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Bruker SMART v5.051 and SAINT v5.A06 programs were used for data collection and data processing, respectively. SMART v5.051; SAINT v5.A06; Bruker Analytical X-ray Instruments, Inc.: Madison WI.
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SMART V5.051; SAINT V5.A06
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SADABS v2.10 was used for the application of semiempirical absorption and beam corrections. Sheldrick, G. M. SADABS v2.10; University of Göttingen: Göttingen, Germany.
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SHELXTL v5.03, 6.1, and 6.14 were used for the structure solution and generation of figures and tables. Neutral-atom scattering factors were used as stored in this package. Sheldrick, G. M. SHELXTL v5.03, 6.1, and 6.14; University of Göttingen: Göttingen, Germany; Bruker Analytical X-ray Solutions, Inc.: Madison, WI.
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34
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33751539731
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note
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Recent computational results (ref 23), suggesting significant isocyanide contribution to the LUMO, are at odds with experiments that indicate minimal MLCT character in this excited state (ref 33).
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35
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0001145901
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0001256249
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51
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33751519507
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note
-
We have found that detailed investigation of this reaction on long time scales is complicated by this apparent degradation chemistry, which is sensitive to light and heat.
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-
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54
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0000692316
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Sigal, I. S.; Mann, K. R.; Gray, H. B. J. Am. Chem. Soc. 1980, 102, 7252-7256.
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56
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33751529648
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note
-
1H NMR spectroscopy, we have observed singlet resonances at 4.10 and 4.07 nm that are tentatively assigned to the inequivalent methylene protons of the tetramer.
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