Near-infrared resonance Raman spectra of chlorosomes: Probing nuclear coupling in electronic energy transfer

Journal of Physical Chemistry

Volumn 100, Issue 11, 1996, Pages 4662-4671

  Cherepy, Nerine J ^a,b   Du, Mei ^a   Holzwarth, Alfred R ^a   Mathies, Richard A ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b MAX PLANCK INSTITUTE FOR CHEMICAL ENERGY CONVERSION   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33751122874     PISSN: 00223654     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp952992e     Document Type: Article

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57. An important caveat in representing the magnitude and mechanistic importance of the excited-state nuclear distortions is that the extent of electron-nuclear coupling as determined by the total Huang-Rhys factor (total 5) is nonetheless quite small for the chlorosome, on the order of 0.20.3. This means that although nuclear motion is certainly driven in the excited state, the ground-to-excited-state displacements are relatively weak compared to, for example, the rhodopsin system.
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