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Volumn 45, Issue 22, 2006, Pages 9123-9131

Rhodium dimers with 2,2-dimethyl-1,3-diisocyano and bis(diphenylphosphino) methane bridging ligands

Author keywords

[No Author keywords available]

Indexed keywords


EID: 33751503536     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic060923g     Document Type: Article
Times cited : (16)

References (56)
  • 17
    • 33751502120 scopus 로고    scopus 로고
    • Bruker Analytical X-ray Instruments, Inc.: Madison WI
    • Bruker SMART v5.051 and SAINT v5.A06 programs were used for data collection and data processing, respectively. SMART v5.051; SAINT v5.A06; Bruker Analytical X-ray Instruments, Inc.: Madison WI.
    • SMART V5.051; SAINT V5.A06
  • 18
    • 16644386465 scopus 로고    scopus 로고
    • University of Göttingen: Göttingen, Germany
    • SADABS v2.10 was used for the application of semiempirical absorption and beam corrections. Sheldrick, G. M. SADABS v2.10; University of Göttingen: Göttingen, Germany.
    • SADABS V2.10
    • Sheldrick, G.M.1
  • 19
    • 0004150157 scopus 로고    scopus 로고
    • University of Göttingen: Göttingen, Germany; Bruker Analytical X-ray Solutions, Inc.: Madison, WI
    • SHELXTL v5.03, 6.1, and 6.14 were used for the structure solution and generation of figures and tables. Neutral-atom scattering factors were used as stored in this package. Sheldrick, G. M. SHELXTL v5.03, 6.1, and 6.14; University of Göttingen: Göttingen, Germany; Bruker Analytical X-ray Solutions, Inc.: Madison, WI.
    • SHELXTL V5.03, 6.1, and 6.14
    • Sheldrick, G.M.1
  • 25
    • 79958167167 scopus 로고
    • Academic Press: New York
    • Keehn, P. M. Cyclophanes Vol 1; Academic Press: New York, 1983; Vol. 1.
    • (1983) Cyclophanes Vol 1 , vol.1
    • Keehn, P.M.1
  • 34
    • 33751539731 scopus 로고    scopus 로고
    • note
    • Recent computational results (ref 23), suggesting significant isocyanide contribution to the LUMO, are at odds with experiments that indicate minimal MLCT character in this excited state (ref 33).
  • 51
    • 33751519507 scopus 로고    scopus 로고
    • note
    • We have found that detailed investigation of this reaction on long time scales is complicated by this apparent degradation chemistry, which is sensitive to light and heat.
  • 56
    • 33751529648 scopus 로고    scopus 로고
    • note
    • 1H NMR spectroscopy, we have observed singlet resonances at 4.10 and 4.07 nm that are tentatively assigned to the inequivalent methylene protons of the tetramer.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.