A General Treatment of Hydrogen Bond Complexation Constants in Tetrachloromethane

Journal of the American Chemical Society

Volumn 110, Issue 25, 1988, Pages 8534-8536

  Abraham, Michael H ^a   Grellier, Priscilla L ^a   Prior, David V ^a   Taft, Robert W ^b   Morris, Jeffrey J ^c   Taylor, Peter J ^c   Laurence, Christian ^d   Berthelot, Michel ^d   Doherty, Ruth M ^e   Kamlet, Mortimer J ^e   Abboud, José Luis M ^f   Sraidi, Khadija ^g   Guihéneuf, Georges ^d  

^a UNIVERSITY OF SURREY   (United Kingdom)

^b UNIVERSITY OF CALIFORNIA   (United States)

^c AKZO NOBEL CENTRAL RESEARCH   (Netherlands)

^d UNIVERSITÉ DE NANTES   (France)

^e NAVAL SURFACE WARFARE CENTER   (United States)

^f INSTITUTO DE QUÍMICA FÍSICA ROCASOLANO   (Spain)

^g CADI AYYAD UNIVERSITY   (Morocco)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33845279116     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00233a034     Document Type: Article

References (11)

1. Abraham, M. H.; Duce, P. P.; Grellier, P. L.; Prior, D. V.; Morris, J. J.; Taylor, P. J. Tetrahedron Lett. 1988, 29, 1587.
2. Abraham, M. H.; Grellier, P. L.; Prior, D. V.; Morris, J. J.; Taylor, P. J.; Laurence, C.; Berthelot, M., manuscript in preparation.
3. Abraham et al. (Abraham, M. H.; Grellier, P. L.; Prior, D. V.; Morris, J. J.; Taylor, P. J.; Maria, P.-C.; Gal, J.-F. J. Phys. Org. Chem., in press) have shown that these hydrogen bond acids give rise to a different electrostatic: covalent ratio in their complexes, with a Maria-Gal θ value of 77-86°, as compared to a θ value of 64-73° for the other hydrogen bond acids in Table I. For the first analysis of basicity using θ values, see: Maria, P.-C.; Gal, J.-F; de Franceschi, J.; Fargin, E. J. Am. Chem. Soc. 1987, 109, 483.
4. Abboud, J.-L.M.; Bellon, L. Ann. Chim. (Paris) 1970, 5, 63. These authors also suggested that a product term might possibly be included in a general treatment.
5. Terent'ev, V. A. Zh. Fiz. Khim. 1972, 46, 1918.
6. 2H.
7. Taft, R. W.; Abraham, M. H.; Famini, G. R.; Doherty, R. M.; Abboud, J.-L.M.; Kamlet, M. J. J. Pharm. Sci. 1985, 74, 807.
8. Kamlet, M. J.; Doherty, R. M.; Veith, G. D.; Taft, R. W.; Abraham, M. H. Environ. Sci. Technol. 1986, 20, 690.
9. Kamlet, M. J.; Doherty, R. M.; Taft, R. W.; Abraham, M. H.; Veith, G. D.; Abraham, D. J. Environ. Sci. Technol. 1987, 21, 149.
10. Drago, R. S. Coord. Chem. Revs. 1980, 33, 251.
11. Ruostesuo, P.; Salminen, U.; Liias, R. Spectrochim. Acta 1987, 43A, 1135.