Low-Lying Singlet and Triplet Electronic Excited States of Binuclear (d10-d10) Palladium(0) and Platinum(0) Complexes

Journal of the American Chemical Society

Volumn 110, Issue 7, 1988, Pages 2145-2147

  Harvey, Pierre D ^a   Gray, Harry B ^a  

^a CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33845278121     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00215a023     Document Type: Article

References (29)

1. Marshall, J. L.; Stiegman, A. E.; Gray, H. B. In Excited States and Reactive Intermediates: Photochemistry, Photophysics, and Electrochemistry; Lever, Ed.; A.B.P. ACS Symposium Series 307; American Chemical Society: Washington, DC, 1986; p 166.
2. Che, C.-M.; Lee, W. M. J. Chem. Soc., Chem. Commun. 1986, 512.
3. Roundhill, D. M. J. Am. Chem. Soc. 1985, 107, 4354.
4. Peterson, J. R.; Kalyanasundaram, K. J. Phys. Chem. 1985, 89, 2486.
5. Che, C.-M.; Butler, L. G.; Grunthaner, P.; Gray, H. B. Inorg. Chem. 1985, 24, 4662.
6. Kim, J.; Fan, F. F.; Bard, A. J.; Che, C.-M.; Gray, H. B. Chem. Phys. Lett. 1985, 121, 543.
7. Rice, S. F.; Gray, H. B. J. Am. Chem. Soc. 1983, 105, 4571.
8. Che, C.-M.; Butler, L. G.; Gray, H. B. J. Am. Chem. Soc. 1981, 103, 7796.
9. Fordyce, W. A.; Crosby, G. A. J. Am. Chem. Soc. 1982, 103, 7061.
10. Rice, S. F.; Milder, S. J.; Gray, H. B.; Goldbeck, R. A.; Kliger, D. S. Coord. Chem. Rev. 1982, 43, 349 and references therein.
11. Gray, H. B.; Maverick, A. W. Science (Washington, D.C.) 1981, 214, 1201.
12. Eidem, P. K.; Maverick, A. W.; Gray, H. B. Inorg. Chim. Acta 1981, 50, 59.
13. Mann, K. R.; DiPierro, M. J.; Gill, T. P. J. Am. Chem. Soc. 1980, 102, 3965.
14. Marshall, J. L.; Stobart, S. R.; Gray, H. B. J. Am. Chem. Soc. 1984, 106, 3027.
15. Winkler, J. R.; Marshall, J. L.; Netzel, T. L.; Gray, H. B. J. Am. Chem. Soc. 1986, 108, 2263.
16. DeLaet, D. L.; Fanwick, P. E.; Kubiak, C. P. Organometallics 1986, 5, 1807.
17. Stern, E. W.; Maples, P. K. J. Catal. 1972, 27, 120.
18. Grossel, M. C.; Brown, M. P.; Nelson, C. D.; Yavari, A.; Kalles, E.; Moulding, R. P.; Seddon, K. R. J. Organomet. Chem. 1982, 232, C13.
19. Yoshida, T.; Tulip, T. H.; Ibers, J. A.; Otsuka, S. J. Am. Chem. Soc. 1978, 100, 2063.
20. Karch, H. H.; Schubert, U. Z. Naturforsch., B: Anorg. Chem., Org. Chem. 1982, 37B, 186.
21. Briant, C. E.; Hall, K. P.; Mingos, D. M. P. J. Organomet. Chem. 1982, 229, C5 and references therein.
22. Caspar, J. V. J. Am. Chem. Soc. 1985, 107, 6718.
23. Perrin, D. D.; Armarego, W. L. F.; Perrin, D. R. Purifications of Laboratory Chemicals; Pergamon: Oxford, 1966.
24. 2-Methyltetrahydrofuran was purified according to the procedure outlined for tetrahydrofuran in: Gordon, A. J.; Ford, R. A. The Chemist's Companion, A Handbook of Practical Data, Techniques, and References; Wiley: New York, 1972, p 436.
25. Nocera, D. G.; Winkler, J. R.; Yocom, K. M.; Bordignon, E.; Gray, H. B. J. Am. Chem. Soc. 1984, 106, 5145.
26. Albano, V.; Bellon, P. L.; Scatturin, V. J. Chem. Soc., Chem. Commun. 1966, 507.
27. Manojlovic-Muir, L.; Muir, K. W. J. Chem. Soc., Chem. Commun. 1982, 1155. Manojlovic-Muir, L.; Muir, K. W.; Grossel, M. C.; Brown, M. P.; Nelson, C. D.; Yavari, A.; Kallas, E.; Moulding, R. P.; Seddon, K. R. J. Chem. Soc., Dalton Trans. 1986, 1955.
28. Aggregation also can be ruled out, because the emission energy and lifetime do not depend on complex concentration. Ligand dissociation does not occur in solution at room temperature: Mann, B. E.; Musco, A. J. Chem. Soc., Dalton Trans. 1975, 1673. Tolman, C. A.; Seidel, W. C.; Gerlach, D. H. J. Am. Chem. Soc. 1972, 94, 2669.
29. Woodruff, W. H., unpublished results. A brief account of Woodruff's correlation for 4d species has appeared: Miskowski, V. M.; Dal linger, R. F.; Christoph. G. G.; Morris, D. E.; Spies, G. H.; Woodruff, W. H. Inorg. Chem. 1987, 26, 2127.