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Volumn 100, Issue 6, 1996, Pages 2012-2018

Deactivation of 9,9'-bianthryl in solution studied by photoacoustic calorimetry and fluorescence

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EID: 33751125959     PISSN: 00223654     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp951193t     Document Type: Article
Times cited : (44)

References (52)
  • 39
    • 85033054747 scopus 로고    scopus 로고
    • note
    • Due to a typos error Oi = ai* + Oj/fa -r\) was given in ref 21 instead of the correct eq 7c.
  • 40
    • 0003016484 scopus 로고
    • After submission of our work a paper appeared (Mac, M.; Najbar, J.; Wirz, J. J. Photochem. Photobiol. A: Chem. 1995,88,93-104.) reporting values of Qlx of BA determined by the method of Medinger and Wilkinson, which requires a single fluorescing species with a solvent-independent rate constant of fluorescence. Ethyl iodide (El) was used as heavy atom quencher. The addition of larger amounts of El to HEX leads to an increase of the solvent polarity and consequently to a shift of the LE = CT equilibrium, which in turn should reduce kt, see Table 1. We therefore believe that the value QIX = 0.43 determined in HEX by the much simpler PAC method is more realistic.
    • (1995) Photochem. Photobiol. A: Chem. , vol.88 , pp. 93-104
    • Mac, M.1    Najbar, J.2    Wirz, J.J.3
  • 47
    • 85033062728 scopus 로고    scopus 로고
    • note
    • The electrostatic solute-solvent interaction in BNZ is not appropriately described by the parameter (f -l)/(2e 4- 1). This holds true to a minor degree also for the parameter qr. BNZ has an effective e & 5. Therefore, the qf value of CHClj (e = 4.7) is also taken for BNZ.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.