Metallabenzene: Synthesis, Structure, and Spectroscopy of a 1-Irida-3,5-dimethylbenzene Complex

Journal of the American Chemical Society

Volumn 111, Issue 11, 1989, Pages 4118-4120

  Bleeke, John R ^a   Xie, Yun Feng ^a   Peng, Wei Jun ^a   Chiang, Michael ^a  

^a WASHINGTON UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33845183932     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00193a064     Document Type: Article

References (7)

1. Ashe, III, A. J. J. Am. Chem. Soc. 1971, 93, 3293.
2. For a theoretical discussion of delocalization in metallacycles, see: Thorn, D. L.; Hoffmann, R. Nouv. J. Chem. 1979, 3, 39.
3. Elliot, G. P.; Roper, W. R.; Waters, J. M. J. Chem. Soc., Chem. Commun. 1982, 811.
4. Bleeke. J. R.; Peng, W.-J. Organometallics 1987. 6, 1576.
5. Jesson, J. P.; Muetterties, E. L. In Dynamic Nuclear Magnetic Reso nance Spectroscopy; Jackman, L. M., Cotton, F. A., Eds.; Academic Press: New York, 1975; pp 253–316.
6. Ferede, R.; Allison, N. T. Organometallics 1983, 2, 463. (b) Ferede, R.; Hinton, J. F.; Korfmacher, W. A.; Freeman, J. P.; Allison, N. T. Dynamic Nuclear Magnetic Reso nance Spectroscopy 1985, 4, 614. (c) Egan, J. W., Jr.; Hughes, R. P.; Rheingold, A. L. Dynamic Nuclear Magnetic Reso nance Spectroscopy 1987, 6, 1578.
7. For drawings of these orbitals, see: Albright, T. A.; Hoffmann, R.; Tse, Y.-C.; D'Ottavio, T. J. Am. Chem. Soc. 1979, 101, 3812.