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Volumn , Issue 21, 2006, Pages 4219-4224

"Isomerism" of coordination modes and numbers in pentanuclear organozinc hydroxylamides: An exercise in subtle substituent size effects

Author keywords

Coordination modes; Crystal structure; Hydroxylamines; Organometallic; Zinc

Indexed keywords

AMINES; LIGANDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANOMETALLICS; STEREOCHEMISTRY; ZINC COMPOUNDS;

EID: 33751007296     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200600625     Document Type: Article
Times cited : (24)

References (42)
  • 6
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    • note
    • [2]). Nevertheless, this tendency is mainly due to the Lewis-acidity and/or oxophilicity of the group 13 elements and cannot be accounted for by means of core shell saturation demands, as it is the case with Zn.
  • 21
    • 85163228257 scopus 로고    scopus 로고
    • -3.
  • 28
    • 85163226301 scopus 로고    scopus 로고
    • note
    • For clarity, the single steps of isomerisation are discussed as if they occurred one after the other. By logic, a nearly simultaneous course of bond formation and disconnection is most likely to exist.
  • 29
    • 85163232223 scopus 로고    scopus 로고
    • note
    • In principle, the whole process of isomerisation of the heteroatom array into itself would consist of six such periods (if the single atoms of a same element were labelled distinguishable). After one period, a molecule equal by connectivity, but of inverted stereochemistry would be furnished. Thus, after three periods, the starting molecule would be reattained in its enantiomeric form. Conversion of this ent-molecule back to its original would then call for another three periods.
  • 30
    • 85163234535 scopus 로고    scopus 로고
    • note
    • Supporting Information for computational details is available (see footnote on the first page of this article).
  • 35
    • 85163231250 scopus 로고    scopus 로고
    • Nonius B. V., 1994
    • a) Nonius B. V., 1994;
  • 36
    • 85163232381 scopus 로고    scopus 로고
    • K. Fair, Enraf Nonius B. V., 1990
    • b) K. Fair, Enraf Nonius B. V., 1990;
  • 37
    • 85163227086 scopus 로고    scopus 로고
    • Nonius B. V., 1998
    • c) Nonius B. V., 1998;
  • 40
    • 85163225900 scopus 로고    scopus 로고
    • G. M. Sheldrick, Universität Göttingen, 1997
    • f) G. M. Sheldrick, Universität Göttingen, 1997;


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.