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Volumn 348, Issue 16-17, 2006, Pages 2363-2370

Enantioselective cyclopropanation with TADDOL-derived phosphate ligands

Author keywords

Asymmetric synthesis; Br nsted acid; Cyclopropanes; Simmons Smith reaction; TADDOL phosphate

Indexed keywords


EID: 33845274756     PISSN: 16154150     EISSN: 15213897     Source Type: Journal    
DOI: 10.1002/adsc.200600351     Document Type: Article
Times cited : (42)

References (61)
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    • During the preparation of this manuscript, Akiyama et al. reported, without synthetic details, the use of similar chiral phosphates in a Mannich-Type reaction: T. Akiyama, Y. Saitoh, H. Morita, K. Fuchibe, Adv. Synth. Catal. 2005, 347, 1523-1526.
    • (2005) Adv. Synth. Catal. , vol.347 , pp. 1523-1526
    • Akiyama, T.1    Saitoh, Y.2    Morita, H.3    Fuchibe, K.4
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    • note
    • With the corresponding simple diol TADDOL(Ph), we obtained only 52% conversion with 12% ee in the cyclopropanation of benzyl-protected cinnamyl alcohol.
  • 61
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    • note
    • In the cyclopropanation of the benzylated cinnamylic alcohol (substrate A with Shi's ligand (the dipeptide N-Boc-L-Val-L-Pro-OMe) 7% ee was obtained with 81% yield (unpublished results).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.