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33751325169
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note
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In this letter 'cis' and 'trans' are used to show the relative position of phenyl groups connected to the amide group. The designation can be easily understood at a glance; although, ordinarily, 'cis-amide' and 'trans-amide' should be named (E)- and (Z)-amide, respectively.
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32
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33751310891
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note
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2 = 0.1937 (all data). CCDC-619690.
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34
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33751316347
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note
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Most probably, a low yield of amide coupling reaction is ascribed to the steric hindrance of the iodine group in macrocycle 2.
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35
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33751327882
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note
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The hinge angle in the biphenyl moiety of 3 is defined by the angle formed by the planes A and B (Fig. 2c).
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36
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33751308717
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note
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The crystals of 3 had two independent molecules in the asymmetric unit.
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