Synthesis and Structural Characterization of Pt-Si Dimers with Unusually Short Cross-Ring Silicon-Silicon Interactions

Journal of the American Chemical Society

Volumn 110, Issue 12, 1988, Pages 4068-4070

  Zarate, Eugene A ^a   Tessier Youngs, Claire A ^a   Youngs, Wiley J ^a  

^a CASE WESTERN RESERVE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33845279637     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00220a073     Document Type: Article

References (63)

1. For a recent review, see: West, R. J. Organomet. Chem. 1986, 300, 327–346.
2. Ojima, I.; Inaba, S.-I.; Kogure, T.; Nagai, Y. J. Organomet. Chem. 1973, 55, C7-C8.
3. Yamamoto, K.; Okinoshima, H.; Kumada, M. J. Organomet. Chem. 1971, 27, C31-C32; 1970, 23, C7-C8.
4. Corey, J. Y.; Chang, L. S.; Corey, E. R. Organometallics 1987, 6, 1595–1596.
5. Brown-Wensley, K. A. Organometallics 1987, 6, 1590–1591.
6. Lappert, M. F.; Maskell, R. K. J. Organomet. Chem. 1984, 264, 217–228.
7. Curtis, M. D.; Epstein, R. S. Adv. Organomet. Chem. 1981, 19, 213–255.
8. Petz, W. Chem. Rev. 1986, 86, 1019–1047.
9. Zybill, C.; Müller, G. Angew. Chem., Int. Ed. Engl. 1987, 669–670.
10. Straus, D. A.; Tilley, T. D.; Rheingold, A. L. J. Am. Chem. Soc. 1987, 109, 5872–5873.
11. Aitken, C. T.; Harrod, J. F.; Samuel, E. J. Am. Chem. Soc. 1986, 108, 4059–4066.
12. Aitken, C. T.; Harrod, J. F.; Samuel, E. Can. J. Chem. 1986, 64, 1677–1679.
13. Aitken, C. T.; Harrod, J. F.; Samuel, E. J. Organomet. Chem. 1985, 279, C11–C13.
14. Harrod, J. F.; Yun, S. S. Organometallics 1987, 6, 1381–1387.
15. 3. Its properties were as reported by Jensen (Jensen, K. A., Z. Anorg. Allg. Chem. 1936, 229, 225–281).
16. Gilman. H.; Steudel, W. Chem. Ind. 1959. 1094.
17. Hazeldine, R. N.; Parish, R. V.; Parry, D. J. J. Chem. Soc. A 1969, 683–690.
18. Citron, J. D.; Lyons, J. E.; Sommer, L. H. J. Org. Chem. 1969, 34, 638–640.
19. Citron, J. D. J. Org. Chem. 1969, 34, 1977.
20. Sommer, L. H.; Citron, J. D. J. Org. Chem. 1967, 32, 2470.
21. Watanabe, H.; Okawa, T.; Maraoka, T.; Nagai, Y. Chem. Lett. 1981, 1321–1322.
22. Watanabe, H.; Kato, M.; Okawa, T.; Koguyo, Y.; Nagai, Y. Goto, M.; Appl. Organomet. Chem. 1987, 1, 157–169.
23. Benkeser, R. A.; Yeh, M.-H. J. Organomet. Chem. 1984, 264, 239–244.
24. Aylett, B. J. Adv. Inorg. Chem. Radiochem. 1982, 25, 1–133.
25. Wittenberg, D.; Gilman, H. Quart. Rev. 1959, 13, 116–145.
26. Wiberg, N.; Schuster, H.; Simon, A.; Peters, K. Angew. Chem., Int. Ed. Engl. 1986, 25, 79–80.
27. Watanabe, H.; Kato, M.; Okawa, T.; Nagai, Y.; Goto, M. J. Organomet. Chem. 1984, 271, 225–233.
28. Weidenbruch, M. Comments Inorg. Chem. 1986, 5, 247–261.
29. Auburn, M.; Ciriano, M.; Howard, J. A. K.; Murray, M.; Pugh, N. J.; Spencer, J. L.; Stone, F. G. A.; Woodward, P. J. Chem. Soc., Dalton Trans. 1980, 659–666.
30. Bennet, M. J.; Simpson, K. A. J. Am. Chem. Soc. 1971, 93, 7156.
31. Crozat, M. M.; Watkins, S. F. J. Chem. Soc., Dalton Trans. 1972, 2512–2515.
32. Cowie, M.; Bennett, M. J. Inorg. Chem. 1977, 16, 2321–2325 and 2325–2329.
33. Simon, G. L.; Dahl, L. F. J. Am. Chem. Soc. 1973, 95, 783.
34. Hencken, G.; Weiss, E. Chem. Ber. 1973, 106, 1747–1751.
35. [Cp2TiHSi(Ph)H]24a is unlike any other metal-silicon dimer (Si-Si = 3.820 A, Ti-Ti = 3.890 A, ∠Ti-Si-Ti = 90.40° and 90.88°, and ZSi-Ti-Si = 87.91° and 89.180).21
36. Huheey, J. E. Inorganic Chemistry, 3rd. ed.; Harper & Row: New York, 1983, pp 258–259 (van der Waals radii) and pp A32-A40 (bond lengths).
37. Anderson, A. B.; Shiller, P.; Zarate, E. A.; Tessier-Youngs, C. A.; Youngs, W. J., submitted to J. Am. Chem. Soc.
38. West, R. Angew. Chem., Int. Ed. Engl. 1987, 26, 1201–1211.
39. Fink, M. J.; Michalczyk, M. J.; Hallen, K. J.; West, R.; Michl, J. Organometallics 1984, 3, 793–800.
40. Masamune, S.; Muarkami, S.; Snow, J. T.; Williams, D. J. Organometallics 1984, 3, 333–334.
41. Cotton, F. A.; Kibala, P. A. Polyhedron 1987, 6, 645–646.
42. For a related complex, see: Burns, C. J.; Andersen, R. A. J. Am. Chem. Soc. 1987, 109, 915–917.
43. Grev, R. S.; Schaefer, H. F. J. Am. Chem. Soc. 1987, 109, 6577–6585.
44. Fink, M. J.; Haller, K. J.; West, R.; Michl, J. J. Am. Chem. Soc. 1984, 106, 822–823.
45. Yokelson, H. B.; Millevolte, A. J.; Adams, B. R.; West, R. J. Am. Chem. Soc. 1987, 109, 4116–4118.
46. Schafer, H.; Binder, D.; Fenske, D. Angew. Chem., Int. Ed. Engl. 1985, 24, 522–524.
47. Schafer, H. Z. Naturforsch., B: Anorg. Chem., Org. Chem. 1979, 34, 1358–1361.
48. Hey, E.; Engelhardt, L. M.; Raston, C. L.; White, A. H. Angew. Chem., Int. Ed. Engl. 1987, 26, 81–82.
49. Caminade, A.-M.; Majoral, J.-P.; Sanchez, M.; Mathieu, R.; Attali, S.; Grand, A. Organometallics 1987, 6, 1459–1465.
50. Cowley, A. H.; Norman, N. C. Prog. Inorg. Chem. 1986, 34, 1–63.
51. Cowley, A. H. Polyhedron 1984, 3, 389–432.
52. Holmes, R. R. Prog. Inorg. Chem. 1984, 32, 119–235.
53. For examples of pentacoordinated silicon in transition-metal complexes see ref 10, 18, 21a, and 22b and the following: (a) Schubert, U.; Alt, H. G. Organometallics 1987, 6, 469–472.
54. Smith, R. A.; Bennett, M. J. Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. 1977, 33, 1118–1122.
55. Schubert, U.; Scholz, G.; Muller, J.; Ackermann, K.; Wörle, B.; Stansfield, R. F. D. J. Organomet. Chem. 1986, 306, 303–326.
56. Carrè, F.; Colomer, E.; Corriu, R. J. P.; Vioux, A. Organometallics 1984, 3, 1272–1278.
57. Breliere, C.; Carrè, F.; Cornu, R. J. P.; Poirier, M.; Royo, G. Organometallics 1986, 5, 388.
58. Dabisch, T.; Schoeller, W. W. J. Chem. Soc., Chem. Commun. 1986, 896-898.
59. Schoeller, W. W.; Dabisch, T.; Busch, T. Inorg. Chem, 1987, 26, 4383–4389.
60. Schleyer. P. V. R.; Sax, A. F.; Kalcher, J.; Janos-chck, R. Angew. Chem. Int. Ed. Engl. 1987, 26. 364–366,
61. Collins, S.; Butler, R.; Rauk, A. J. Am. Chem. Soc. 1987, 109, 2564–2569.
62. Nagese, S.; Kudo, T. Organometallics 1987, 6, 2456–2458.
63. Schleyer, P. V. R.; Janoschek, R. Angew. Chem., Int. Ed. Engl. 1987, 26, 1267–1268.