Are d0 ML6 Complexes Always Octahedral? The X-ray Structure of Trigonal-Prismatic [Li(tmed)]2[ZrMe6]

Journal of the American Chemical Society

Volumn 111, Issue 11, 1989, Pages 4114-4116

  Morse, Paige M ^a   Girolami, Gregory S ^a  

^a UNIVERSITY OF ILLINOIS AT URBANA CHAMPAIGN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33845184515     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00193a061     Document Type: Article

References (7)

1. Guggenberger, L. J.; Titus, D. D.; Flood, M. T.; Marsh, R. E.; Orio, A. A.; Gray, H. B. J. Am. Chem. Soc. 1972, 94, 1135–1143. (b) Meakin, P.; Muetterties, E. L.; Jesson, J. P. J. Am. Chem. Soc. 1973, 95, 75–85. For other examples, see: (c) Vancea, L.; Bennett, M. J.; Jones, C. E.; Smith, R. A.; Graham, W. A. G. Inorg. Chem. 1977, 16, 897–902. (d) McNeill, E. A.; Scholer, F. R. J. Am. Chem. Soc. 1977, 99, 6243–6249.
2. Bennett, M. J.; Cowie, M.; Martin, J. L.; Takats, J. J. Am. Chem. Soc. 1973, 95, 7504–7505. For other examples, see: (b) Kepert, D. L. Prog. Inorg. Chem. 1977, 23, 1–65. (c) Pierpont, C. G.; Buchanan, R. M. J. Am. Chem. Soc. 1975, 97, 4912–4917. (d) Cowie, M.; Bennett, M. J. Inorg. Chem. 1976, 15, 1584–1589. (e) Cowie, M.; Bennett, M. J. Inorg. Chem. 1976, 15, 1589–1595. (f) Draganjac, M.; Coucouvanis, D. J. Am. Chem. Soc. 1983, 105, 139–140. (g) Colmanet, S. F.; Williams, G. A.; Mackay, M. F. J. Chem. Soc., Dalton Trans. 1987, 2305–2310. (h) Boyde, S.; Garner, C. D.; Enemark, J. H.; Bruck, M. A.; Kristofzski, J. G. J. Chem. Soc., Dalton Trans. 1987, 2267–2271. (i) Tatsumi, K.; Matsubara, I.; Sekiguchi, Y.; Nakamura, A.; Mealli, C. Inorg. Chem. 1989, 28, 773–780.
3. Morris, R. J.; Girolami, G. S. J. Am. Chem. Soc. 1988, 110, 6245–6246.
4. Hoffman, R.; Howell, J. M.; Rossi, A. R. J. Am. Chem. Soc. 1976, 98, 2484–2492. (b) Stiefel, E. I.; Eisenberg, R.; Rosenberg, R. C.; Gray, H. B. J. Am. Chem. Soc. 1966, 88, 2956–2966. (c) Huisman, R.; DeJonge, R.; Haas, C.; Jellinek, F. J. Solid State Chem. 1971, 3, 56–66. (d) Eisenstein, O.; Jean, Y. J. Am. Chem. Soc. 1985, 107, 1 177–1186. (e) Demolliens, A.; Jean, Y.; Eisenstein, O. Organometallics 1986, 5, 1457–1464. (f) Cameron, A. D.; Fitzgerald, G.; Zerner, M. C. lnorg. Chem. 1988, 27, 3437–3439. (g) Anslyn, E. V.; Brusich, M. J., Goddard, W. A. Organometallics 1988, 7, 98–105. (h) Kang, S. K.; Albright, T. A.; Eisenstein, O., submitted for publication.
5. Barskaya, I. B.; Toptygina, G. M. Russ. J. Inorg. Chem. (Engl. Transl.) 1967, 12, 14–16.
6. Chisholm, M. H.; Hammond, C. E.; Huffman, J. C. Polyhedron 1988, 7, 2515–2520.
7. Shortland, A. J.; Wilkinson, G. J. Chem. Soc., Dalton Trans. 1973, 872–876. (b) Galyer, A. L.; Wilkinson, G. J. Chem. Soc., Dalton Trans. 1976, 2235–2238. (c) Green, J. C.; Lloyd, D. R.; Galyer, L.; Mertis, K.; Wilkinson, G. J. Chem. Soc., Dalton Trans. 1978, 1403–1407.