. Rev. , vol.83 , pp. 537
    • Howell, J.A.1    Burkinshaw, P.M.2


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