In Situ Attenuated Total Reflectance Fourier Transform Infrared Spectroscopy of Carboxylate-Bearing, Siloxane-Anchored, Self-Assembled Monolayers: A Study of Carboxylate Reactivity and Acid-Base Properties

Langmuir

Volumn 11, Issue 4, 1995, Pages 1190-1195

  Cheng, Shih Song ^a   Scherson, Daniel A ^a   Sukenik, Chaim N ^a  

^a CASE WESTERN RESERVE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33751156141     PISSN: 07437463     EISSN: 15205827     Source Type: Journal    
DOI: 10.1021/la00004a026     Document Type: Article

References (37)

1. Holmes-Farley, S. R.; Reamey, R. H.; McCarthy, T. J.; Deutch, J.; Whitesides, G. M. Langmuir 1985, 1, 725-740.
2. Holmes-Farley, S. R.; Whitesides, G. M. Langmuir 1987, 3, 62-76.
3. Holmes-Farley, S. R.; Bain, C. D.; Whitesides, G. M. Langmuir 1988, 4, 921-937.
4. Bain, C. D.; Whitesides, G. M. Langmuir 1989, 5, 1370-1378.
5. Wang, J.; Frostman, L. M.; Ward, M. D. J. Phys. Chem. 1992, 96, 5224-5228.
6. Nuzzo, R. G.; Dubois, L. H.; Allara, D. L. J. Am. Chem. Soc. 1990, 112, 558-569.
7. Dubois, L. H.; Zegarski, B. R.; Nuzzo, R. G. J. Am. Chem. Soc. 1990, 112, 570-579.
8. Troughton, E. B.; Bain, C. D.; Whitesides, G. M.; Nuzzo, R. G.; Allara, D. L.; Porter, M. D. Langmuir 1988, 4, 365-386.
9. Lovelock, B.; Grieser, F.; Healy, T. W. J. Phys. Chem. 1985, 89, 501.
10. Lovelock, B.; Grieser, F.; Healy, T. W. Langmuir 1986, 2, 443.
11. Grieser, F.; Drummond, C. J. J. Phys. Chem. 1988, 92, 5580.
12. Hall, R. A.; Hayes, D.; Thistlethwaite, P. J.; Grieser, F. Colloid Surf. 1991, 56, 339.
13. Murray, B. S.; Godfrey, J. S.; Grieser, F.; Healey, T. W.; Lovelock, B.; Scales, P. J. Langmuir 1991, 7, 3057.
14. Bryant, M. A.; Crooks, R. M. Langmuir 1993, 9, 385.
15. Petrov, J. G.; Mobius, D. Langmuir 1993, 9, 756.
16. Drummond, G. J.; Grieser, F. Langmuir 1987, 3, 855.
17. Caspors, J.; Goormaghtigh, E.; Ferreira, J.; Brasseur, R.; Vanden-Branden, J.; Ruysschaert, J. M. J. Colloid Interface Sci. 1983, 91, 546.
18. For example, despite the power of photoaucoustic calorimetry to study the acid/base chemistry of surfaces (see: Zhang, L.; Shulman, M. A.; Whitesides, G. M.; Grabowski, J. J. J. Am. Chem. Soc. 1990, 112, 7069-7071), it cannot be directly applied to simple alkyl carboxylates.
19. Sun, L.; Kepley, L. J.; Crooks, R. M. Langmuir 1992, 8, 2101.
20. Nuzzo, R. G.; Dubois, L. H.; Allara, D. L. J. Am. Chem. Soc. 1990, 112, 558.
21. Allcock, H. R.; Fitzpatrick, R. J. Chem Mater. 1992, 4, 769.
22. For comments on the difficulties of such experiments see Whitesides, G. M.; Biebuyck, H. A.; Folkers, J. P.; Prime, K. L. J. Adhesion Sci. Technol. 1991, 5, 57-69.
23. Cheng, S. S.; Scherson, D. A.; Sukenik, C. N. J. Am. Chem. Soc. 1992, 114, 5436.
24. Chang, S. C.; Weaver, M. J. J. Phys. Chem. 1991, 95, 5391; and references therein.
25. Wasserman, S. R.; Tao, Y.-T.; Whitesides, G. M. Langmuir 1989, 5, 1074-1087. (Note: This paper also discusses the wetting properties ofcarboxylate surfaces made by acid hydrolysis of a methyl ester, but no details of the experimental procedure are given.
26. Maoz, R.; Netzer, L.; Sagiv, J. J. Chem Phys. 1988, 85, 1059.
27. Ogawa, K.; Mino, N.; Tamura, H.; Hatada, M. Langmuir 1990, 6, 851.
28. Ferguson, G. S.; Chaudhury, M. K.; Biebuyck, H. A.; Whitesides, G. M. Macromolecules 1993, 26, 5870-5875.
29. Tarasevich, B. J.; Koike, P. C.; McVay, G. L.; Fryxell, G. E.; Campbell, A. A. Synthesis of Ceramic Infrastructures Using Biologic Processes. In Chemical Processing of Advanced Materials', Hench, L. L., West, J. K., Eds.; 1992; pp 529–541.
30. Balachander, N.; Sukenik, C. N. Langmuir 1990, 6, 1621.
31. Balachander, N.; Sukenik, C. N. Tetrahedron Lett. 1988, 29, 5593.
32. Cheng, S. S. Ph.D. Thesis, Submitted to Case Western Reserve University, January 1994.
33. Tillman, N.; Ulman, A.; Penner, T. L. Langmuir 1989, 5, 101.
34. Evans, S. D.; Sharma, R.; Ulman, A. Langmuir 1991, 7, 156-161.
35. Cabaniss, S. E. Anal. Chim. Acta 1991, 255, 23-30.
36. Cheng, S. S.; Chittur, K. K.; Sukenik, C. N.; Culp, L. A.; Lewandowska, K. J. Colloid Interface Sci. 1994, 162, 135-143.
37. Pike, P. R.; Sworan, P. A.; Cabaniss, S. E. Anal. Chim. Acta 1993, 280, 253-261.