An unusual dichromium(II,II) compound bearing di-2-pyridyl ketone oximate ligands and prepared by the ligand-assisted reduction of a trichromium(III,III,III) complex in air

Inorganic Chemistry Communications

Volumn 9, Issue 12, 2006, Pages 1178-1182

  Stamatatos, Theocharis C ^a   Pringouri, Konstantina V ^a   Raptopoulou, Catherine P ^b   Vicente, Ramon ^c   Psycharis, Vassilis ^b   Escuer, Albert ^c   Perlepes, Spyros P ^a  

^a UNIVERSITY OF PATRAS   (Greece)

^b INSTITUTE OF MATERIALS SCIENCE   (Greece)

^c UNIVERSITY OF BARCELONA   (Spain)

Author keywords

Stacking interactions; Di 2 pyridyl ketone oximate complexes; Dichromium(II,II) complexes; Ligand assisted reduction of chromium(III); Trigonal bipyramidal chromium(II)

Indexed keywords

EID: 33751174295     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2006.07.030     Document Type: Article

References (33)

1. Cotton F.A. In: Cotton F.A., Murillo C.A., and Walton R.A. (Eds). Multiple Bonds Between Metal Atoms. third ed. (2005), Springer Science 35-68
2. Eglin J.L. In: McCleverty J.A., and Meyer T.J. (Eds). Comprehensive Coordination Chemistry II vol. 4 (2004), Elsevier, Amsterdam 599-603
3. Representative literature:. Edema J.J.H., Gambarotta S., Bolhuis F.V., and Spek A.L. J. Am. Chem. Soc. 111 (1989) 2142
4. Cotton F.A., Luck R.L., and Son K.-A. Inorg. Chim. Acta 168 (1990) 3
5. Fryzuk M.D., Leznoff D.B., Rettig S.J., and Thompson R.C. Inorg. Chem. 33 (1994) 5528
6. For an excellent review see:. Chaudhuri P. Coord. Chem. Rev. 243 (2003) 143
7. For a comprehensive review see:. Milios C.J., Stamatatos Th.C., and Perlepes S.P. Polyhedron 25 (2006) 134 Polyhedron Report
8. For an excellent review see:. Pecoraro V.L., Stemmler A.J., Gibney B.R., Bodwin J.J., Wang H., Kampf J.W., and Barwinski A. Prog. Inorg. Chem. 45 (1997) 83
9. For example see:. Mori F., Nyui T., Ishida T., Nogami T., Choi K.-Y., and Nojiri H. J. Am. Chem. Soc. 128 (2006) 1440
10. Afrati T., Dendrinou-Samara C., Raptopoulou C.P., Terzis A., Tangoulis V., and Kessissoglou D.P. Angew. Chem. Int. Ed. 41 (2002) 2148
11. Milios C.J., Kyritsis P., Raptopoulou C.P., Terzis A., Vicente R., Escuer A., and Perlepes S.P. Dalton Trans. (2005) 501
12. Kumagai H., Endo M., Kondo M., Kawata S., and Kitagawa S. Coord. Chem. Rev. 237 (2003) 197
13. Th.C. Stamatatos, A.K. Boudalis, Y. Sanakis, C.P. Raptopoulou, Inorg. Chem., submitted for publication.
14. Milios C.J., Raptopoulou C.P., Terzis A., Vicente R., Escuer A., and Perlepes S.P. Inorg. Chem. Commun. 6 (2003) 1056
15. Stamatatos Th.C., Dionyssopoulou S., Efthymiou G., Kyritsis P., Raptopoulou C.P., Terzis A., Vicente R., Escuer A., and Perlepes S.P. Inorg. Chem. 44 (2005) 3374
16. Th.C. Stamatatos, J.C. Vlahopoulou, Y. Sanakis, C.P. Raptopoulou, V. Psycharis, A.K. Boudalis, S.P. Perlepes, Inorg. Chem. Commun., in press.
17. Coxall R.A., Parkin A., Parsons S., Smith A.A., Timco G.A., and Winpenny R.E.P. J. Solid State Chem. 159 (2001) 321
18. Satisfactory C, H and N analyses were obtained (the product was maintained in a small tube sealed with a septum under dinitrogen).
19. Kukushkin V.Yu., Tudela D., and Pombeiro A.J.L. Coord. Chem. Rev. 156 (1996) 333
20. Gibson V.C., Newton C., Redshaw C., Solan G.A., White A.J.P., and Williams D.J. J. Chem. Soc., Dalton Trans. (1999) 827
21. 6] on the condenser back into the flask four or five times during the course of the reaction. Warning: Carbon monoxide is extremely dangerous and the experiments should be carried out in a hood.
22. The identity of the product was confirmed by unit cell determination and IR spectroscopic comparison with the authentic sample prepared employing the triangular chromium(III) starting material.
23. Cotton F.A., Murillo C.A., and Pascual I. Inorg. Chem. 38 (1999) 2746
24. For example see:. Asato E., Kida S., and Murase I. Inorg. Chem. 28 (1989) 800 and references therein
25. 2) = 0.0527 (0.1353) for 2815 observed (I > 2σ(I)) reflections.
26. Coxall R.A., Harris S.G., Henderson D.K., Parsons S., Tasker P.A., and Winpenny R.E.P. J. Chem. Soc., Dalton Trans. (2000) 2349
27. Addison A.W., Rao T.N., Reedijk J., Rijin J.V., and Verschoor G.C. J. Chem. Soc., Dalton Trans. (1984) 1349
28. Schlemper E.O., Stunkel J., and Patterson C. Acta Crystallogr., Sect. C 46 (1990) 1226
29. Babar M.A., Larkworthy L.F., and Fitzsimmons B.W. Inorg. Chim. Acta 148 (1988) 25
30. Burdinski D., Birkelbach F., Weyhermüller T., Flörke U., Haupt H.- J., Lengen M., Trautwein A.X., Bill E., Wieghardt K., and Chaudhuri P. Inorg. Chem. 37 (1998) 1009
31. Ross S., Weyhermüller T., Bill E., Wieghardt K., and Chaudhuri P. Inorg. Chem. 40 (2001) 6656
32. M at 6.0 K both indicate an S = 0 ground state. The full magnetic description of the complex will be reported in the full paper.
33. Alfaro N.M., Cotton F.A., Daniels L.M., and Murillo C.A. Inorg. Chem. 31 (1992) 2718