Aspects of Intermediacy of Carbalkoxymetal Complexes in CO Reactions

Accounts of Chemical Research

Volumn 21, Issue 11, 1988, Pages 428-434

  Milstein, David ^a  

^a WEIZMANN INSTITUTE OF SCIENCE   (Israel)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33845278814     PISSN: 00014842     EISSN: 15204898     Source Type: Journal    
DOI: 10.1021/ar00155a007     Document Type: Article

References (42)

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29. See, for example: (a) Dombek, B. D. ACS Symp. Ser. 1981, No. 152, 213. Fahey, D. R. J. Am. Chem. Soc. 1981,103,136. Feder, H. M.; Rathke, J. W.; Chen, J. M.; Curtiss, L. A. ACS Symp. Ser. 1981, No. 152, 19. Keim, W. Catalysis in Ci Chemistry; D. Reidel: Dordrecht, The Netherlands, 1983; P89.
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37. Reduction of benzaldehydes with CO and water is thought, on the basis of electronic effects, to involve Rh-OR intermediacy rather than Rh-CHROH, and it is suggested that this is true also for methanol synthesis: Thompson, W. J.; Laine, R. M. ACS Symp. Ser. 1981, No. 152, 133.
38. Milstein, D., unpublished results.
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42. It is thought that cleavage of MeCOCo(CO)3L to C2 products in methanol homologation involves attack by H2 rather than cleavage by a hydride: Martin, J. T.; Baird, M. C. Organometallics 1983, 2, 1073.