Kinetic analysis of photochromic systems under continuous irradiation. application to spiropyrans

Journal of Physical Chemistry

Volumn 100, Issue 11, 1996, Pages 4485-4490

  Pimienta, V ^a   Lavabre, D ^a   Levy, G ^a   Samat, A ^a   Guglielmetti, R ^a   Micheau, J C ^a  

^a UNIVERSITÉ DE TOULOUSE   (France)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33751142898     PISSN: 00223654     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp9531117     Document Type: Article

References (34)

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33. If the photokinetic curve is close to first order, Abs' changes little during irradiation and F is practically constant. On the other hand, if the photokinetic curve departs from first order, F may sometimes (if the change is sufficient) be estimated by fitting this curve alone without having to monitor the irradiation wavelength. See: Misra, G. P.; Lavabre, D.; Micheau, J. C. J. Photochem. Photobiol., A: Chem. 1994, SO, 251-56.
34. This approach is akin to the temperature variation method used in the study of thermochromic equilibria. See: Tan-Sien-Hee, L.; Lavabre, D.; Levy, G.; Micheau, J. C. New J. Chem. 1989, 13, 227-33.