Studies of two-center three-electron s∴s bonds in [n-Pr2S∴Sn-Pr2]+ and [i-Pr2S∴Si-Pr2]+: Thermochemistry of adduct formation and MS/MS metastable and collision-induced dissociation spectra of the adducts

Journal of Physical Chemistry

Volumn 100, Issue 39, 1996, Pages 15794-15799

  James, Mary A ^a   Illies, Andreas J ^a  

^a AUBURN UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33751156689     PISSN: 00223654     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp9612487     Document Type: Article

References (29)

1. Deng, Y.; Illies, A. J.; James, M. A.; McKee, M. L.; Peschke, M. J. Am. Chem. Soc. 1995, 117, 420.
2. Ekern, S.; Illies, A.; McKee, M. L.; Peschke, M. J. Am. Chem. Soc. 1993, 115, 12510.
3. Livant, P.; Illies, A. J. Am. Chem. Soc. 1991, 113, 1510.
4. Illies, A. J.; Livant, P.; McKee, M. L. J. Am. Chem. Soc. 1988, 110, 7980.
5. James, M. A.; McKee, M. L.; Illies, A. J. J. Am. Chem. Soc, in press.
6. Peschke, M.; McKee, M. L.; Illies, A. J. To be submitted for publication.
7. Pauling, L. J. Am. Chem. Soc. 1931, 53, 3225.
8. Baird, N. C. J. Chem. Educ. 1977, 54, 291.
9. Chang, R. Chemistry, 4th ed.; McGraw-Hill, Inc.: New York, 1991; p 378.
10. Gill, P. M. W.; Weatherall, P.; Radom, L. J. Am. Chem. Soc. 1989, 111, 2782.
11. Drewello, T.; Lebrilla, C. B.; Schwarz, H.; deKoning, L. J.; Fokkens, R. H.; Nibbering, N. M. M.; Anklam, E.; Asmus, K.-D. J. Chem. Soc., Chem. Commun. 1987, 1381.
12. (a) Asmus, K.-D. In Sulfur-Centered Reactive Intermediates in Chemistry and Biology; Chatgilialoglu, C., Asmus, K.-D., Eds.; Plenum Press: New York, 1990; p 155.
13. (b) Monig, J.; Goslich, R.; Asmus, K.-D. Ber. Bunsen-Ges. Phys. Chem. 1986, 90, 115.
14. Anklam, E.; Mohan, H.; Asmus, K.-D. J. Chem. Soc., Perkin Trans. 2 1988, 1297.
15. Asmus, K.-D. Acc. Chem. Res. 1979, 12, 436.
16. (e) Chaudhri, S. A.; Mohan, H.; Anklam, E.; Asmus, K.-D. J. Chem. Soc., Perkin Trans. 2 1996, 383.
17. Clark, T. J. Commit. Chem. 1981, 2, 261.
18. Bally, T. In Radical Ionic Systems; Lund. A., Shiotani, M., Eds.; Kluwer Academic Publishers: The Netherlands, 1991; pp 3-54.
19. (a) Illies, A. J. J. Phys. Chem. 1988, 92, 2889.
20. (b) Illies, A. J. Org. Mass Spectrom. 1990, 25, 73.
21. Chang. C.; Sroka, G. J.; Meisels, G. G. J. Chem. Phys. 1971, 55, 5154.
22. + was scaled by 4 kJ/mol to obtain the S∴S bond energy (this value is similar to the corrections over a similar temperature range from previous studies). The enthalpy of reaction at 298 K was obtained by scaling the experimental bond enthalpy at 507 K by 3 kJ/mol.
23. + are from the following: Lias, S. G.; Bartmess, J. E.; Liebman, J. F.; Holmes, J. L.; Levin, R. D.; Mallard, W. G. J. Phys. Chem. Ref. Data 1988, 17, Suppl. 1.
24. Benson, S. W. Thermochemical Kinetics, Methods for the Estimation of Thermochemical Data and Rate Parameters, 2nd ed.; John Wiley & Sons: New York, 1976; p 299.
25. (a) Jennings, K. R. Int. J. Mass Spectrom. Ion Phys., 1 1968, 227.
26. (b) McLafferty, F. W.; Kornfeld, R.; Haddon, W. F.; Levsen, K.; Sakai, I.; Bente, P. F., III; Tsai, S.-C.; Schuddemage, H. D. R. J. Am. Chem. Soc. 1973, 95, 3886.
27. McLafferty, F. W.; Bente, P. F., III; Kornfeld, R.; Tsai, S.-C.; Howe, I. J. Am. Chem. Soc. 1973, 95, 2120.
28. (a) Jarrold, M. F.; Illies, A. J.; Kirchner. N. J.; Wagner-Redeker, W.; Bowers, M. T.; Mandich, M. L.; Beauchamp, J. L. J. Phys. Chem. 1983, 87, 2213.
29. (b) Jarrold, M. F.; Wagner-Redeker, W.; Illies, A. J.; Kirchner, N. J.; Bowers, M. T. Int. J. Mass Spectrom. Ion Processes 1984, 58, 63.