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The transient Raman spectra were recorded for a nonflowing sample in order to confirm whether or not a permanent photoreaction would occur under our experimental condition. Although no evidence of the photoreaction under the low-power excitation was found, some new bands (1567, 1536, and 1485 cm1) could be detected using the high-power excitation (not shown) in the nonflowing sample. On the contrary, it was found that, in the flowing sample with a sufficient flow rate, the new bands mentioned above were not observed under even sufficiently high-power illumination.
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