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[2]). Nevertheless, this tendency is mainly due to the Lewis-acidity and/or oxophilicity of the group 13 elements and cannot be accounted for by means of core shell saturation demands, as it is the case with Zn.
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85163226301
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For clarity, the single steps of isomerisation are discussed as if they occurred one after the other. By logic, a nearly simultaneous course of bond formation and disconnection is most likely to exist.
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29
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85163232223
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note
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In principle, the whole process of isomerisation of the heteroatom array into itself would consist of six such periods (if the single atoms of a same element were labelled distinguishable). After one period, a molecule equal by connectivity, but of inverted stereochemistry would be furnished. Thus, after three periods, the starting molecule would be reattained in its enantiomeric form. Conversion of this ent-molecule back to its original would then call for another three periods.
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30
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85163234535
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note
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Supporting Information for computational details is available (see footnote on the first page of this article).
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