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See for example: a) B. Bildstein, M. Schweiger, H. Angleitner, H. Kopacka, K. Wurst, K.-H. Ongania, M. Fontani, P. Zanello, Organo-metallics 1999,18, 4286;
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Fontani, M.7
Zanello, P.8
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2
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0003627206
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(Ed.: S. Patai), Wiley, Chichester, Chapter 20
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b) H. Hopf in The Chemistry of Ketenes, Allenes, and Related Compounds (Ed.: S. Patai), Wiley, Chichester, 1980, Chapter 20.
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Hopf, H.1
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4
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0003795078
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Wiley, Chichester
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b) K. B. Dillon, F. Mathey, J. F. Nixon, Phosphorus: The Carbon Copy, Wiley, Chichester, 1998.
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Phosphorus: The Carbon Copy
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Dillon, K.B.1
Mathey, F.2
Nixon, J.F.3
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5
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4243352645
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Other cumulenes based on carbon and phosphorus are known, but they contain C-C double bonds, see for example: a) G. Märkl, P. Kreitmeier, Angew. Chem. 1988, 100, 1411;
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7
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b) H. J. Bestmann, D. Hadawi, H. Behl, M. Bremer, F. Hampel, Angew. Chem. 1993, 105, 1198;
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Bestmann, H.J.1
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c) J. Escudié, H. Ranaivonjatovo, L. Rigon, Chem. Rev. 2000, 100, 3639, and references therein.
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0003397099
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(Ed.: A. W. Johnson), Wiley-Interscience, New York
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b) A. W. Johnson, W. C. Kaska, K. A. O. Starzewski, D. A. Dixon, in Ylides and Imines of Phosphorus (Ed.: A. W. Johnson), Wiley-Interscience, New York, 1993;
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Ylides and Imines of Phosphorus
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Johnson, A.W.1
Kaska, W.C.2
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Dixon, D.A.4
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0001247017
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(Eds.: B. M. Trost, I. Fleming, E. Winterfeldt), Pergamon, Oxford
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c) H. J. Bestmann, R. Zimmermann in Comprehensive Organic Synthesis Vol. 6 (Eds.: B. M. Trost, I. Fleming, E. Winterfeldt), Pergamon, Oxford, 1991, p. 171.
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Bestmann, H.J.1
Zimmermann, R.2
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a) M. Gouygou, M. Koenig, J. Escudié, C. Couret, Heteroat. Chem. 1991, 2, 221;
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Gouygou, M.1
Koenig, M.2
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Couret, C.4
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15
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0001601030
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c) H. H. Karsh, H. U. Reisacher, G. Müller, Angew. Chem. 1993, 96, 619;
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Karsh, H.H.1
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0001942114
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a) R. Appel, J. Peters, A. Westerhaus, Angew. Chem. 1982, 94, 76;
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c) R. Pietschnig, M. Nieger, E. Niecke, K. Airola, J. Organomet. Chem. 1997, 541, 237;
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Pietschnig, R.1
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0037662178
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d) T. Baumgartner, P. Moors, M. Nieger, H. Hupfer, E. Niecke, Organometallics 2002, 21, 4919.
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Baumgartner, T.1
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a) T. Kato, H. Gornitzka, A. Baceiredo, G. Bertrand, Angew. Chem. 2000, 112, 3457;
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b) D. Martin, H. Gornitzka, A. Baceiredo, G. Bertrand, Eur. J. Inorg. Chem. 2005, 13, 2619.
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Martin, D.1
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25
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0005253319
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The synthesis of cumulene D in the coordination sphere of a transition metal has been reported earlier: W. V. Konze, V. G. Young, Jr., R. J. Angelici, Organometallics 1998, 17, 1569.
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Konze, W.V.1
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Angelici, R.J.3
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26
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0038783483
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A cumulene of type E, but with a terminal imino instead of a methylene group has already been reported: W. Schilbach, V. von der Gönna, D. Gudat, M. Nieger, E. Niecke, Angew. Chem. 1994, 106, 1037;
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Schilbach, W.1
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D. Seyferth, E. M. Hanson, F. M. Armbrecht Jr., J. Organomet. Chem. 1970, 23, 361.
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0001154962
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The tautomeric equilibrium between α-chlorophosphanes and the corresponding chloro-ylides is well documented. See for example; a) O. I. Kolodiazhnyi, Russ. Chem. Rev. 1997, 66, 225;
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Russ. Chem. Rev.
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b) R. Appel, M. Huppertz, A. Westerhaus, Chem. Ber. 1983, 116, 114.
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