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Volumn 8, Issue 45, 2006, Pages 5339-5349

Stepwise conformational cooling towards a single isomeric state in the four internal rotors system 1,2-butanediol

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EID: 33750968765     PISSN: 14639076     EISSN: None     Source Type: Journal    
DOI: 10.1039/b610962d     Document Type: Article
Times cited : (69)

References (41)
  • 27
    • 33750982454 scopus 로고    scopus 로고
    • Temperatures lower than 10 K are not accessible in our experimental setup
    • Temperatures lower than 10 K are not accessible in our experimental setup
  • 29
    • 33750991927 scopus 로고    scopus 로고
    • Strictly speaking, a pair of isoenergetic or almost isoenergetic conformers, separated by a low energy barrier, may exist in a matrix in the true thermodynamic equilibrium with both forms populated in the detectable amounts. However we found that it is not the case for 1,2-butanediol
    • Strictly speaking, a pair of isoenergetic or almost isoenergetic conformers, separated by a low energy barrier, may exist in a matrix in the true thermodynamic equilibrium with both forms populated in the detectable amounts. However we found that it is not the case for 1,2-butanediol
  • 33
    • 0002481824 scopus 로고
    • -1. In the mixture of conformers, the components' spectra are reduced to less than a half (form 1), or less than 20% (remaining forms) of their calculated values (see Fig. 5). It is then clear that the resulting absorptions in the experimental spectrum are very weak and required a very long accumulation of the spectral signals
    • H. Takeuchi M. Tasumi Chem. Phys. 1983 77 21 34
    • (1983) Chem. Phys. , vol.77 , pp. 21-34
    • Takeuchi, H.1    Tasumi, M.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.